公开(公告)号：ES2219418T3

公开(公告)日：2004-12-01

申请号：ES00979613

申请日：2000-11-21

Applicant: BASF AG

Inventor： KRONER MATTHIAS ,  BUCHNER KARL-HEINZ ,  PERNER JOHANNES

IPC: C04B24/26 ,  C04B24/32 ,  C08F2/06 ,  C08F8/44 ,  C08F220/28 ,  C08F290/06 ,  C08F290/14 ,  C08G65/332 ,  C08L71/02

Abstract: Procedimiento para la obtención de polímeros hidrosolubles que contienen cadenas laterales de éter polialquilenglicólico y que tienen masas moleculares de 15000 hasta 65000, mediante polimerización en solución de ésteres de ácidos carboxílicos etilénicamente insaturados y polialquilenglicoles unilateralmente cerrados por grupos terminales, en caso dado conjuntamente con otros monómeros en al menos un hidrocarburo en presencia de iniciadores de polimerización formadores de radicales y, en caso dado, reguladores de polimerización a temperaturas hasta 200ºC, eliminación del disolvente empleado en la polimerización en solución y disolución de los polímeros en agua para dar soluciones al 50 hasta 80%, neutralizándose, en caso dado, polímeros que contienen grupos ácido, caracterizado porque la concentración de los monómeros en los hidrocarburos asciende a un 70 hasta un 95% en peso.

公开(公告)号：DE50006188D1

公开(公告)日：2004-05-27

申请号：DE50006188

申请日：2000-11-21

Applicant: BASF AG

Inventor： KRONER MATTHIAS ,  BUECHNER KARL-HEINZ ,  PERNER JOHANNES

IPC: C04B24/26 ,  C04B24/32 ,  C08F2/06 ,  C08F8/44 ,  C08F220/28 ,  C08F290/06 ,  C08F290/14 ,  C08G65/332 ,  C08L71/02

Abstract: The invention relates to a process for the preparation of water-soluble polymers containing polyalkylene glycol ether side chains and having molecular weights of from 15,000 to 65,000 by solution polymerization of esters of ethylenically unsaturated carboxylic acids and polyalkylene glycols which are masked on the end groups at one end, if desired together with another monomer in at least one hydrocarbon at monomer concentrations of from 70 to 95% by weight in the presence of free-radical-forming polymerization initiators and, if desired, polymerization regulators at temperatures of up to 200° C., removal of the solvent used in the solution polymerization, and dissolution of the polymers in water to give from 50 to 80% strength by weight solutions, with polymers containing acid groups being neutralized if desired.

公开(公告)号：AT264877T

公开(公告)日：2004-05-15

申请号：AT00979613

申请日：2000-11-21

Applicant: BASF AG

Inventor： KRONER MATTHIAS ,  BUECHNER KARL-HEINZ ,  PERNER JOHANNES

IPC: C04B24/26 ,  C04B24/32 ,  C08F2/06 ,  C08F8/44 ,  C08F220/28 ,  C08F290/06 ,  C08F290/14 ,  C08G65/332 ,  C08L71/02

Abstract: The invention relates to a process for the preparation of water-soluble polymers containing polyalkylene glycol ether side chains and having molecular weights of from 15,000 to 65,000 by solution polymerization of esters of ethylenically unsaturated carboxylic acids and polyalkylene glycols which are masked on the end groups at one end, if desired together with another monomer in at least one hydrocarbon at monomer concentrations of from 70 to 95% by weight in the presence of free-radical-forming polymerization initiators and, if desired, polymerization regulators at temperatures of up to 200° C., removal of the solvent used in the solution polymerization, and dissolution of the polymers in water to give from 50 to 80% strength by weight solutions, with polymers containing acid groups being neutralized if desired.

