公开(公告)号：DE4039918A1

公开(公告)日：1992-06-17

申请号：DE4039918

申请日：1990-12-14

Applicant: BASF AG

Inventor： BRENNER KARL ,  GOETZ NORBERT ,  HENKELMANN JOCHEM DR ,  KUEKENHOEHNER THOMAS DR ,  SPIEGLER WOLFGANG DR

IPC: B01J23/48 ,  B01J23/72 ,  C07B61/00 ,  C07D309/06

Abstract: Disclosed is a method for the preparation of formyltetrahydropyrans (I) by dehydrogenating hydroxymethyltetrahydropyrans (II) in the presence of a copper, silver and/or gold catalyst. The formyltetrahydropyrans (I) thus obtained are useful intermediates in the preparation of pharmaceuticals and phytopathalogical products.

公开(公告)号：DE58901104D1

公开(公告)日：1992-05-14

申请号：DE58901104

申请日：1989-01-30

Applicant: BASF AG

Inventor： ZIPPLIES MATTHIAS DR ,  SAUTER HUBERT DR ,  ROEHL FRANZ DR ,  KUEKENHOEHNER THOMAS DR ,  JANITSCHKE LOTHAR DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR

IPC: C07D295/02 ,  A01N43/60 ,  C07D295/00 ,  C07D295/03 ,  C07D295/033 ,  C07D295/067 ,  C07D295/08

Abstract: N,N'-disubstituted piperazines of the general formula I (1) where the group is unsaturated (=) or saturated (-) and the substituents R1, R2 and A have the following meanings: A is -, -CH=, -CH2-, -CH2-CH2-, R1 is alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, alkylcycloalkyl, cycloalkenylalkyl, alkylcycloalkenyl, bicycloalkyl, bicycloalkylalkyl or alkylbicycloalkyl, these radicals being unsubstituted or substituted by hydroxy, halogen, alkoxy or trialkylsilyl, R1 is further heterocycloalkyl with oxygen and/or sulfur, heterocycloalkylmethyl with oxygen and/or sulfur, alkyl-substituted heterocycloalkylmethyl with oxygen and/or sulfur, and R2 is alkyl, alkoxy, trimethylsilyl, cycloalkyl, alkylthio, and plant-physiologically tolerated salts thereof, and fungicides containing these compounds.

公开(公告)号：DE4028391A1

公开(公告)日：1992-03-12

申请号：DE4028391

申请日：1990-09-07

Applicant: BASF AG

Inventor： KIRSTGEN REINHARD DR ,  HARREUS ALBRECHT DR ,  KARDORFF UWE DR ,  KUEKENHOEHNER THOMAS DR ,  RANG HARALD DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  KUENAST CHRISTOPH DR

IPC: A01N37/36 ,  A01N37/38 ,  A01N43/10 ,  A01N43/40 ,  A01N43/50 ,  C07C69/734 ,  C07C69/736 ,  C07C205/56 ,  C07C255/54 ,  C07C255/57 ,  C07C323/20 ,  C07C323/62 ,  C07D213/55 ,  C07D233/60 ,  C07D237/08 ,  C07D237/16 ,  C07D239/54 ,  C07D241/12 ,  C07D241/24 ,  C07D249/00 ,  C07D249/06 ,  C07D261/08 ,  C07D277/20 ,  C07D277/30 ,  C07D307/54 ,  C07D333/24

Abstract: alpha -Arylacrylic acid derivatives of the general formula I in which the substituents and indices have the following meanings: X is ethylene or ethenylene; Y is a direct bond or oxygen; R is an optionally substituted aromatic or heteroaromatic system with one or two rings; R is cyano, nitro, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or haloalkylthio; n is 1 or 2, it being possible for the radicals to differ if n denotes 2; m is 0, 1 or 2, it being possible for the radicals to differ if m denotes 2, with the proviso that R does not denote phenyl when n is 1 and m is 0, their preparation, insecticidal and fungicidal agents containing them, and methods of using them.

