公开(公告)号：AU2003214061A1

公开(公告)日：2003-09-09

申请号：AU2003214061

申请日：2003-02-17

Applicant: BASF AG

Inventor： WALSDORFF CHRISTIAN ,  SCHINDLER GOTZ-PETER ,  HARTH KLAUS ,  HIBST HARTMUT

IPC: C07C2/46 ,  C07B61/00 ,  C07C2/52 ,  C07C5/367 ,  C07C13/20 ,  C07C15/073 ,  C07C15/46

Abstract: The invention relates to a process for preparing 4-vinylcyclohexene, which comprises the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into at least one dehydrogenation zone and dehydrogenating n-butane to butadiene to give a product stream comprising butadiene, n-butane, possibly 1-butene and 2-butene and possibly water vapor and other secondary constituents, (C) feeding the product stream from dehydrogenation, if appropriate after separating off water vapor and secondary constituents, into a dimerization zone and catalytically dimerizing butadiene to give a product stream comprising 4-vinylcyclohexene, n-butane and possibly 1-butene, 2-butene and unreacted butadiene, and (D) separating off 4-vinylcyclohexene from the product stream from the dimerization and recirculating n-butane and possibly 1-butene, 2-butene and unreacted butadiene to the dehydrogenation zone.

公开(公告)号：AT238240T

公开(公告)日：2003-05-15

申请号：AT99971784

申请日：1999-11-10

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUER STEFAN ,  DIETRICH ULF

IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G1/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31

Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O,  I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.

公开(公告)号：DE10119933A1

公开(公告)日：2002-10-24

申请号：DE10119933

申请日：2001-04-23

Applicant: BASF AG

Inventor： BORGMEIER FRIEDER ,  TENTEN ANDREAS ,  HIBST HARTMUT ,  MUELLER-ENGEL KLAUS JOACHIM ,  UNVERRICHT SIGNE ,  COX GERHARD

IPC: B01J23/00 ,  B01J23/28 ,  B01J27/057 ,  B01J37/02 ,  C07C45/33 ,  C07C45/35 ,  C07C57/05

Abstract: Acrolein and acrylic acid are produced from propane and propene by absorption/desorption of propane and propene from a gas mixture followed by oxidation, in which no heterogeneously catalyzed dehydrogenation of propane occurs between the desorption and oxidation stages without addition of oxygen. Acrolein and acrylic acid are produced from propane and propene by: (a) separation of propane and propene from a gas mixture (A) by absorption in an absorption medium; (b) separation of propane and propene from the absorbent to give a mixture (B) containing propane and propene; and (c) using mixture (B) for oxidation to the required product(s). In this process, no catalytic dehydrogenation of propane without the addition of oxygen is carried out between stages (b) and (c).

公开(公告)号：BR0016290A

公开(公告)日：2002-08-13

申请号：BR0016290

申请日：2000-12-11

Applicant: BASF AG

Inventor： BITTERLICH STEFAN ,  VOSS HARTWIG ,  HIBST HARTMUT ,  TENTEN ANDREAS ,  VOIGT INGOLF ,  PIPPARDT UTE

IPC: C07D307/60 ,  B01D69/04 ,  B01D69/06 ,  B01D69/12 ,  B01D71/02 ,  B01J20/28 ,  B01J23/00 ,  B01J23/34 ,  B01J27/198 ,  B01J35/02 ,  B01J35/06 ,  C07B41/00 ,  C07B61/00 ,  C07C5/48 ,  C07C45/35 ,  C07C45/38 ,  C07C51/215 ,  C07C51/25 ,  C07C51/265 ,  C07C253/24 ,  C07C253/26 ,  C07C253/28 ,  C07D307/89 ,  B01J35/00

Abstract: Reactor membranes advantageously useful in oxidation reactions of hydrocarbons involving oxygen comprise a selective oxidation catalyst on a mixed conducting, oxide ion selective ceramic membrane of the composition (Sr1-xCax)1-yAyMn1-zBzO3-delta, where A is Ba, Pb, Na, K, Y, an element of the lanthanide group or a combination thereof, B is Mg, Al, Ga, In, Sn, an element of the 3d or 4d period or a combination thereof, x is from 0.2 to 0.8, y is from 0 to 0.4, z is from 0 to 0.6, and delta is a number, dependent on x, y and z, that renders the composition charge neutral.

