103.
    发明专利
    未知

    公开(公告)号:DE3775657D1

    公开(公告)日:1992-02-13

    申请号:DE3775657

    申请日:1987-08-18

    Applicant: BASF AG

    Abstract: Quinoline-8-carboxylic acid derivs. of formula (I) are new, where R1 = H, 1-4C alkyl, 2-4C alkenyl, or one equivalent of an alkali or alkaline earth metal cation; R2 = F, Cl or Br, R3 = -CHX-R4, -CY-R5, F, Br, I, -SCN, NO2, amino, hydrazino, -N2+Z-, -NHCHO, -NHCOOR6, -NHCONHR5, -NHCOCOR6, -NHCOCH2COR6, -NHCOCH2COOR6, -NH-CH=C(COOR6)2, -N=CH-NR7R8, -NHCOR5, -NHCONHCOR6, -NHSO2R6 or -NHSO2NHR6; X = Cl, Br, I, -SCN, -OR5, -SR5, -SO2R6; Y = O, =NR5, =NOH, =NNH2, =NOR4, =N-OCHO, =NOCOR5, =NO-CO2R4, =NO-CO-NHR6, =N-NHR5, =N-NH-COR5, =N-NH-CO2R4, =N-NHCONH2, =N-NH-CS-NH2 or =N-NH-SO2R6; Z = Br, BF4, PF6 or SbF6; R4 = 1-4C alkyl, 2-4C alkenyl, 1-4C haloalkyl or 2-4C haloalkenyl; R5 = H (provided that Y is other than 0), 1-4C alkyl, 1-4C hydroxyalkyl, 1-4C halo-alkyl, phenyl (opt. substd. by halogen or 1-4C alkyl), 2-5C carboxyalkyl, or 3-8C alkoxycarbonylalkyl; R6 = 1-4C alkyl, 1-4C haloalkyl, 2-5C alkylcarbonyl, 2-5C haloalkylcarbonyl, or phenyl (opt. substd. by halogen or 1-4C alkyl); R7, R8 = 1-4C alkyl.

    New cyclohexenone oxime phenyl- and hetero:aryl-alkynyl ether(s) - useful as herbicides, esp. for control of weed grasses

    公开(公告)号:DE4018508A1

    公开(公告)日:1991-12-12

    申请号:DE4018508

    申请日:1990-06-09

    Applicant: BASF AG

    Abstract: Cyclohexenone oxime ethers (I) and their salts and 1-10C carboxylic acid and inorganic acid esters are new: where A = 3-6C alkynylene opt. mono-, di- or tri-substd. by 1-3C alkyl and/or halogen; Z = phenyl or an O, S or N-contg. 5- or 6-membered heteroaromatic gp. opt. substd. by Xn; X = nitro, cyano, halogen, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C haloalkyl, 1-4C haloalkoxy, carboxyl, 1-4C alkoxycarbonyl, benzyloxycarbonyl, and/or phenyl; where the rings are opt. mono-, di- or tri-substd. by nitro, cyano, halogen, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C haloalkyl, 1-4C haloalkoxy, carboxyl, 1-4C alkoxycarbonyl, and/or benzyloxycarbonyl; n = 0-3 or 1-5 when X = halogen; R1 = 1-6C alkyl; R2 = 1-4C alkoxy-1-6C alkyl, 1-4C alkylthio-1-6C alkyl, 3-7C cycloalkyl or 5-7C cycloalkenyl opt. mono-, di- or tri-substd. by 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C haloalkyl, hydroxy and/or halogen; a 5-membered satd. heterocyclic gp. contg. 1 or 2 O and/or S atoms and opt. mono-, di- or tri-substd. by 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio and/or 1-4C haloalkyl; a 6- or 7-membered heterocyclic gp. contg. 1 or 2 O and/or S atoms and up to 2 double bonds and opt. mono-, di- or tri-substd. by hydroxy, halogen, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio and/or 1-4C haloalkyl; a 5-membered heteroaromatic gp. contg. 1 or 2 N atoms and/or 1 O or S atom and opt. mono-, di- or tri-substd. by halogen, cyano, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C haloalkyl, 2-6C alkenyl, 2-6C alkenyloxy, 2-6C haloalkenyl and/or 1-4C alkoxy-1-4C alkyl; or phenyl or pyridyl opt. mono-, di- or tri-substd. by halogen, nitro, cyano, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio, 1-4C alkoxy-1-4C alkyl, 1-4C alkylthio-1-4C alkyl, 1-4C haloalkyl, 3-6C alkenyloxy, 3-6C alkynyloxy. Intermediates of formula H2N-O-A-Z (III) are also claimed. USE - Cpds. (I) are herbicides, esp. against weed grasses. They can be applied at a rate of 0.001-3 kg/ha.