公开(公告)号：DE4024281A1

公开(公告)日：1992-02-06

申请号：DE4024281

申请日：1990-07-31

Applicant: BASF AG

Inventor： RENTZEA COSTIN DR ,  KARDORFF UWE DR ,  KUENAST CHRISTOPH DR ,  THEOBALD HANS DR ,  KUEKENHOEHNER THOMAS DR

IPC: A01N43/10 ,  A01N43/78 ,  C07D277/22 ,  C07D277/24 ,  C07D333/08 ,  C07D333/12 ,  C07D333/16 ,  C07D333/24 ,  C07D333/28

Abstract: Acetylene derivatives of the formula I R -C IDENTICAL C-R I in which the substituents have the following meanings: R is an optionally substituted five-membered heteroaromatic, R is an optionally substituted aromatic ring system containing one to three rings, their preparation, agents containing them for controlling insects and acarids, and their use.

公开(公告)号：DE4020432A1

公开(公告)日：1992-01-02

申请号：DE4020432

申请日：1990-06-27

Applicant: BASF AG

Inventor： SEELE RAINER DR ,  GOETZ NORBERT DR ,  KUEKENHOEHNER THOMAS DR ,  KEIL MICHAEL DR ,  KOBER REINER DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

IPC: A01N43/50 ,  A01N43/653 ,  C07D233/64 ,  C07D249/08 ,  C07D303/04 ,  C07D303/08 ,  C07D303/22 ,  C07D303/34 ,  C07D405/06 ,  C07D405/08 ,  C07D407/04 ,  C07D407/06 ,  C07D493/10 ,  C07D521/00

Abstract: (A)Azolylmethyl-substd. cyclic alcohols of formula (I) and their acid-addn. salts and metal complexes are new. X= CH or N; T= (CH2)n, CR11R12, O or S; n= 1-5; R1 and R5= H or 1-4C alkyl, or CR1R5= C=CHR7 or CHZR'7; Z=CH2, O, SO, SO, SO2 or NR8; R7= (a) 1-8C alkyl, phenyl, biphenylyl, naphthyl, benzyl or 3-8C cycloalkyl, all opt. substd. by 1-3 of halogen, NO2, OPh, NH2, 1-4C alkyl, 1-4C alkoxy, or 1-4C haloalkyl, or (b) tetrahydropyranyl; R'7= H or R7; R2 and R3= H or 1-4C alkyl, or CR2R3 may be C=CHR7 when CR1R5 is C=CHR7; R4 and R8= H or 1-4C alkyl; or R3+R4 completes a satd. or unsatd. 5-6C carbocyclic ring; R6 and R9-R12= 1-8C alkyl, phenyl, biphenylyl, naphthyl, heteroaryl, benzyl, dioxolanyl or 3-8C cycloalkyl, all opt. substd. by 1-3 of halogen, NO2, OPh, NH2, 1-4C alkyl, 1-4C alkoxy or 1-4C haloalkyl; or R2+R3+R4+R9 completes an opt. halo-substd. benzene ring; etc.

公开(公告)号：DE4020072A1

公开(公告)日：1992-01-02

申请号：DE4020072

申请日：1990-06-23

Applicant: BASF AG

Inventor： MAYWALD VOLKER DR ,  DITRICH KLAUS DR ,  KUEKENHOEHNER THOMAS DR ,  HAMPRECHT GERHARD DR ,  FREUND WOLFGANG DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR

IPC: A01N43/90 ,  C07D498/04 ,  C07D513/04

Abstract: Dicarboximides of formulae (Ia) and (Ib) and their salts are new. In the formulae, X = O or S; R1 = H; halo; 1-6C alkyl opt. mono- to penta-substd. by halogen and/or mono- or disubstd. by cyclopropyl, 1-4C alkoxy, etc or cyano; phenyl or phenyl-1-4C alkyl opt. mono-, di- or trisubstd. in the ring by 1-6C alkyl, 1-6C haloalkyl, etc 3-8C cycloalkyl opt. mono-, di- or trisubstd. by 1-4C alkyl or halogen; 2-6C alkenyl or 2-6C alkynyl opt. mono-, di- or trisubstd. by halogen or 1-3C alkoxy and/or monosubstd. by A; opt. halo-substd. 1-4C alkoxy or 1-4C alkylthio; OA; SA; or a 5-or 6- membered satd. or aromatic heterocyclic gp. contg. 1 or 2 N, S and/or O atoms and opt. mono- or disubstd. by 1-3C alkyl, halogen 1-3C alkoxy or 1-3C alkoxycarbonyl; R2 = H; OH; 1-4C alkoxy; 1-6C alkyl opt. mono-, di- or trisubstd. by cyano, 1-4C alkoxy-1-4C alkoxy, 1-4C alkoxy, 3-8C or A; 3-8C cycloalkyl opt. mono- di- or trisubstd. by 1-6C alkyl, 1-6C haloalkyl, 1-4C alkoxy etc; 3-6C alkenyl or 3-6C alkynyl opt. mono-, di- or trisubstd. by halogen and/or monosubstd. by A; di(1-4C alkyl)amino; or a 5- or 6-membered satd. or aromatic heterocyclic gp. contg. 1 or 2 N, S and/or O atoms and opt. mono-, di- or trisubstd. by 1-4C alkyl or halogen; or 1-4C alkoxycarbonyl; or naphthyl opt. mono-, di- or trisubstd. by 1-4C alkyl or halogen; A = phenyl opt. mono-, di- or trisubstd. by 1-4C alkyl, 1-4C haloalkyl, 1-4C alkoxy, 1-4C haloalkoxy, 1-4C alkylthio, 1-4C haloalkylthio, halogen, cyano or nitor; except 3-methylisoxazole-4,5-dicarboximide (Ic). USE - Cpds (Ia) and (Ib) are pre- and post-emergence herbicides and plant growth regulators. (Ia) and (Ib) are applied e.g. at a rate of 0.01-3 kg/ha.

