公开(公告)号：CA2221515A1

公开(公告)日：1997-02-06

申请号：CA2221515

申请日：1996-07-09

Applicant: BASF AG

Inventor： RUEBENACKER MARTIN ,  DENZINGER WALTER ,  M NCH DIETMAR ,  STANGE ANDREAS ,  SCHUHMACHER RUDOLF ,  LORENCAK PRIMOZ ,  NILZ CLAUDIA

IPC: C08B37/00 ,  C08F8/12 ,  C08F261/04 ,  C08F263/02 ,  C08F283/06 ,  C08F291/00 ,  C09D7/45 ,  D21H17/34 ,  D21H17/37 ,  D21H21/10 ,  D21H21/14 ,  D21H21/16 ,  D21H21/18 ,  C09D7/02 ,  C08F291/06 ,  D21H17/36

Abstract: Graft polymers obtainable by the radically initiated polymerisation of (A) monomers or monomer mixture of (a) 1 to 100 wt.% N-vinyl carboxylic acid amides of the formula (I) in which R1, R2 = H and C1 to C6 alkyl, (b) 0 to 99 wt.% other monoethylenically unsaturated monomers copolymerisable with the monomers (a), and (c) 0 to 5 wt.% of at least two ethylenically unsaturated monomers with unconjugated double bonds in the molecule; in the presence of (B) polymers containing units of vinyl esters of saturated C1 to C4 carboxylic acids and/or vinyl alcohol units, or mixtures containing these polymers and polymers containing at least 3 alkylene oxide units or polytetrahydrofurane; in the ratio by weight (A) : (B) of (95 to 10) : (5 to 90), possibly followed by the separation of the group (II) from the polymerised monomers (I) of the graft polymer, with the formation of units of the formula (III); process for the production of the graft polymers and use of the graft polymers described above in the production of paper, paperboard and cardboard as a dry and wet strengthening agent, as a retention and dewatering agent and as a promoter in diketene gumming and as a starch cationisation agent, as a dispersant for pigments and as a creping auxiliary in the production of tissue papers.

公开(公告)号：FI964647A0

公开(公告)日：1996-11-21

申请号：FI964647

申请日：1996-11-21

Applicant: BASF AG

Inventor： HARTMANN HEINRICH ,  SCHNEIDER KARL-HEINRICH ,  DENZINGER WALTER ,  NILZ CLAUDIA ,  MOENCH DIETMAR

IPC: B01J13/00 ,  C02F1/54 ,  C02F1/56 ,  C04B24/26 ,  C08F2/32 ,  C08F8/12 ,  C08F26/00 ,  C08F26/02 ,  C08F126/02 ,  C08L39/02 ,  C09K8/32 ,  C09K23/52 ,  D21H17/34 ,  D21H21/10 ,  C08F

Abstract: PCT No. PCT/EP95/01818 Sec. 371 Date Nov. 21, 1996 Sec. 102(e) Date Nov. 21, 1996 PCT Filed May 13, 1995 PCT Pub. No. WO95/32227 PCT Pub. Date Nov. 30, 1995A process for the preparation of a stable water-in-oil emulsion of a hydrolyzed polymer of an N-vinyl amide of the formula (I) in which R and R1 denote H or C1-C6 alkyl, by the polymerization of a compound of the formula I alone or in admixture with another ethylenically unsaturated monomer in the presence of a polymerization initiator and emulsifier in the form of a water-in-oil emulsion, to form a water-in-oil polymeric emulsion, followed by hydrolysis of the polymer in the form of the water-in-oil polymeric emulsion in the presence of an acid or base and from 1 to 30 wt %, based on the polymer, of an emulsifier, the emulsifier used being a mixture of (a) from 5 to 95 wt % of a block or graft copolymer of the structure (A-B)m, (A)-B or (B)-A, in which in each case (a) from 5 to 95 wt % of a block or graft copolymer of the structure (A-B)m, (A)nB or (B)nA, in which in each case A is a hydrophobic homopolymer or copolymer having a degree of polymerization of at least 3, B is a hydrophilic homopolymer or copolymer having a degree of polymerization of at least 3, m is equal to or greater than 1, and n is equal to or greater than 2, and (b) from 5 to 95 wt % of another water-in-oil emulsifier having a molar mass below 1000 g/mol.

