公开(公告)号：PL195428B1

公开(公告)日：2007-09-28

申请号：PL36133397

申请日：1997-08-06

Applicant: BASF AG

Inventor： BARTH THOMAS ,  RIEBER NORBERT ,  GOLD RANDALL EVAN ,  DRESSEL JUERGEN ,  ERHARDT KLAUS ,  HORCHLER VON LOCQUENGH KLAUS ,  LEIBOLD EDGAR ,  RITTINGER STEFAN

IPC: C05F3/00 ,  C05G3/00 ,  C05G3/90 ,  C05G5/00 ,  C07D231/12 ,  C07D231/16 ,  C07D321/12 ,  C07D521/00

Abstract: The use of inorganic or organic poly acids is claimed for treating mineral fertilisers containing a nitrification inhibitor. The use of compounds of formula (I) is claimed as nitrification inhibitors. R1 = H, halo or 1-4C alkyl; R2 = 1-4C alkyl; R3 = H or CH2OH, and when R3 = H, the compound may be converted to a phosphoric acid salt. A mineral fertiliser containing a poly acid and optionally (I) is also claimed. 3,4-dimethylpyrazole (Ia), 4-chloro-3-methyl-pyrazole (Ib), N-hydroxymethyl-3,4-dimethylpyrazole (Ic), N-hydroxymethyl-4-chloro-3-methylpyrazole (Id), acid addition salts of (Ic) and (Id), and mixtures of two or more of (Ia)-(d) are new.

公开(公告)号：SA1477B1

公开(公告)日：2006-10-29

申请号：SA01220361

申请日：2001-09-12

Applicant: BASF AG

Inventor： TELES JOAQUIM HENRIQUE ,  REHFINGER ALWIN ,  BERG ANNE ,  RUDOLF PETER ,  RIEBER NORBERT ,  BABLER PETER

IPC: C07D20060101 ,  C07D301/12 ,  C07D301/32 ,  C07D303/04

Abstract: الملخص: عمليةلتحضيرأكسيدالبروبيلين propylene oxide فيها:(i) يتمتفاعلالبروبين propene معفوقأكسيدالهيدروجين hydrogen peroxide فيوجودالميثانول methanol ليعطيأكسيدبروبيلين propylene oxide،حيثينتجمخلوط (Gi) يتضمنعلىأكسيدبروبيلين،propylene oxide ميثانول methanol،ماءوفوقأكسيدهيدروجين hydrogen peroxide غيرمتفاعل،(ii) يتمفصلمخلوط (Gii) يتضمنعلىميثانول methanol،ماءوفوقأكسيدالهيدروجين hydrogen peroxide منالمخلوط (Gi)،لينتجمخلوط (Ga) يتضمنعلىأكسيدالبروبيلين propylene oxide،وiii)) يتمفصلالماءمنالمخلوط (Gi) لينتجمخلوط (Giii) يتضمنعلىميثانول methanol وفورماتالمثيل methyl formate.

公开(公告)号：DE50204869D1

公开(公告)日：2005-12-15

申请号：DE50204869

申请日：2002-02-06

Applicant: BASF AG

Inventor： TELES HENRIQUE ,  REHFINGER ALWIN ,  BERG ANNE ,  RUDOLF PETER ,  RIEBER NORBERT ,  BASSLER PETER

IPC: C07D301/12 ,  C07D301/19 ,  C07D301/32 ,  C07D303/04

Abstract: An organic compound having at least one C-C double bond is epoxidized by means of hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent, wherein a product mixture comprising alpha-hydroperoxyalcohols is reduced using at least one reducing agent. The process advantageously comprises at least the following steps: (i) reacting an organic compound having at least one C-C double bond with hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent to give a product mixture P1 comprising alpha-hydroperoxyalcohols; (ii) separating an epoxide formed in the reaction in step (i) and the unreacted organic compound having at least one C-C double bond from P1 or P1' to give a product mixture P2 or P2', where P2 comprises the alpha-hydroperoxyalcohols formed as by-product in the reaction in step (i) and P2' is largely free of alpha-hydroperoxyalcohols; (iii) treating P1 and/or P2 with at least one reducing agent so that the alpha-hydroperoxyalcohols are converted into corresponding glycols to give a product mixture P1' or P3.

公开(公告)号：DE50104409D1

公开(公告)日：2004-12-09

申请号：DE50104409

申请日：2001-07-05

Applicant: BASF AG

Inventor： TELES HENRIQUE ,  REHFINGER ALWIN ,  BASSLER PETER ,  BERG ANNE ,  RIEBER NORBERT ,  RUDOLF PETER

IPC: C07D20060101 ,  C07D301/12 ,  C07D301/32 ,  C07D303/04

Abstract: A process for the preparation of propylene oxide in which (i) propene is reacted with hydrogen peroxide in the presence of methanol to give propylene oxide, giving a mixture (Gi) comprising propylene oxide, methanol, water and unreacted hydrogen peroxide, (ii) a mixture (Gii) comprising methanol, water and hydrogen peroxide is separated off from the mixture (Gi), giving a mixture (Ga) comprising propylene oxide, and (iii) water is separated off from the mixture (Gii), giving a mixture (Giii) comprising methanol and methyl formate.