公开(公告)号：DE10046672A1

公开(公告)日：2002-03-28

申请号：DE10046672

申请日：2000-09-20

Applicant: BASF AG

Inventor： BORGMEIER FRIEDER ,  TENTEN ANDREAS ,  HIBST HARTMUT ,  MUELLER-ENGEL KLAUS ,  UNVERRICHT SIGNE ,  COX GERHARD

IPC: B01J23/00 ,  B01J23/28 ,  B01J27/057 ,  B01J37/02 ,  C07C45/33 ,  C07C45/35 ,  C07C57/05 ,  B01J23/18 ,  B01J23/22 ,  B01J27/02

Abstract: Acrolein and acrylic acid are produced from propane and propene by absorption/desorption of propane and propene from a gas mixture followed by oxidation, in which no heterogeneously catalyzed dehydrogenation of propane occurs between the desorption and oxidation stages without addition of oxygen. Acrolein and acrylic acid are produced from propane and propene by: (a) separation of propane and propene from a gas mixture (A) by absorption in an absorption medium; (b) separation of propane and propene from the absorbent to give a mixture (B) containing propane and propene; and (c) using mixture (B) for oxidation to the required product(s). In this process, no catalytic dehydrogenation of propane without the addition of oxygen is carried out between stages (b) and (c).

公开(公告)号：DE10034825A1

公开(公告)日：2002-01-31

申请号：DE10034825

申请日：2000-07-18

Applicant: BASF AG

Inventor： BORGMEIER FRIEDER ,  TENTEN ANDREAS ,  HIBST HARTMUT ,  MUELLER-ENGEL KLAUS JOACHIM ,  UNVERRICHT SIGNE ,  COX GERHARD

IPC: B01J23/00 ,  B01J23/28 ,  B01J27/057 ,  B01J37/02 ,  C07C45/33 ,  C07C45/35 ,  C07C57/05 ,  B01J23/16

Abstract: Acrolein and acrylic acid are produced from propane and propene by absorption/desorption of propane and propene from a gas mixture followed by oxidation, in which no heterogeneously catalyzed dehydrogenation of propane occurs between the desorption and oxidation stages without addition of oxygen. Acrolein and acrylic acid are produced from propane and propene by: (a) separation of propane and propene from a gas mixture (A) by absorption in an absorption medium; (b) separation of propane and propene from the absorbent to give a mixture (B) containing propane and propene; and (c) using mixture (B) for oxidation to the required product(s). In this process, no catalytic dehydrogenation of propane without the addition of oxygen is carried out between stages (b) and (c).

公开(公告)号：ID30386A

公开(公告)日：2001-11-29

申请号：ID20011041

申请日：1999-11-10

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUIER STEFAN ,  DIETRICH ULF

IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G1/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31

Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O,  I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.

公开(公告)号：CZ20011626A3

公开(公告)日：2001-09-12

申请号：CZ20011626

申请日：1999-11-10

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUER STEFAN ,  DIETRICH ULF

IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G1/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  C01G5/00

Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O,  I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.

公开(公告)号：MXPA01004078A

公开(公告)日：2001-08-01

申请号：MXPA01004078

申请日：1999-11-10

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUER STEFAN ,  DIETRICH ULF

IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G1/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31

公开(公告)号：NO20012273A

公开(公告)日：2001-07-10

申请号：NO20012273

申请日：2001-05-09

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUER STEFAN ,  DIETRICH ULF

IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  C01G1/00 ,  C01G5/00

CPC classification number: B01J23/682 ,  B01J23/683 ,  C01G31/00 ,  C01G31/006 ,  C01G39/006 ,  C01P2002/50 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/77 ,  C01P2004/10 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2004/80 ,  C01P2006/12 ,  C01P2006/60 ,  C01P2006/80 ,  C01P2006/82 ,  C07C51/265 ,  C07C51/313 ,  C07C63/16