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公开(公告)号:DE50107292D1
公开(公告)日:2005-10-06
申请号:DE50107292
申请日:2001-06-06
Applicant: BASF AG
Inventor: NEUMANN PETER , BERTLEFF WERNER , KRONER MATTHIAS , MOHR BERNHARD
IPC: C08F290/06 , C08G81/02 , C11D3/37 , C11D11/00
Abstract: Polymers of a poly(meth)acrylic acid main chain in which, based on the main chain, 0 to 30% by weight of the (meth)acrylic acid basic building blocks may be replaced by maleic acid (anhydride) basic building blocks, fumaric acid basic building blocks or mixtures thereof and 0 to 10% by weight of the (meth)acrylic acid basic building blocks may be replaced by other copolymerizable ethylenic basic building blocks,and C1-30-alkylpoly-C2-4-alkylene glycols, bonded to the main chain via ester groups, having an average molecular weight of from 250 to 10 000 as side chains,where, based on the polymer, 1 to 19% by weight of the main chain and 81 to 99% by weight of the side chains are present and this ratio and the average molecular weight of the side chains are chosen such that free carboxyl groups are present in the polymer,are used as controllable dispersants for detergents or cleaners or constituents thereof.
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公开(公告)号:ES2188545T3
公开(公告)日:2003-07-01
申请号:ES00931199
申请日:2000-05-12
Applicant: BASF AG
Inventor: MOHR BERNHARD , BOECKH DIETER , BORZYK OLIVER
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公开(公告)号:DE50002206D1
公开(公告)日:2003-06-18
申请号:DE50002206
申请日:2000-08-16
Applicant: BASF AG
Inventor: LINHART FRIEDRICH , DIRKS BERND , TRESCH RAINER , MOHR BERNHARD , FEHRINGER DIETRICH
IPC: C08G69/10 , C08G18/60 , C08G59/40 , C08G69/48 , D21H17/21 , D21H17/22 , D21H17/54 , D21H21/10 , D21H21/18 , D21H21/22
Abstract: Paper, board and cardboard are produced by a process in which a paper stock is drained in the presence of condensates of basic amino acids with sheet formation. In particular, homo- and cocondensates of lysine and the crosslinked condensates obtainable therefrom by reaction with crosslinking agents are used in amounts of from 0.01 to 5% by weight, based on dry paper stock, as a means of increasing the dry and wet strength and the absorptivity of paper, for fixing anionic dyes and interfering substances in the paper, for increasing the drainage rate and the retention as well as the efficiency of synthetic anionic and cationic retention aids in the production of paper, board and cardboard by draining a paper stock with sheet formation.
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公开(公告)号:DE10027638A1
公开(公告)日:2001-12-13
申请号:DE10027638
申请日:2000-06-06
Applicant: BASF AG
Inventor: BOECKH DIETER , NOERENBERG RALF , HILDEBRANDT SOEREN , MOHR BERNHARD , SCHOEPKE HOLGER , LEYRER REINHOLD , HUFF JUERGEN
IPC: C09K3/00 , C11D1/02 , C11D1/38 , C11D1/66 , C11D1/83 , C11D3/02 , C11D3/30 , C11D3/37 , C11D3/395 , C11D3/40 , C11D3/43 , C11D3/50 , C11D17/08 , C09D5/02 , B01F17/00 , C08G69/48 , C09D7/02 , C09D133/26 , C09K3/18
Abstract: The use of particulate, hydrophobic polymers with a particle size of 10 nm to 100 microns, cationically modified by coating with cationic polymers, as additives in washing, cleaning and impregnating materials for hard surfaces. Independent claims are also included for: (i) a cleaning material for hard surfaces, containing: (a) 0.05-40 wt.% of (I); (b) 0-20 wt.% of water-soluble salt(s) of magnesium, calcium, zinc or aluminum and/or 0.01-30 wt.% of a cationic surfactant and/or 0.01-15 wt.% of cationic polymer; (c) 0-80 wt.% of additive(s) such as acid or base, inorganic builders, organic co-builders, other surfactants, polymeric color-transfer or greying inhibitors, soil-release polymers, enzymes, complex-formers, corrosion inhibitors, waxes, silicone oils, light stabilizers. dyes, solvents, hydrotropic additives, thickeners and/or alkanolamines; and (d) water (to make up to 100 wt.