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    Ultralow-loss silica glass and optical fibers using the same
    102.
    发明授权
    Ultralow-loss silica glass and optical fibers using the same 有权
    超低损耗石英玻璃和使用其的光纤

    公开(公告)号：US06153546A

    公开(公告)日：2000-11-28

    申请号：US229582

    申请日：1999-01-13

    Applicant: Kazuya Saitoh ,  Akira Ikushima

    Inventor： Kazuya Saitoh ,  Akira Ikushima

    IPC: C03C3/06 ,  C03C13/04

    CPC classification number: C03C13/046 ,  C03B37/014 ,  C03C3/06 ,  G02B6/02 ,  C03B2201/07 ,  C03B2201/30 ,  C03B2201/50 ,  C03B2201/54 ,  C03C2201/40 ,  C03C2201/50 ,  C03C2201/54

    Abstract: This ultralow-loss glass is characterized in that high purity silica glass contains 1 to 500 wt.ppm of at least one network modifying oxide. It is assumed that the network modifying oxide appropriately loosens the tetrahedral network structure of silica and hence Rayleigh scattering is decreased. Examples of the network modifying oxide include Na.sub.2 O, K.sub.2 O, Li.sub.2 O, MgO, CaO, and PbO. Since Rayleigh scattering losses are minimal in comparison with those of high purity silica glass, this impurity-added silica glass is excellent as a base material of a glass fiber for a long-distance transmission.

    Abstract translation: 这种超低损耗玻璃的特征在于，高纯度二氧化硅玻璃含有1至500重量ppm的至少一种网络改性氧化物。 假设网络修饰氧化物适当地松散二氧化硅的四面体网络结构，因此瑞利散射降低。 网络改性氧化物的实例包括Na 2 O，K 2 O，Li 2 O，MgO，CaO和PbO。 由于与高纯度二氧化硅玻璃相比，瑞利散射损失最小，所以这种添加了杂质的石英玻璃作为用于长距离传输的玻璃纤维的基材是优异的。

    Electric incandescent and discharge lamps having doped quartz glass envelopes
    103.
    发明授权
    Electric incandescent and discharge lamps having doped quartz glass envelopes 失效
    具有掺杂石英玻璃信封的电白炽灯和放电灯

    公开(公告)号：US5680010A

    公开(公告)日：1997-10-21

    申请号：US595408

    申请日：1996-02-05

    Applicant: Werner Weiss ,  Gerhard Wagner

    Inventor： Werner Weiss ,  Gerhard Wagner

    IPC: C03C3/06 ,  H01J17/16 ,  H01J61/30

    CPC classification number: C03C3/06 ,  C03C2201/10 ,  C03C2201/32 ,  C03C2201/54 ,  C03C2203/10

    Abstract: Soft quartz glass having low viscosity and a low thermal coefficient of expansion, high electrical insulation capability and free from release of contaminants, when used as a bulb of an incandescent lamp or as an envelope in an arc vessel of a discharge lamp, is a quartz glass made of ultra-pure quartz (SiO.sub.2), for example having a purity of 99.99 mol-%, doped with stoichiometric compounds of alkaline earth oxides with boron oxide, optionally also with a small quantity of Al.sub.2 O.sub.3 in an overall quantity of the doping substance of between about 0.05% to 0.8%, by weight.

    Abstract translation: 当用作白炽灯的灯泡或放电灯的电弧容器中的封套时，具有低粘度和低热膨胀系数，高电绝缘能力并且不会释放污染物的软石英玻璃是石英 用超纯石英（SiO 2）制成的玻璃，例如纯度为99.99mol％，掺杂有化学计量的碱土金属氧化物与氧化硼的化合物，任选地还含有少量的掺杂物质的总量的Al2O3 在约0.05％至0.8％之间。

    Fixation by anion exchange of toxic materials in a glass matrix
    104.
    发明授权
    Fixation by anion exchange of toxic materials in a glass matrix 失效
    通过玻璃基质中有毒物质的阴离子交换固定

    公开(公告)号：US4544499A

    公开(公告)日：1985-10-01

    申请号：US386215

    申请日：1982-06-07

    Applicant: Danh C. Tran ,  Pedro B. Macedo ,  Joseph H. Simmons ,  Catherine J. Simmons ,  Nicholas Lagakos