    New and known pyrimido-1,2,4-triazine derivs.

    公开(公告)号:DE3924845A1

    公开(公告)日:1991-01-31

    申请号:DE3924845

    申请日:1989-07-27

    Applicant: BASF AG

    Abstract: (A) Pyrimido(5,4-e)(1,2,4) triazine-5,7(6H,8H)-diones of formula (Ia) and their mineral acid salts are new, where n = 0 or 1; R1 and R2 = H, 1-6C alkyl, 3-6C cycloalkyl, 2-8C alkenyl, phenyl or benzyl; R'3 = (a) 1-8C alkyl substd. by 1 or 2 of halogen, OH, 1-6C alkoxy, (1-4C)alkoxy(1-4C)alkoxy and 1-6C alkylthio, (b) 3-6C cycloalkyl substd. by 0-3 of 1-4C alkyl, (c) 5- or 6-membered satd. heterocyclyl with one NR'4 heteroatom or with 2 non-adjacent heteroatoms selected from O, S and NR'4, (d) COR'4 or COOR'4, (e) monocyclic heteroaryl substd. by 1-3 of halogen, NO2, 1-6C alkyl, 2-6C alkenyl, 1-6C alkoxy or NR'4R'5. or (f) 2-6C alkoxy or Z'R'6; R'4 and R'5 = 1-6C alkyl; Z' = S or NR'7; R'6 = H, 2-6C alkyl, or phenyl or benzyl substd. by 0-3 of 1-6C alkyl, 1-6C alkoxy or halogen; R'7 = 1-6C alkyl; or NR'6R'7 = 5- or 6-membered ring opt. contg. O. (B) Herbicidal compsns. contain pyrimido(5,4-e)(1,2,4) triazine-5,7(6H,8H)-diones of formula (I) or their mineral acid salts: R3 = (a) H, halogen or NO2, (b) 1-8C alkyl substd. by 0-3 of halogen, OH, 1-6C alkoxy, 1-6C alkyl (sic), (1-4C)alkoxy(1-4C)alkoxy, 2-6C alkenyl, 1-6C alkylthio, phenyl and benzyl, (c) 2-6C alkenyl or phenylalkenyl, (d) 2-6C cycloalkyl substd. by 0-3 of 1-4C alkyl, (e) 5- or 6-membered C-organic (sic) heterocyclyl contg. up to two non-adjacent heteroatoms selected from O, S and NR4, (f) COR4 or COOR4, (g) phenyl or monocyclic heteroaryl, substd. by 0-3 of halogen, NO2, 1-6C alkyl, 2-6C alkenyl, 1-6C alkoxy or NR4R5, or (h) ZR6; R4 and R5 =H or 1-4C alkyl; Z = O, S or NR7; R6 = H, 1-6C alkyl, or phenyl or benzyl substd. by 0-3 of 1-6C alkyl, 1-6C alkoxy or halogen; R7 = H or 1-6C alkyl; or NR6R7 = a 5- or 6-membered ring opt. contg. O.

    109.
    发明专利
    未知

    公开(公告)号:DE3860380D1

    公开(公告)日:1990-09-06

    申请号:DE3860380

    申请日:1988-05-31

    Applicant: BASF AG

    Abstract: 1. A cyclohexenone compound of the formula I see diagramm : EP0293817,P16,F3 where R**1 is hydrogen ; C1 -C6 -alkyl which is unsubstituted or substituted by C1 -C4 -alkoxy, C1 -C4 -alkylthio, C1 -C4 dialkylamino, hydroxyl or halogen ; C2 -C6 -alkenyl ; C3 -C6 -cycloalkyl ; or phenyl or benzyl which is unsubstituted or substituted by halogen, C1 -C4 -alkyl, C1 -C4 -alkoxy or nitro, R**2 is C1 -C4 -alkyl or cyclopropyl, A is oxygen ; a radical NOR**3 , where R**3 is C1 -C4 -alkyl, C3 or C4 -alkenyl, C3 - or C4 -alkynyl, C2 -C4 -haloalkyl, C3 - or C4 -haloalkenyl or C2 -C4 -alkoxyalkyl ; or a radical NR4 , where R4 is hydrogen, C1 -C6 -alkyl, C1 -C4 -hydroxyalkyl, C1 -C4 -alkoxyalkyl, benzyl or phenyl, and X is hydroxyl ; chlorine ; C1 -C6 -alkylthio which is unsubstituted or substituted by C1 -C4 -alkoxy, C1 -C4 -alkylthio, C1 -C4 dialkylamino, hydroxyl or halogen ; C2 -C6 -alkenylthio ; C3 -C6 -cycloalkylthio ; or phenylthio or benzylthio which is unsubstituted or substituted by halogen, C1 -C4 -alkoxy or nitro, or an agriculturally usable salt thereof.

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