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公开(公告)号:MX2012001098A
公开(公告)日:2012-02-28
申请号:MX2012001098
申请日:2010-08-03
Applicant: BASF SE
Inventor: VORBERG GERALD , RIEMANN CHRISTIAN , KATZ TORSTEN , SIEDER GEORG , DENGLER ERIKA
Abstract: La invención se refiere a un medio de absorción para retirar gases ácidos de una corriente de fluidos que comprende una solución acuosa (A) de una sal de metal alcalino de un ácido N,N-di-C1-C4-alquilaminocarboxílico y (B) N-hidroxietilpiperazina. El medio de absorción tiene una presión de vapor baja y una mayor resistencia al oxígeno. Las corrientes de fluidos preferidas son gases de escape de combustión o biogas.
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公开(公告)号:AT531700T
公开(公告)日:2011-11-15
申请号:AT06763482
申请日:2006-06-02
Applicant: BASF SE
Inventor: SCHNEIDER JOERG , SCHERR GUENTER , EHRHARDT RAINER , EICHFELDER ANDREAS , REIF MARTIN , HIRSCH STEFAN , SIEDER GEORG , HOLTMANN THOMAS , CIPRIAN JUERGEN , ASCHERL HERMANN
IPC: C07D251/70
Abstract: Processes comprising: providing an alkanolic reaction mixture, the alkanolic reaction mixture comprising: at least one alkoxycarbonylaminotriazine; at least one carbonic ester; at least one C1-C13-alkanol, which alkanol may further comprise up to two ether-bound oxygen atoms and may further comprise a substituent selected from the group consisting of C1-C4-alkyls and hydroxyls; and at least one alkali metal alkoxide or alkaline earth metal alkoxide; and subjecting the alkanolic reaction mixture to extraction with a polar extractant such that at least a portion of polar/ionic components present in the reaction mixture are removed, wherein the polar extractant is less than entirely miscible with an organic phase of the reaction mixture, to form an alkanolic phase comprising the at least one alkoxycarbonylaminotriazine and a polar phase comprising the polar extractant and the portion of polar/ionic components; and wherein the extraction is carried out with one or more selected from the group consisting of mixer/settler units, columns, centrifugal field separation extractors, and combinations thereof.
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公开(公告)号:BRPI0806767A2
公开(公告)日:2011-09-13
申请号:BRPI0806767
申请日:2008-01-24
Applicant: BASF SE
Inventor: DIEFENBACHER ARMIN , HAMMON ULRICH , SCHLIEPHAKE VOLKER , SIEDER GEORG
IPC: C07C57/07 , C07C51/215 , C07C51/25 , C07C51/44 , C07C51/48
Abstract: A process for preparing acrylic acid, in which an acrylic acid-comprising product gas mixture obtained by catalytic gas phase partial oxidation of a C3 precursor of acrylic acid is fractionally condensed in a condensation column provided with internals ascending into itself with side draw removal of crude acrylic acid and with liquid phase draw removal of acrylic acid-comprising acid water, and acrylic acid present in acid water is taken up into an extractant and then removed from the extractant and recycled into the condensation column, or taken up in aqueous metal hydroxide, or sent to further purification of the crude acrylic acid.