    Inventor： Danh C. Tran ,  Pedro B. Macedo ,  Joseph H. Simmons ,  Catherine J. Simmons ,  Nicholas Lagakos

    IPC: G21F9/30 ,  G21F9/36 ,  G21F9/16

    CPC classification number: C03C11/005 ,  C03C1/002 ,  C03C1/026 ,  C03C21/001 ,  C03C23/0095 ,  C03C3/06 ,  C03C3/061 ,  C03C3/089 ,  G21F9/305 ,  G21F9/36 ,  C03C2201/10 ,  C03C2201/20 ,  C03C2201/23 ,  C03C2201/3411 ,  C03C2201/3423 ,  C03C2201/3429 ,  C03C2201/40 ,  C03C2201/54 ,  C03C2201/60

    Abstract: This invention relates to the immobilization of toxic, e.g., radioactive materials, internally in a silicate glass or silica gel matrix for extremely long periods of time. Toxic materials, such as radioactive wastes containing radioactive anions, and in some cases cations, which may be in the form of liquids, or solids dissolved or dispersed in liquids or gases, are internally incorporated into a glass matrix, having hydrous organofunctionalsiloxy groups, e.g., hydrous aminoalkylsiloxy or carboxyorganosiloxy, bonded to silicon atoms of said glass and/or hydrous polyvalent metals bonded to silicon atoms of said glass through divalent oxygen linkages or otherwise immobilized therein, by a process which involves the ion exchange of said toxic, radioactive anions with hydroxyl groups attached to said organofunctionalsiloxy groups or with hydroxyl groups attached to the hydrous polyvalent metal. Thereafter, the resulting glass now characterized by a distribution of internally bonded or immobilized, toxic, radioactive anions can be packaged in suitable containers, and disposed of as by burial, and/or they can be sintered to collapse the pores thereof to disposal or for producing useful radiation sources. The porous glass or a porous silica gel having said silicon-bonded organofunctionalsiloxy groups and/or said hydrous polyvalent metal oxy groups, the pores of said glass or silica gel remaining open and uncollapsed, can be used advantageously as a backfill for an underground radioactive waste burial site and as overpack in the waste disposal container. Also included is a novel method for bonding the polyvalent metal to the porous silica glass or gel by substituting the protons of the silicon-bonded hydroxyl groups thereof with an alkali metal or ammonium cation followed by displacement of said cation with the non-radioactive polyvalent metal cation.

    Abstract translation: 本发明涉及在硅酸盐玻璃或硅胶基质中内部有毒的例如放射性物质固定极长时间。 含有放射性阴离子的放射性废物，以及在某些情况下，可能是液体形式的阳离子或溶解或分散在液体或气体中的固体的有毒材料内部加入到具有含水官能团的甲硅烷氧基的玻璃基质中，例如 ，含水氨基烷基甲硅烷氧基或羧基有机基甲硅烷氧基，通过涉及将所述有毒放射性阴离子与所述有机放射性阴离子的离子交换的方法，通过二价氧键键合到所述玻璃的硅原子和/或与所述玻璃的硅原子键合的含水多价金属， 连接到所述有机电致甲硅烷氧基基团的羟基或与水合多价金属连接的羟基的羟基。 此后，所得玻璃的特征在于内部结合或固定的，有毒的放射性阴离子的分布可以包装在合适的容器中，并通过埋置进行处理，和/或它们可以烧结以将其孔隙塌缩以处理或用于 生产有用的辐射源。 所述多孔玻璃或多孔硅胶具有所述与硅键合的有机铁氧基甲硅烷氧基和/或所述含水多价金属氧基，所述玻璃或硅胶的孔保持开放和未破裂，可有利地用作地下放射性废物的回填 垃圾处理容器内的包装物， 还包括一种通过用碱金属或铵阳离子取代与硅键合的羟基的质子，然后用非放射性多价金属置换所述阳离子来将多价金属键合到多孔石英玻璃或凝胶上的新方法 阳离子。

    Fixation by anion exchange of toxic materials in a glass matrix
    105.
    发明授权
    Fixation by anion exchange of toxic materials in a glass matrix 失效
    通过玻璃基质中有毒物质的阴离子交换固定