公开(公告)号：CA2217295A1

公开(公告)日：1996-11-07

申请号：CA2217295

申请日：1996-04-20

Applicant: BASF AG

Inventor： STANGE ANDREAS ,  RUEBENACKER MARTIN ,  DENZINGER WALTER ,  MOENCH DIETMAR ,  SCHUHMACHER RUDOLF ,  LORENCAK PRIMOZ ,  NILZ CLAUDIA

IPC: C08B31/12 ,  C08F8/12 ,  C08F283/00 ,  C08F283/06 ,  C09B67/46 ,  C09D17/00 ,  D21H17/53 ,  D21H19/20 ,  D21H21/10 ,  D21H21/16 ,  D21H21/18

Abstract: Graft polymers are obtained by radically initiated polymerisation of (A) monomers or monomer mixtures of (a) 10 to 100 % by weight N-vinyl carboxylic acid amides having the formula (I), in which R1 stands for R2=H and C1-C6 alkyl, (b) 0 to 90 % by weight other monoethylenically unsaturated monomers that may be copolymerised with monomers (a), and (c) 0 to 5 % by weight of at least two ethylenically unsaturated monomers that contain non-conjugated double bonds in their molecule, in the presence of (B) polymers that contain at least 3 units of a C2-C4 alkylene oxide and/or polytetrahydrofuranes, in a weight ratio (A):(B) equal to (95 to 10):(5 to 80). The group (IV) is then optionally separated from the polymerised monomer (a) of the graft polymer, forming at least units having the formula (1). Also disclosed are a process for preparing said graft polymers and their use as dry and wet strengthincreasing agents, as fixatives for impurities and fillers, as retention and dewatering agents for paper-making, as promoters during paper, cardboard and paperboard diketen gluing, as pigment dispersants, as starch cationising agents and as auxiliary substances for producing paper tissues.

公开(公告)号：DE59302953D1

公开(公告)日：1996-07-18

申请号：DE59302953

申请日：1993-11-25

Applicant: BASF AG

Inventor： NILZ CLAUDIA ,  DENZINGER WALTER ,  HARTMANN HEINRICH ,  KROENER MICHAEL ,  LINHART FRIEDRICH ,  SCHUHMACHER RUDOLF ,  MOENCH DIETMAR ,  STANGE ANDREAS

IPC: C08F220/04 ,  C08F8/12 ,  C08F26/00 ,  C08F226/02 ,  D21H17/34 ,  D21H17/37 ,  D21H17/43 ,  D21H17/45 ,  D21H21/10 ,  D21H21/18

公开(公告)号：CA2186289A1

公开(公告)日：1995-09-28

申请号：CA2186289

申请日：1995-03-11

Applicant: BASF AG

Inventor： HARTMANN HEINRICH ,  DENZINGER WALTER ,  NILZ CLAUDIA

IPC: C05G3/00 ,  C08F263/00 ,  C08F265/00 ,  C08F271/00 ,  C09B67/00 ,  C09B67/46 ,  C09D17/00 ,  C09K17/20 ,  C09K23/00 ,  C09K23/52 ,  C11D3/37 ,  D21H17/34 ,  D21H21/18

Abstract: Graft polymers containing N-vinyl units in which the graft base is a polymer which contains at least 5 wt % units of formulae (I), (II) in which R1, R2 = H or C1 to C6 alkyl, monoethylenically unsaturated monomers are grafted on the graft base in the ratio by weight of 100 : 1 to 1: 100 and the graft polymers have K values of at least 7 (determined according to H. Fikentscher in 5 wt % aqueous solution at 25 ~C and pH 7), process for producing graft polymers containing N-vinyl units by the polymerisation of monoethylenically unsaturated monomers in the presence of polymers containing at least 5 wt % units of formula (I) and/or (II) as the graft base in the ratio by weight of 100 : 1 to 1 : 100 and use of the graft polymers as dispersants for pigments, additives in washing and cleaning agents, compacting agents for paper, and floor and fertiliser compacting agents.