公开(公告)号：DE50101617D1

公开(公告)日：2004-04-08

申请号：DE50101617

申请日：2001-03-27

Applicant: BASF AG

Inventor： KRONER MATTHIAS ,  PERNER JOHANNES ,  BUECHNER KARL-HEINZ ,  WILD JOCHEN ,  PFISTER JUERGEN

IPC: C08G81/02 ,  C04B24/26 ,  C08F8/14 ,  C08F8/30

Abstract: Polymers containing acid groups are modified by reaction of(a) polymers which comprise at least 5% by weight of a copolymerized monoethylenically unsaturated monomer containing acid groups, have molar masses of from 200 to 100,000 and are obtainable by free-radical polymerization of monoethylenically unsaturated acids in aqueous solution in the presence or absence of other monoethylenically unsaturated monomers and in the presence of at least 4% by weight, based on the monomers used in the polymerization, of a water-soluble sulfur compound in which the sulfur is in the oxidation state +4,with(b) polyalkylene glycols which are end-capped at one end, alkylpolyalkylene glycol amines or mixtures thereof, or mixtures of at least one of the two compounds specified with up to 30% by weight, based on the mixtures, of ammonia, amines, alcohols, hydroxycarboxylic acids or aminocarboxylic acidsat up to 250° C.

公开(公告)号：DE59710275D1

公开(公告)日：2003-07-17

申请号：DE59710275

申请日：1997-03-25

Applicant: BASF AG

Inventor： BAUR RICHARD ,  BERTLEFF WERNER ,  POTTHOFF-KARL BIRGIT ,  EHLE BEATE ,  KRONER MATTHIAS ,  SCHORNICK GUNNAR

IPC: C11D3/30 ,  C11D1/40 ,  C11D1/83 ,  C11D3/00 ,  C11D3/08 ,  C11D3/10 ,  C11D3/36 ,  C11D3/37 ,  C11D3/39 ,  C11D7/08 ,  C11D7/32

Abstract: A mixture comprising(a) from 0.1 to 99% by weight of at least one polycarboxylate having at least 3 carboxyls,(b) from 0.1 to 99% by weight of at least one amine having a pKa value of more than 9, and(c) from 0.1 to 99% by weight of at least one acid selected from the group consisting of mineral acids and organic acids having one or two carboxyls and not more than 10 carbons,with the proviso that the mixture contains less than 24% by weight of triphosphates, is used in detergent and rinse aid formulations.

公开(公告)号：DE59905502D1

公开(公告)日：2003-06-12

申请号：DE59905502

申请日：1999-09-10

Applicant: BASF AG

Inventor： BUECHNER KARL-HEINZ ,  EHLE MICHAEL ,  PERNER JOHANNES ,  OPPENLAENDER KNUT ,  HARTMANN MARKUS ,  GUENTHER WOLFGANG ,  KRONER MATTHIAS

IPC: C04B24/28 ,  C04B24/12 ,  C04B24/26 ,  C04B24/32 ,  C04B28/02 ,  C04B40/00 ,  C04B103/50

公开(公告)号：BR0109615A

公开(公告)日：2003-02-04

申请号：BR0109615

申请日：2001-03-27

Applicant: BASF AG

Inventor： KRONER MATTHIAS ,  PERNER JOHANNES ,  CHNER KARL-HEINZ B ,  WILD JOCHEN ,  PFISTER J RGEN

IPC: C08G81/02 ,  C04B24/26 ,  C08F8/14 ,  C08F8/30

Abstract: Polymers containing acid groups are modified by reaction of(a) polymers which comprise at least 5% by weight of a copolymerized monoethylenically unsaturated monomer containing acid groups, have molar masses of from 200 to 100,000 and are obtainable by free-radical polymerization of monoethylenically unsaturated acids in aqueous solution in the presence or absence of other monoethylenically unsaturated monomers and in the presence of at least 4% by weight, based on the monomers used in the polymerization, of a water-soluble sulfur compound in which the sulfur is in the oxidation state +4,with(b) polyalkylene glycols which are end-capped at one end, alkylpolyalkylene glycol amines or mixtures thereof, or mixtures of at least one of the two compounds specified with up to 30% by weight, based on the mixtures, of ammonia, amines, alcohols, hydroxycarboxylic acids or aminocarboxylic acidsat up to 250° C.