%); (ii) a hard surface cleaner containing: (a) 0.1-30 wt.% of modified polymer as above (I) containing anionic unsaturated monomer units and dispersed in water; (b) 0.05-20 wt.% of acid; (c) 0-30 wt.% of water-soluble salt(s) of magnesium, calcium, zinc or aluminum and/or a cationic surfactant and/or 0.01-15 wt.% of cationic polymer; (d) 0-20 wt.% of additive(s) such as perfume, other surfactants, silicone oil, light stabilizers, dyes, complex-formers, greying inhibitors, soil-release polyesters, color-transfer inhibitors, non-aqueous solvents, hydrotropic additives, thickeners and/or alkanolamines; and (e) water (to make up 100 wt.%); (iii) a liquid cleaning and care formulation containing: (a) 0.05-30 wt.% of (I); (b) 0.1-40 wt.% of non-ionic or anionic surfactant(s); (c) 0-30 wt.% of salts and/or surfactant as above and/or 0.01-15 wt.% of cationic polymer; (d) 0-10 wt.% of complex-former; (e) 0-20 wt.% of additives such as pH regulators, thickeners, solvents, hydrotropic agents, polycarboxylic acids, silicones, brighteners, perfumes and/or dyes; and (f) 0-90 wt.% of water; (iv) a liquid acid cleaner containing: (a) 0.1-30 wt.% of hydrophobic polymer (particle size as above) with anionic monomer units, dispersed in water; (b) 0.05-20 wt.% of acid; (c) 0.1-30 wt.% of water-soluble cationic polymer; (d) 0-10 wt.% of complex former; (e) 0-20 wt.% of additives as in (ii); and (f) 0-90 wt.% of water; (v) a liquid acid cleaner containing: (a) 0.5-25 wt.% of hydrophobic polymer with 5-45 wt.% of unsaturated carboxylic acid monomer units, dispersed in water with anionic emulsifier and/or protective colloid; (b) 0.01-40 wt.% of non-ionic or anionic surfactant; (c) 0.01-20 wt.% of water-soluble or -dispersible cationic polymer; (d) 0.1-30 wt.% of soluble salts as above and/or cationic surfactant; (e) 0.1-20 wt.% of acid; (f) 0-10 wt.% of complex-former; (g) 0-20 wt.% of additives as in (ii); and (h) 0-90 wt.% of water; (vi) a solid cleaning formulation containing: (a) 0.05-30 wt.% of (I); (b) 0.1-40 wt.% of non-ionic and/or anionic surfactant; (c) 0-10 wt.% of cationic polymer; (d) 0-20 wt.% of salts and/or cationic surfactant as above; (e) 0-80 wt.% of inorganic builder, regulator and/or abrasive; (f) 0-20 wt.% of complex former and/or organic co-builder; (g) 0-10 wt.% of additives such as brighteners, wax, oils, perfume, corrosion inhibitors, bleaching agents, activators and/or catalysts and dyes; and (h) water (to make up 100 wt.%); (vii) a liquid after-rinse and impregnating formulation containing: (a) 0.05-30 wt.% of (I); (b) 0.1-30 wt.% of non-ionic or anionic surfactant; (c) 0-10 wt.% of acid, preferably a carboxylic acid; (d) 0-10 wt.% of cationic polymer; (e) 0-20 wt.% of salts and/or cationic surfactant as above; (f) 0-10 wt.% of additives such as thickeners, complex-formers, solvents, oils, waxes, hydrotropic agents, foam suppressants, polycarboxylic acids, silicones, brighteners, perfume and/or dyes; and (g) 0-90 wt.% of water.
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公开(公告)号:CA2410442A1
公开(公告)日:2001-12-13
申请号:CA2410442
申请日:2001-06-02
Applicant: BASF AG
Inventor: MOHR BERNHARD , HUFF JURGEN , SCHOPKE HOLGER , HILDEBRANDT SOREN , BOECKH DIETER , LEYRER REINHOLD J , NORENBERG RALF
IPC: D06L1/12 , C08J3/205 , C11D3/37 , C11D17/06 , D06M15/267 , D06M15/285 , D06M15/356
Abstract: The invention relates to the use of cationically-modified, particle-shaped, hydrophobic polymers as addition agents in rinsing, care, detergent, and cleaning products. The surface of said polymers is cationically modified by means of a coating of cationic polymers and the particle size of said polyme rs ranges from 10 nm to 100 .mu.m.
