101.
    发明专利
    未知

    公开(公告)号:DE102004054303A1

    公开(公告)日:2006-05-11

    申请号:DE102004054303

    申请日:2004-11-09

    Applicant: BASF AG

    Abstract: A process for preparing perylene-3,4-dicarboximides which bear a sterically demanding substituent on the imide nitrogen atom by reacting a perylene-3,4:9,10-tetracarboxylic dianhydride with a sterically hindered primary amine in a substantially anhydrous reaction medium, which comprises undertaking the reaction in the presence of a tertiary amine, of a solvent based on a cyclic imine or amide and of a Lewis acid as a catalyst.

    102.
    发明专利
    未知

    公开(公告)号:DE102004041604A1

    公开(公告)日:2006-03-02

    申请号:DE102004041604

    申请日:2004-08-26

    Applicant: BASF AG

    Abstract: A process for preparing quaterrylene-3,4:13,14-tetracarboximides of the general formula I in which R, R′ are each independently hydrogen or optionally substituted C1-C30-alkyl, C5-C8-cycloalkyl or aryl or hetaryl; which comprises reacting a perylene-3,4-dicarboximide of the general formula IIa in the presence of a base-stable, high-boiling, organic solvent and of an alkali metal base or alkaline earth metal base, with a perylene-3,4-dicarboximide of the general formula IIb in which X is hydrogen, bromine or chlorine.

    104.
    发明专利
    未知

    公开(公告)号:DE10110552A1

    公开(公告)日:2002-09-12

    申请号:DE10110552

    申请日:2001-03-05

    Applicant: BASF AG

    Abstract: The present invention relates to novel reactive dyes of formula I, (I), in which the variable independently denote X hydrogen, NO2, or NR R , Y NR R , OR , SR , or SO2R or a group suitable as a leaving group under the conditions of nucleophilic, aromatic substitution, R to R independently hydrogen, C1-C8 alkyl, C2-C8 alkyl, in which non-adjacent CH2 groups can be replaced by oxygen atoms, imino groups, or C1-C4 alkylimino groups, and/or CH2 groups may be replaced by carbonyl groups, C2-C8 alkenyl, or a group containing an active site or the precursor of an active site, with the proviso that at least one group R to R is present which contains an active site or the precursor of an active site. The present invention also relates to the use of the reactive dyes of Formula I for dyeing substrates containing nucleophilic groups, and to compositions containing at least one reactive dye of formula I.

    105.
    发明专利
    未知

    公开(公告)号:DE10059032A1

    公开(公告)日:2002-05-29

    申请号:DE10059032

    申请日:2000-11-28

    Applicant: BASF AG

    Abstract: According to the invention, trisazo dyes are produced by half-side coupling bis-diazotized 4-(4-amino phenylsulfamoyl)aniline to 1-amino-8-hydroxynaphthalene monosulfonic and disulfonic acids, by subsequently coupling diazotized substituted anilines to the other portion of the sulfonic acid, and finally by reacting the second diazonium group on the 4-(4-amino phenylsulfamoyl)aniline with a coupling partner. The inventive trisazo dyes are particularly suited for dying leather and polyamide fibers.

    3-acylamino-4-(2-[nitro/cyano]-4-nitro-5-substituted-phenylazo)aniline azo dyes & the 2-(nitro/cyano)-4-nitro-5-substituted-aniline diazo component precursors

    公开(公告)号:GB2327426A

    公开(公告)日:1999-01-27

    申请号:GB9815161

    申请日:1998-07-13

    Applicant: BASF AG

    Abstract: Azo dyes of the formula [where X is oxygen or a radical of the formula NR 6 , where R 6 is hydrogen or optionally substituted C 1 -C 13 -alkyl (optionally interrupted by 1-4 ether groups and optionally substituted by hydroxy or C 1-4 -alkanoyloxy) R 1 is C 1 -C 13 -alkyl (optionally interrupted by 1-4 ether groups and optionally substituted by hydroxy or optionally halogenated C 1-4 -alkanoyloxy) or is optionally substituted phenyl, Y is hydrogen, halogen or cyano Z is nitro or additionally cyano when Y is halogen or cyano, R 2 is C 1 -C 4 -alkyl, methoxymethyl or optionally substituted phenyl, R 3 is hydrogen, C 1 -C 4 -alkoxy or C 1 -C 4 -alkyl, and R 4 and R 5 are each C 1 -C 13 -alkyl (optionally interrupted by 1-4 ether groups and optionally substituted by hydroxy, cyano or C 1-4 -alkanoyloxy) or C 2 -C 6 -alkenyl] are useful for dyeing or printing synthetic materials and are synthesizable using novel dinitroaminoaromatics (as diazo components) of formula where X, Y, Z and R 1 are as defined above. Compounds of formulae (IIa) and (IIb), which are defined in claims 11 and 12 respectively and lie within the definition of formula (II) above, are claimed per se.

    Method for producing 4,4' dihalogendiphenylsulfone

    公开(公告)号:AU8437998A

    公开(公告)日:1999-01-04

    申请号:AU8437998

    申请日:1998-06-10

    Applicant: BASF AG

    Abstract: The invention relates to a method for producing 4,4'-dihalogendiphenylsulfone by reacting halogenated benzene with 4-halogenphenylsulfonyl chloride in a liquid phase at high temperature, in the presence of a solid catalyst having acid centers. The method is characterized in that the reaction of 4-halogenphenylsulfonyl chloride with formula (I), in which X is chlorine, bromine or fluorine, with chlorobenzene, bromobenzene, or fluorobenzene, is carried out in the presence of a catalyst which is selected from one of the following groups: K1) catalysts consisting of essentially stratified silicates not having Lewis acids and having proton-saturated negative layer loads, or containing these as a basic component; K2) catalysts consisting of zeolites in the acid H form, or containing these as a basic component; and K3) catalysts consisting of mixed oxides having acidic centres, or containing these as basic components. The mixed oxides consist of a combination of (a) titanium, circonium, hafnium, tin, iron or Cr(III) oxides on the one hand, and (b) vanadium, chromium(VI), molybdenum, wolfram or scandium oxides on the other hand; or the mixed oxides are sulfatized or phosphatized oxides of the group (a), and said mixed oxides are calcined after combination, at temperatures of 450 to 800 DEG C.

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