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公开(公告)号:ZA200905851B
公开(公告)日:2011-04-28
申请号:ZA200905851
申请日:2009-08-24
Applicant: BASF SE
Inventor: SIEDER GEORG , DIEFENBACHER ARMIN , SCHLIEPHAKE VOLKER , HAMMON ULRICH
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公开(公告)号:ES2354087T3
公开(公告)日:2011-03-09
申请号:ES06763407
申请日:2006-05-31
Applicant: BASF SE
Inventor: HIRSCH STEFAN , REIF MARTIN , ASCHERL HERMANN , SIEDER GEORG , SCHNEIDER JORG , HOLTMANN THOMAS , CIPRIAN JURGEN , EICHFELDER ANDREAS , EHRHARDT RAINER , SCHERR GUNTER
IPC: C07D251/70
Abstract: Un método para la producción de alcoxicarbonilaminotriazina en polvo a partir de una mezcla de reacción alcanólica que resulta por la producción de alcoxicarbonilaminotriazinas, que contiene por lo menos unaalcoxicarbonilaminotriazina,por lo menos un éster cíclico y/o acíclico de ácido carbónico, por lo menos un alcanol C1-C13quedado el caso contiene uno o dos átomos de oxígeno como enlace éter, dado el caso sustituido por alquilo C1-C4 y/o hidroxi así como por lo menos alcanolato alcalino o alcalinotérreo, dado el caso melamina y dado el caso catalizador, donde la mezcla de reacción es nebulizada y secada en un secador por atomización.
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公开(公告)号:AT483696T
公开(公告)日:2010-10-15
申请号:AT06763407
申请日:2006-05-31
Applicant: BASF SE
Inventor: SCHNEIDER JOERG , SCHERR GUENTER , EHRHARDT RAINER , EICHFELDER ANDREAS , REIF MARTIN , HIRSCH STEFAN , SIEDER GEORG , HOLTMANN THOMAS , CIPRIAN JUERGEN , ASCHERL HERMANN
IPC: C07D251/70
Abstract: The invention relates to a process for preparing free-flowing, pulverulent alkoxycarbonylaminotriazine from an alkanolic reaction mixture which is obtained in the preparation of alkoxycarbonylaminotriazines and comprises at least one alkoxycarbonylaminotriazine, at least one cyclic and/or acyclic carbonic ester, at least one C1-C13-alkanol which optionally comprises one or two oxygen atoms in the form of ether bonds and is optionally substituted by C1-C4-alkyl and/or hydroxyl, and also at least one alkali metal or alkaline earth metal alkoxide, with or without melamine and with or without catalyst, by atomizing and drying the reaction mixture in a spray drier.
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公开(公告)号:CA2750458A1
公开(公告)日:2010-08-05
申请号:CA2750458
申请日:2010-01-27
Applicant: BASF SE
Inventor: VORBERG GERALD , KATZ TORSTEN , SIEDER GEORG , RIEMANN CHRISTIAN , WAGNER RUPERT , LICHFERS UTE , DENGLER ERIKA
Abstract: An absorbent for removing acidic gases from a fluid stream, comprising an aqueous solution a) of at least one metal salt of an amino carboxylic acid and b) of at least one acidic promoter, where the molar ratio of b) to a) is in the range from 0.0005 to 1Ø The acidic promoter is selected from mineral acids, carboxylic acids, sulfonic acids, organic phosphonic acids and partial esters thereof. The absorbent exhibits, compared to absorbents based on amino acid salts, a reduced requirement for regeneration energy, without significantly reducing the absorption capacity of the solution for acidic gases. In a process for removing acidic gases from a fluid stream, the fluid stream is contacted with the absorbent.
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118.
公开(公告)号:CA2726922A1
公开(公告)日:2009-12-30
申请号:CA2726922
申请日:2009-06-09
Applicant: BASF SE
Inventor: LICHTFERS UTE , THIELE ROBIN , VOGES SUSANNA , SIEDER GEORG , SPUHL OLIVER , GARCIA ANDARCIA HUGO RAFAEL
Abstract: Absorption medium for sour gases, comprising an oligoamine (A) of the general formula (I) and a primary or secondary alkanol amine (B) of the general formula (II), in which the weight ratio of oligoamine (A) to primary or secondary alkanol amine (B) is 0.2 to 4, and a method for removing sour gases from a gas stream by contacting the gas stream at a pressure of 0.05 to 10 MPa abs with an aqueous solution of said absorption medium, said solution being temperature-controlled at a temperature of 20 to 80°C.