公开(公告)号：DE4018623A1

公开(公告)日：1991-12-12

申请号：DE4018623

申请日：1990-06-11

Applicant: BASF AG

Inventor： MISSLITZ ULF DR ,  MEYER NORBERT DR ,  KAST JUERGEN DR ,  GOETZ NORBERT DR ,  HARREUS ALBRECHT DR ,  KUEKENHOEHNER THOMAS DR ,  WUERZER BRUNO DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR

IPC: A01N43/10 ,  A01N43/14 ,  C07D213/30 ,  C07D307/42 ,  C07D333/16 ,  C07D405/12 ,  C07D407/12 ,  C07D409/12

Abstract: Cyclohexenone oxime ether derivs. of formula (I) their salts and esters with 1-10C carbonic acids or inorganic acids are new. R1 = 1-6C alkyl; A = 2-6C alkylene or 3-6C alkenylene both opt. substd. by 1-3 1-3C alkyl and/or halo; Z = 5-membered heteroaromatic ring with 1-3 N and/or O or S; or a 6-membered heteroaromatic ring contg. 1-4 N; X = NRaRb; Ra = H, 1-4C alkyl, 3-6C alkenyl or 3-6C alkynyl; Rb = H, 1-4C alkyl, 3-6C alkenyl, 3-6C alkynyl, 1-6C acyl or benzoyl opt. ring substd. by 1-3 NO2, CN, halo, 1-4C alkyl, 1-4C alkoxy, 1-4C alkylthio and/or 1-4C haloalkyl, NO2, CN, halo, 1-4C (halo)alkyl, 1-4C (halo)alkoxy, 1-4C alkylthio, COOH, 1-4C alkoxycarbonyl, benzyloxycarbonyl and/or phenyl opt. ring substd. by 1-3C carbonyl or benzyloxy carbonyl; n = 0-3 or 1-4 when Z = halopyridyl; R2 = (1-4C)alkoxy(1-6C)alkyl or (1-4C)alkylthio(1-6C)alkyl; 3-7C cycloalkyl or 5-7C cycloalkenyl opt. substd. by 1-4C (halo)alkyl, 1-4C alkoxy, 1-4C alkylthio, OH and/or halo; 5-membered satd. heterocycle contg. 1 or 2 O and/or S and opt. carrying 1-3 1-4C (halo)alkyl, 1-4C alkoxy and/or 1-4C alkylthio, a 6- or 7-membered heterocycle contg. 1 or 2 O and/or S and 1 or 2 double bonds and opt. substd. by 1-3 OH, halo, 1-4C (halo)alkyl, 1-4C alkoxy and/or 1-4C alkylthio; 5-membered heteroaromatic ring contg. 1-2 N and 1 O or S opt. substd. by 1-3 halo, CN, 1-4C (halo)alkyl, 1-4C alkoxy, 1-4C alkylthio, 2-6C (halo)alkenyl, 2-6C alkenyloxy and/or (1-4C)alkoxy-(1-4C)alkyl; phenyl or pyridyl opt. substd. by 1-3 halo, NO2, CN, 1-4C(halo)alkyl, 1-4C alkoxy, 1-4C alkylthio, 3-6C alkenyloxy, 3-6C alkynyloxy, 1-4C-alkoxy (1-4C)alkyl and/or NRaRb. Setaria viridis.