公开(公告)号：HU227055B1

公开(公告)日：2010-05-28

申请号：HU9902557

申请日：1997-03-04

Applicant: BASF AG

Inventor： GEBHARDT NORBERT ,  JOHANSEN CHARLOTTE ,  NILZ CLAUDIA ,  STEUERLE ULRICH ,  ZELLER DIETER

IPC: A01N25/04 ,  A01N25/10 ,  A01N33/04 ,  A01N37/18 ,  A01N37/34 ,  A01N43/50 ,  A01N61/00

Abstract: The use of polymers (I) as biocides is new, where (I) comprises: (a) 0.1-100 mol. % vinylamine (VA) or ethyleneimine units; (b) 0-99.9 mol.% units derived from at least one monomer selected from N-vinylcarboxamides of formula CH2=CH-N(R1)-CO-R2 (II), vinyl formate, vinyl acetate, vinyl propionate, vinyl alcohol, (1-6C) alkyl-vinyl ethers, monoethylenically unsaturated 3-8C carboxylic acids, or their esters, nitriles, amides and anhydrides, N-vinylurea, N-vinylimidazoles and N-vinylimidazolines; and (c) 0-5 mol.% units derived from monomers with at least two ethylenically unsaturated double bonds. The sum of (a)-(c) is 100 mol.%. R1, R2 = H or 1-6C alkyl.

公开(公告)号：CA2248154C

公开(公告)日：2006-07-11

申请号：CA2248154

申请日：1997-03-04

Applicant: BASF AG

Inventor： STEUERLE ULRICH ,  JOHANSEN CHARLOTTE ,  NILZ CLAUDIA ,  ZELLER DIETER ,  GEBHARDT NORBERT

IPC: A01N25/04 ,  A01N37/18 ,  A01N25/10 ,  A01N33/04 ,  A01N37/02 ,  A01N37/06 ,  A01N37/34 ,  A01N43/50 ,  A01N47/28 ,  A01N61/00

Abstract: The invention concerns the use as biocides of polymers which contain the following incorporated by polymerization: (a) between 0.1 and 100 mol % vinyl amine units or ethylene imine units; (b) between 0 and 99.9 mol % units of at least one monomer selected from the group comprising open-chain N-vinyl carboxylic acid amides, vinyl formiate, vinyl acetate, vinyl propionate, vinyl alcohol, C1 to C6 alkyl vinyl ether, monoethylenically unsaturated C3 to C8 carboxylic acids, their esters, nitriles, amides and anhydrides, N-vinyl urea, N-vinyl imidazoles and N-vinyl imidazolines; and (c) between 0 and 5 mol % units of monomers having at least two ethylenically unsaturated double bonds. The total of (a), (b) and (c) in mol % is always 100.

公开(公告)号：DE59610738D1

公开(公告)日：2003-10-30

申请号：DE59610738

申请日：1996-04-20

Applicant: BASF AG

Inventor： DENZINGER WALTER ,  RUEBENACKER MARTIN ,  NILZ CLAUDIA ,  LORENCAK PRIMOZ ,  MOENCH DIETMAR ,  SCHUHMACHER RUDOLF ,  STANGE ANDREAS

IPC: C08B31/12 ,  C08F8/12 ,  C08F283/00 ,  C08F283/06 ,  C09B67/46 ,  C09D17/00 ,  D21H17/34 ,  D21H17/53 ,  D21H19/20 ,  D21H21/10 ,  D21H21/16 ,  D21H21/18

公开(公告)号：ES2167010T3

公开(公告)日：2002-05-01

申请号：ES97935551

申请日：1997-07-29

Applicant: BASF AG

Inventor： NIESSNER MANFRED ,  RUBENACKER MARTIN ,  NILZ CLAUDIA ,  HOSSEL PETER

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/81 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/10 ,  A61Q5/12 ,  A61Q11/00 ,  A61Q19/00 ,  C08F8/00 ,  C08F22/38 ,  C08F26/02 ,  C08F226/02 ,  C08F271/00 ,  A61K7/06

公开(公告)号：DE59705203D1

公开(公告)日：2001-12-06

申请号：DE59705203

申请日：1997-07-29

Applicant: BASF AG

Inventor： NIESSNER MANFRED ,  RUEBENACKER MARTIN ,  NILZ CLAUDIA ,  HOESSEL PETER

IPC: A61K8/72 ,  A61K8/00 ,  A61K8/81 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/10 ,  A61Q5/12 ,  A61Q11/00 ,  A61Q19/00 ,  C08F8/00 ,  C08F22/38 ,  C08F26/02 ,  C08F226/02 ,  C08F271/00 ,  A61K7/06