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公开(公告)号:DE102007055086A1
公开(公告)日:2009-05-20
申请号:DE102007055086
申请日:2007-11-16
Applicant: BASF SE
Inventor: DIEFENBACHER ARMIN , HAMMON ULRICH , SCHLIEPHAKE VOLKER , SIEDER GEORG
Abstract: A 3C or more of precursor is subjected to heterogeneously catalyzed gas phase partial oxidation with molecular oxygen in solid-state catalyst to obtain product gas mixture. The product gas mixture is reduced by direct cooling, passed into a condensation column, and crude acrylic acid is conducted, and acid water is disposed. A residual gas mixture is recycled, and crude acrylic acid is subjected to thermal separation process. The acrylic acid is taken in organic solvent to form organic extract, and thermal separation processed to form acrylic acid. A 3C or more of precursor is subjected to heterogeneously catalyzed gas phase partial oxidation with molecular oxygen in solid-state catalyst at elevated temperature to obtain product gas mixture comprising acrylic acid, steam and secondary components. The product gas mixture is reduced by direct/indirect cooling, passed into a condensation column equipped with separating internals, allowed to ascend into the condensation column, and fractionally condensed. The crude acrylic acid comprising water and secondary components, is conducted as the target product from the condensation column through a side draw (A1) disposed above the feed point of the product gas mixture into the condensation column, and acid water comprising acrylic acid and secondary components is disposed above the side draw (A1) through a liquid phase draw (A2). A residual gas mixture comprising secondary components having lower boiling points than water at the top of the condensation column and a bottoms liquid comprising acrylic acid and conversion products, and secondary components having higher boiling points than acrylic acid from the bottom space of the condensation column, is recycled after cooling with reflux liquid, into the condensation column, and the crude acrylic acid is subjected to thermal separation process and purified. The acrylic acid in a portion of acid water not recycled into the condensation column is taken up from the acid water into an organic solvent by extraction with the organic solvent to form an organic extract comprising acrylic acid. The acrylic acid is removed from the organic extract using thermal separation process, and the acrylic acid removed from the extract is recycled into the condensation column into the aqueous solution of a metal hydroxide. Thus, acrylic acid is manufactured.
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公开(公告)号:ES2952010T3
公开(公告)日:2023-10-26
申请号:ES20703790
申请日:2020-02-14
Applicant: BASF SE
Inventor: ERNST MARTIN , INGRAM THOMAS , VORBERG GERALD , SIEDER GEORG
Abstract: Un proceso para eliminar gases ácidos de una corriente de fluido, en el que la corriente de fluido se pone en contacto con un absorbente para obtener una corriente de fluido tratada y un absorbente cargado, comprendiendo el absorbente un diluyente y un compuesto de fórmula general (I) en la que R1 se selecciona entre alquilo C1-C8 e hidroxialquilo C2-C8; R2 se selecciona entre hidrógeno y alquilo C1-C8; R3 se selecciona entre hidrógeno y alquilo C1-C8; R4 se selecciona entre hidrógeno y alquilo C1-C8; R5 es alquilo C1-C8; con la condición de que se cumpla al menos una de las siguientes condiciones (i) y (ii): (i) R5 es alquilo C3-C8 unido al átomo de nitrógeno a través de un átomo de carbono secundario o terciario; (ii) cuando R4 es hidrógeno, R3 es alquilo C1-C8; o cuando R4 es alquilo C1-C8, al menos uno de R2 y R3 es alquilo C1-C8; y n es un número entero de 0 a 6. Además se proporciona un absorbente para la absorción de gases ácidos de una corriente de fluido, que comprende un diluyente y un compuesto de fórmula general (I) como se define anteriormente, así como el uso de un compuesto de fórmula general (I) como se define anteriormente para la eliminación de gases ácidos de una corriente de fluido. Los absorbentes son útiles para la eliminación selectiva de sulfuro de hidrógeno de corrientes de fluidos y tienen alta capacidad de carga de gas ácido, alta estabilidad y baja volatilidad. (Traducción automática con Google Translate, sin valor legal)
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