公开(公告)号：DE3932915A1

公开(公告)日：1991-04-11

申请号：DE3932915

申请日：1989-10-03

Applicant: BASF AG

Inventor： KUEKENHOEHNER THOMAS DR ,  THEOBALD HANS DR ,  GOETZ NORBERT DR ,  DITRICH KLAUS DR ,  STEINIGER MICHAEL DR

IPC: A01N43/80 ,  C07C69/606 ,  C07C251/36 ,  C07C251/48 ,  C07D261/18 ,  C07D413/04

公开(公告)号：DE3927382A1

公开(公告)日：1991-02-21

申请号：DE3927382

申请日：1989-08-19

Applicant: BASF AG

Inventor： RHEINHEIMER JOACHIM DR ,  EICKEN KARL DR ,  VOGELBACHER UWE JOSEF DR ,  ROHR WOLFGANG DR ,  KUEKENHOEHNER THOMAS DR ,  WESTPHALEN KARL-OTTO DR ,  WUERZER BRUNO DR

IPC: C07D251/30 ,  A01N43/54 ,  A01N43/64 ,  A01N43/66 ,  A01N43/80 ,  A01N43/82 ,  A01N43/836 ,  C07D239/52 ,  C07D239/60 ,  C07D251/22 ,  C07D251/34 ,  C07D251/38 ,  C07D401/12 ,  C07D401/14 ,  C07D413/12 ,  C07D413/14 ,  C07D417/12 ,  C07D417/14

Abstract: Carboxylic acid derivatives of the general formula I I where R1 and R2 are each C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and/or C1-C4-alkylthio; R3 is hydrogen, hydroxyl, cyano, nitro, formyl, halogen, unsubstituted or substituted amino, C1-C4-alkyl, C1-C4-alkoxy, C3-C6-alkenyl, C3-C6-alkenyloxy, C3-C6-alkynyl or C3-C6-alkynyloxy; R4 is hydrogen or C1-C4-alkyl; R5 is unsubstituted or substituted five-membered hetaryl or isoxazolinyl or -CR6=NOR7; R6 is hydrogen or unsubstituted or substituted C1-C4-alkyl, C3-C8-cycloalkyl or phenyl; R7 is unsubstituted or substituted C1-C4-alkyl, C3-C6-alkenyl, C3-C8-cycloalkyl or phenyl; A is oxygen or sulfur; X is nitrogen or methine =CR8-; R8 is one of the radicals R3, or R8 and R3 together form unsubstituted or substituted 1,3-butadiene-1,4-yl or aza-1,3-butadiene-1,4-yl, and Y and Z are each nitrogen or methine =CH-, their preparation and agents containing them.

公开(公告)号：DE4007923A1

公开(公告)日：1990-09-27

申请号：DE4007923

申请日：1990-03-13

Applicant: BASF AG

Inventor： KUEKENHOEHNER THOMAS DR ,  GOETZ NORBERT DR

IPC: C07C45/30 ,  C07C47/542 ,  C07C47/546 ,  C07C47/55

Abstract: Prepn. of substd. benzaldehydes (I) comprises the liq. phase oxidn. of a benzyl alcohol (II) using an inorganic or organic hypochlorite or hypobromite and a morpholine, pyrrolidine or piperidine deriv. (III). R1 = methyl, ethyl, F, Cl or Br; R2 = 1-12C alkyl, or 3-8C cycloalkyl or 6-12C bicycloalkyl opt. mono-, di- or trisubstd. by 1-5C alkyl; Alk=. 1-4C alkyl; Q = =N(+)=OX(-), =N-OH or =N-O; X- = anion; n = 0 or 1; Y = O, CO or =C(R3)(R4); R3, R4 = H, OH or a C- and/or O- organic gp., which can be joined to a 5- or 6- membered ring. Also claimed is the in situ prepn. of cpds. (III) from a corresp. morpholine, pyrrolidine and piperidine and an oxidising agent. Pref. the reaction is carried out in the presence of alkali metal, alkaline earth metal and/or ammonium bromides. The liq. phase is a two-phase aq.-organic system, esp. one in which the aq. phase has a pH or 5-10. USE/ADVANTAGE - Cpds. (I) are intermediates for plant protectants, e.g. pyrethroid derivs. Compared with known processes the new process is industrially applicable, economical and gives cpds. (I) in high yields of up to 85%.