    公开(公告)号：US4333847A

    公开(公告)日：1982-06-08

    申请号：US65752

    申请日：1979-08-10

    Applicant: Danh C. Tran ,  Pedro B. Macedo ,  Joseph H. Simmons ,  Catherine J. Simmons ,  Nicholas Lagakos

    Inventor： Danh C. Tran ,  Pedro B. Macedo ,  Joseph H. Simmons ,  Catherine J. Simmons ,  Nicholas Lagakos

    IPC: G21F9/02 ,  G21F9/30 ,  G21F9/36 ,  G21F9/16

    CPC classification number: C03C1/002 ,  C03C1/026 ,  C03C11/005 ,  C03C21/001 ,  C03C23/0095 ,  C03C3/06 ,  C03C3/061 ,  C03C3/089 ,  G21F9/02 ,  G21F9/305 ,  G21F9/36 ,  C03C2201/10 ,  C03C2201/20 ,  C03C2201/23 ,  C03C2201/3411 ,  C03C2201/3423 ,  C03C2201/3429 ,  C03C2201/40 ,  C03C2201/42 ,  C03C2201/50 ,  C03C2201/54

    Abstract: This invention relates to the immobilization of toxic, e.g., radioactive materials, internally in a silicate glass or silica gel matrix for extremely long periods of time. Toxic materials, such as radioactive wastes containing radioactive anions, and in some cases cations, which may be in the form of liquids, or solids dissolved or dispersed in liquids or gases, are internally incorporated into a glass matrix, having hydrous organofunctionalsiloxy groups, e.g., hydrous aminoalkylsiloxy or carboxyorganosiloxy, bonded to silicon atoms of said glass and/or hydrous polyvalent metals bonded to silicon atoms of said glass through divalent oxygen linkages or otherwise immobilized therein, by a process which involves the ion exchange of said toxic, radioactive anions with hydroxyl groups attached to said organofunctionalsiloxy groups or with hydroxyl groups attached to the hydrous polyvalent metal. Thereafter, the resulting glass now characterized by a distribution of internally bonded or immobilized, toxic, radioactive anions can be packaged in suitable containers, and disposed of as by burial, and/or they can be sintered to collapse the pores thereof prior to disposal or for producing useful radiation sources. The porous glass or a porous silica gel having said silicon-bonded organofunctionalsiloxy groups and/or said hydrous polyvalent metal oxy groups, the pores of said glass or silica gel remaining open and uncollapsed, can be used advantageously as a backfill for an underground radioactive waste burial site and as overpack in the waste disposal container. Also included is a novel method for bonding the polyvalent metal to the porous silica glass or gel by substituting the protons of the silicon-bonded hydroxyl groups thereof with an alkali metal or ammonium cation followed by displacement of said cation with the non-radioactive polyvalent metal cation.

    Abstract translation: 本发明涉及在硅酸盐玻璃或硅胶基质中内部有毒的例如放射性物质固定极长时间。 含有放射性阴离子的放射性废物，以及在某些情况下，可能是液体形式的阳离子或溶解或分散在液体或气体中的固体的有毒材料内部加入到具有含水官能团的甲硅烷氧基的玻璃基质中，例如 ，含水氨基烷基甲硅烷氧基或羧基有机基甲硅烷氧基，通过涉及将所述有毒放射性阴离子与所述有机放射性阴离子的离子交换的方法，通过二价氧键键合到所述玻璃的硅原子和/或与所述玻璃的硅原子键合的含水多价金属， 连接到所述有机电致甲硅烷氧基基团的羟基或与水合多价金属连接的羟基的羟基。 此后，所得玻璃的特征在于内部结合或固定的，有毒的放射性阴离子的分布可以包装在合适的容器中，并且通过埋置进行处理和/或它们可以在处理之前烧结以使其孔隙塌缩，或 用于生产有用的辐射源。 所述多孔玻璃或多孔硅胶具有所述与硅键合的有机铁氧基甲硅烷氧基和/或所述含水多价金属氧基，所述玻璃或硅胶的孔保持开放和未破裂，可有利地用作地下放射性废物的回填 垃圾处理容器内的包装物， 还包括一种通过用碱金属或铵阳离子取代与硅键合的羟基的质子，然后用非放射性多价金属置换所述阳离子来将多价金属键合到多孔石英玻璃或凝胶上的新方法 阳离子。