公开(公告)号：CA2410445A1

公开(公告)日：2002-11-26

申请号：CA2410445

申请日：2001-06-06

Applicant: BASF AG

Inventor： MOHR BERNHARD ,  BERTLEFF WERNER ,  KRONER MATTHIAS ,  NEUMANN PETER

IPC: C08F290/06 ,  C08G81/02 ,  C11D3/37 ,  C11D11/00

Abstract: The invention relates to polymers made out of a poly(meth)acrylic acid main chain, in which, in relation to the main chain, 0 to 30 wt. % of the (meth)acrylic acid basic units can be replaced by maleic acid (anhydride) basic units, fumaric acid basic modules or mixtures thereof; and 0 to 10 wt. % of the (meth)acrylic acid basic units can be replaced by other copolymerisable, ethylenic basic units. The polymers are also made of side chains in the form of C1-30-alkylpoly-C2-4-alkylglycols which are bound to t he main chain by means of ester groups and which have an average molecular weig ht of 250 to 10,000. The main chain and side chains make up 1 to 19 wt. % and 8 1 to 99 wt. % of the polymer respectively. The ratio and the average molecular weight of the side chains are chosen in such a way that the polymer contains free carboxyl groups. Said polymers are used as controllable dispersing agen ts for detergents or constituents thereof.

公开(公告)号：AU3723602A

公开(公告)日：2002-07-01

申请号：AU3723602

申请日：2001-12-14

Applicant: BASF AG

Inventor： KRONER MATTHIAS ,  PFISTER JURGEN ,  FAUL DIETER ,  RAUBENHEIMER HANS-JURGEN ,  BUCHNER KARL-HEINZ

IPC: C08G65/48 ,  C08G65/32 ,  C08G65/332 ,  C08G65/00

Abstract: Alkylpolyalkylene glycol esters of monoethylenically unsaturated carboxylic acids are prepared by esterifying (a) monoethylenically unsaturated carboxylic acids with (b) polyalkylene glycols which are endcapped at one end, in the absence of a solvent and in the presence of polymerization inhibitors and esterification catalysts at not more than 160° C. by a process in which the esterification is first carried out under atmospheric pressure or at up to 50 bar, the water formed in the esterification is then distilled from the reaction mixture at from 10 to 500 mbar and the esterification is then continued under atmospheric pressure or at up to 50 bar.

公开(公告)号：DE59607328D1

公开(公告)日：2001-08-23

申请号：DE59607328

申请日：1996-08-29

Applicant: BASF AG

Inventor： BAUR RICHARD ,  BERTLEFF WERNER ,  JAEGER HANS-ULRICH ,  FUNHOFF ANGELIKA ,  KRONER MATTHIAS ,  SCHORNICK GUNNAR

IPC: C08G69/10 ,  C08G69/36 ,  C08G73/06 ,  C08G73/10 ,  C11D3/37

Abstract: PCT No. PCT/EP96/03797 Sec. 371 Date Mar. 4, 1998 Sec. 102(e) Date Mar. 4, 1998 PCT Filed Aug. 29, 1996 PCT Pub. No. WO97/09409 PCT Pub. Date Mar. 13, 1997The use of modified polyaspartic acids which are obtainable by polycondensation of aspartic acid in the presence of, in each case based on the aspartic acid employed, (a) 2.5 to 25 mol % of amines with at least 6 carbon atoms (b) at least 2% by weight of phosphoric acid, phosphorous acid, hypophosphorous acid, polyphosphoric acids, phosphorus pentoxide, phosphonic acids or mixtures of said acids, at temperatures of at least 120 DEG C. and subsequent hydrolysis with bases to give modified polyaspartic acids with a phosphorus content of from 0.5 to 10% by weight, as additive to detergents, and detergents which contain the modified polyaspartic acids in amounts of from 0.1 to 20% by weight.