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公开(公告)号:DE19925251A1
公开(公告)日:2000-12-07
申请号:DE19925251
申请日:1999-06-01
Applicant: BASF AG
Inventor: SCHERZER DIETRICH , GAUS GUENTER , JACOB CHRISTOPHE , MOHR BERNHARD , LUTTER HEINZ-DIETER , BRUCHMANN BERND
Abstract: Polyurethane foam preparation comprises reacting isocyanates with isocyanate reactive compounds in the presence of substituted imidazole catalyst(s) Preparation of polyurethane (PU) foams comprises reacting: (a) isocyanates; (b) isocyanate reactive compounds of mol. wt. 500-8500; and optionally (c) chain extenders and/or crosslinkers of mol. wt. 60-499; in the presence of (d) propellants; and (e) imidazole catalysts of formula (I); and optionally (f) aids and/or additives; R = 1-20C alkyl; R , R = phenyl, halogen, H, 1-4C alkoxy, N-mono or N,N-dialkylamino where the alkyl has 1-4C, , N-mono or N,N-dialkylaminoalkylene where the alkyl has 1-4C and the alkylene has 2-4C; X = 1-6C hydrocarbon or phenyl; A = H, OH or NRZ; Y = H, 2-4C hydroxyalkyl or 2-20C hydroxypolyalkyl; and Z = H, -4C alkyl, phenyl, 2-4C hydroxyalkyl or 2-20C hydroxypolyalkyl. Independent claims are included for the preparation of PU foams as above by reacting 2,4- and/or 2,6-toluylene diisocyanate and/or 4,4'-, 2,2'- and/or 2,4'-diphenylmethane diisocyanate in the presence of 0.02-0.08 wt.% triethylene diamine and 0.05-0.3 wt.% of at least one aminoalkyl and/or an aminophenyl imidazole of formulae (I) or (II) as catalyst and also the use of triethylene diamine and of at least one aminoalkyl and/or an aminophenyl imidazole in a wt. ratio of 1.6-0.06:1 in the preparation of PU foams. R4 = R except halogen and alkoxy; X = 2-6C hydrocarbon or phenyl; A = OH or NYZ.
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公开(公告)号:DE19902982A1
公开(公告)日:2000-07-27
申请号:DE19902982
申请日:1999-01-26
Applicant: BASF AG
Inventor: SCHERZER DIETRICH , GAUS GUENTER , JACOB CHRISTOPHE , MOHR BERNHARD , LUTTER HEINZ-DIETER
Abstract: A new method for preparing foamed materials involves the reaction of: (a) isocyanates; (b) compounds reactive to isocyanates of molecular weight 500-8500; and optionally (c) chain lengthening and/or crosslinking agents of molecular weight 60-499 in the presence of: (d) a propellant; and (e) a catalyst, and optionally (f) adjuvants and/or additives. Foamed materials are prepared by reaction of (a) isocyanates with (b) compounds reactive to isocyanates of molecular weight 500-8500 and optionally (c) chain lengthening and/or crosslinking agents of molecular weight 60-499 in the presence of (d) a propellant and (e) a catalyst, and optionally (f) adjuvants and/or additives. The isocyanate (a) is 2,4- and or 2,6-toluylenediisocyanate and/or 4,4, 2,2, and/or 2,4-diphenylmethane diisocyanate, and the reaction is carried out in the presence of (e1) 0.02-0.08 wt.% triethylenediamine and 0.05-0.3 wt.% of at least one aminoalkyl and/or aminophenyl-imidazole (e2) of formulas (I) and/or (II): where: R -R = phenyl, halogen, H, 1-10C linear or branched alkyl, 1-4C alkoxy, N-mono- or 1-4C N,N-dialkylamino, N-mono- or N,N-dialkylaminoalkylene, i.e. 1-4C alkyl and 2-4C alkylene, R = R , with the exception of halogen and alkoxy; Y = H, 2-4C hydroxalkyl, or hydroxypolyoxyalkyl with 2-20 alkylene oxide units, X (catalyst) = 2-6C alkylene or phenyl, Z = H, 1-4C alkylene, phenyl, 2-4C hydroxyalkyl, or 2-20C hydroxypolyoxyalkylene, and the weigh proportions of (e1) and (e2) are based on the weight proportion of component (b)(sic). Independent claims are included for: (1) A spongy plastic based on polyurethanes, prepared as above; (2) a mixture containing (e1) triethylenediamine and (e2) at least one aminoalkyl- and/or aminophenyl-imidazole at an e1 to e2 ratio of 1.6:1 to 0.06:1.