    실리카 용기 및 그 제조 방법
    106.
    发明授权
    실리카 용기 및 그 제조 방법 有权
    二氧化硅船及其生产方法

    公开(公告)号：KR101333190B1

    公开(公告)日：2013-11-26

    申请号：KR1020117017618

    申请日：2010-10-19

    Applicant: 신에쯔 세끼에이 가부시키가이샤

    Inventor： 야마가타,시게루 ,  우스이,토모미

    IPC: C30B15/10 ,  C03B20/00 ,  C30B29/06

    CPC classification number: B65D13/02 ,  C03B19/095 ,  C03B2201/54 ,  C03C3/06 ,  C03C2201/54 ,  C30B15/10 ,  C30B29/06 ,  C30B35/002 ,  Y02P40/57

    Abstract: 본 발명은, Li, Na, K의 합계 농도가 50wt ppm 이하인 기체형성용 원료분말과, Ca, Sr, Ba를 합계 50~2000wt ppm으로 함유하는 내부층형성용 원료분말을 제작하고, 형틀 내에서 기체의 가성형체를 형성하고, 그 내부표면 상에 내부층의 가성형체를 형성하고, 수소 혹은 헬륨 또는 이들 혼합 가스를 10vol.%를 초과하는 비율로 함유하는 가스 분위기에서, 방전 가열 용융법에 의해 기체와 내부층의 가성형체의 내측으로부터 가열시킴으로써, 기체의 가성형체의 외주부분을 소결체로 함과 동시에, 기체의 가성형체의 내주부분 및 내부층의 가성형체를 용융 유리체로 함으로써, 외주부분에 기포를 함유하는 기체와, 이 기체의 내부표면 상에 형성된, 투명 실리카 유리로 이루어진 내부층을 갖는 실리카 용기를 제조하는 방법이다. 이에 따라, 고 치수정밀도, 고 내열성을 갖는 실리카 용기를 저비용으로 제조 가능한 실리카 용기의 제조 방법 및 이러한 실리카 용기가 제공된다.

    초저손실 실리카 유리 및 이를 사용한 광파이버
    107.
    发明公开
    초저손실 실리카 유리 및 이를 사용한 광파이버 失效
    超薄二氧化硅玻璃和使用其的光学纤维

    公开(公告)号：KR1020000023743A

    公开(公告)日：2000-04-25

    申请号：KR1019997000207

    申请日：1997-07-14

    Applicant: 도요타 지도샤(주) ,  각코호진 도요타가쿠엔

    Inventor： 사이토가즈야 ,  이쿠시마아키라

    IPC: C03C13/04

    CPC classification number: C03C13/046 ,  C03B37/014 ,  C03B2201/07 ,  C03B2201/30 ,  C03B2201/50 ,  C03B2201/54 ,  C03C3/06 ,  C03C2201/40 ,  C03C2201/50 ,  C03C2201/54 ,  G02B6/02

    Abstract: PURPOSE: An ultra-low loss glass having low Rayleigh scattering loss is provided which is excellent as the mother material of a glass fiber for long distance forwarding by doping impurities to a high purity glass. CONSTITUTION: An ultra low loss glass is obtained by doping at least one metallic oxide selected from Na2O, K2O, Li2O, MgO, CaO, PbO of 1- 500 wt, ppm to a high purity glass which loosen the tetrahedron network structure of silica. The resultant glass is used for the optical fiber due to low Rayleigh scattering compared with a pure silica glass.

    Abstract translation: 目的：提供具有低瑞利散射损耗的超低损耗玻璃，作为用于通过将杂质掺杂到高纯度玻璃的长距离转发的玻璃纤维的母材而言是优异的。 构成：通过将选自Na 2 O，K 2 O，Li 2 O，MgO，CaO，PbO的至少一种金属氧化物掺入到具有1-500重量ppm ppm的高纯度玻璃上，从而获得了超低损耗玻璃，该玻璃使二氧化硅的四面体网络结构松动。 与纯二氧化硅玻璃相比，所得玻璃由于低瑞利散射而用于光纤。

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