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公开(公告)号:DE19902506A1
公开(公告)日:2000-07-27
申请号:DE19902506
申请日:1999-01-22
Applicant: BASF AG
Inventor: BOECKH DIETER , MOHR BERNHARD , SEELMANN-EGGEBERT HANS-PETER , STOECKIGT DIETER
Abstract: Water-soluble and/or -dispersible polymers based on lysine, arginine, ornithine and/or tryptophan are used as additives to water for rinsing cleaned hard articles made from metals, glass, porcelain or plastics or lacquered surfaces of these materials.
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公开(公告)号:DE19902982B4
公开(公告)日:2007-02-08
申请号:DE19902982
申请日:1999-01-26
Applicant: BASF AG
Inventor: SCHERZER DIETRICH , GAUS GUENTER , JACOB CHRISTOPHE , MOHR BERNHARD , LUTTER HEINZ-DIETER
Abstract: A new method for preparing foamed materials involves the reaction of: (a) isocyanates; (b) compounds reactive to isocyanates of molecular weight 500-8500; and optionally (c) chain lengthening and/or crosslinking agents of molecular weight 60-499 in the presence of: (d) a propellant; and (e) a catalyst, and optionally (f) adjuvants and/or additives. Foamed materials are prepared by reaction of (a) isocyanates with (b) compounds reactive to isocyanates of molecular weight 500-8500 and optionally (c) chain lengthening and/or crosslinking agents of molecular weight 60-499 in the presence of (d) a propellant and (e) a catalyst, and optionally (f) adjuvants and/or additives. The isocyanate (a) is 2,4- and or 2,6-toluylenediisocyanate and/or 4,4, 2,2, and/or 2,4-diphenylmethane diisocyanate, and the reaction is carried out in the presence of (e1) 0.02-0.08 wt.% triethylenediamine and 0.05-0.3 wt.% of at least one aminoalkyl and/or aminophenyl-imidazole (e2) of formulas (I) and/or (II): where: R -R = phenyl, halogen, H, 1-10C linear or branched alkyl, 1-4C alkoxy, N-mono- or 1-4C N,N-dialkylamino, N-mono- or N,N-dialkylaminoalkylene, i.e. 1-4C alkyl and 2-4C alkylene, R = R , with the exception of halogen and alkoxy; Y = H, 2-4C hydroxalkyl, or hydroxypolyoxyalkyl with 2-20 alkylene oxide units, X (catalyst) = 2-6C alkylene or phenyl, Z = H, 1-4C alkylene, phenyl, 2-4C hydroxyalkyl, or 2-20C hydroxypolyoxyalkylene, and the weigh proportions of (e1) and (e2) are based on the weight proportion of component (b)(sic). Independent claims are included for: (1) A spongy plastic based on polyurethanes, prepared as above; (2) a mixture containing (e1) triethylenediamine and (e2) at least one aminoalkyl- and/or aminophenyl-imidazole at an e1 to e2 ratio of 1.6:1 to 0.06:1.
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公开(公告)号:DE50109880D1
公开(公告)日:2006-06-29
申请号:DE50109880
申请日:2001-06-02
Applicant: BASF AG
Inventor: BOECKH DIETER , NOERENBERG RALF , HILDEBRANDT SOEREN , MOHR BERNHARD , SCHOEPKE HOLGER , LEYRER J , HUFF JUERGEN
IPC: C11D3/37 , D06L1/12 , C08J3/205 , C11D17/06 , D06M15/267 , D06M15/285 , D06M15/356
Abstract: The invention relates to the use of cationically-modified, particle-shaped, hydrophobic polymers as addition agents in rinsing, care, detergent, and cleaning products. The surface of said polymers is cationically modified by means of a coating of cationic polymers and the particle size of said polymers ranges from 10 nm to 100 mum.
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