公开(公告)号：ES2217046T3

公开(公告)日：2004-11-01

申请号：ES01105436

申请日：1997-08-06

Applicant: BASF AG

Inventor： BARTH THOMAS ,  RIEBER NORBERT ,  GOLD RANDALL EVAN ,  DRESSEL JUERGEN ,  ERHARDT KLAUS ,  RITTINGER STEFAN

IPC: C05F3/00 ,  C05G3/00 ,  C05G3/90 ,  C05G5/00 ,  C07D231/12 ,  C07D231/16 ,  C07D321/12 ,  C07D521/00 ,  C05G3/08

Abstract: The use of inorganic or organic poly acids is claimed for treating mineral fertilisers containing a nitrification inhibitor. The use of compounds of formula (I) is claimed as nitrification inhibitors. R1 = H, halo or 1-4C alkyl; R2 = 1-4C alkyl; R3 = H or CH2OH, and when R3 = H, the compound may be converted to a phosphoric acid salt. A mineral fertiliser containing a poly acid and optionally (I) is also claimed. 3,4-dimethylpyrazole (Ia), 4-chloro-3-methyl-pyrazole (Ib), N-hydroxymethyl-3,4-dimethylpyrazole (Ic), N-hydroxymethyl-4-chloro-3-methylpyrazole (Id), acid addition salts of (Ic) and (Id), and mixtures of two or more of (Ia)-(d) are new.

公开(公告)号：BR0109572A

公开(公告)日：2004-10-13

申请号：BR0109572

申请日：2001-03-19

Applicant: BASF AG

Inventor： LLER ULRICH M ,  TELES JOAQUIM HENRIQUE ,  RIEBER NORBERT ,  WALCH ANDREAS ,  BASSLER PETER ,  REHFINGER ALWIN ,  WENZEL ANNE ,  HARDER WOLFGANG

IPC: B01J8/02 ,  B01J29/90 ,  C07D301/12 ,  B01J19/00

Abstract: Continuous reaction of an organic compound with hydroperoxide using a catalyst comprises using at least two parallel reactors and a high stream flow. An independent claim is included for the apparatus used comprising at least two parallel isothermal fixed bed reactors, a separator(s) and an adiabatic fixed bed reactor(s).

公开(公告)号：ZA200306056B

公开(公告)日：2004-09-28

申请号：ZA200306056

申请日：2003-08-06

Applicant: BASF AG

Inventor： BASSLER PETER ,  BERG ANNE ,  REHFINGER ALWIN ,  RIEBER NORBERT ,  RUDOLF PETER ,  TELES JOAQUIM HENRIQUE

IPC: C07D301/12 ,  C07D301/19 ,  C07D301/32 ,  C07D

Abstract: An organic compound having at least one C-C double bond is epoxidized by means of hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent, wherein a product mixture comprising alpha-hydroperoxyalcohols is reduced using at least one reducing agent. The process advantageously comprises at least the following steps: (i) reacting an organic compound having at least one C-C double bond with hydrogen peroxide in the presence of at least one catalytically active compound and at least one solvent to give a product mixture P1 comprising alpha-hydroperoxyalcohols; (ii) separating an epoxide formed in the reaction in step (i) and the unreacted organic compound having at least one C-C double bond from P1 or P1' to give a product mixture P2 or P2', where P2 comprises the alpha-hydroperoxyalcohols formed as by-product in the reaction in step (i) and P2' is largely free of alpha-hydroperoxyalcohols; (iii) treating P1 and/or P2 with at least one reducing agent so that the alpha-hydroperoxyalcohols are converted into corresponding glycols to give a product mixture P1' or P3.

公开(公告)号：DE59909131D1

公开(公告)日：2004-05-13

申请号：DE59909131

申请日：1999-08-09

Applicant: BASF AG

Inventor： BASSLER PETER ,  HARDER WOLFGANG ,  RESCH PETER ,  RIEBER NORBERT ,  RUPPEL WILHELM ,  TELES HENRIQUE ,  WALCH ANDREAS ,  WENZEL ANNE ,  ZEHNER PETER

IPC: C07D301/19 ,  B01J20060101 ,  B01J8/04 ,  C07B20060101 ,  C07B33/00 ,  C07B41/00 ,  C07B61/00 ,  C07D20060101 ,  C07D301/03 ,  C07D301/12 ,  C07D303/04

Abstract: A process for the reaction of an organic compound with a hydroperoxide comprises at least the steps (i) to (iii) below:(i) reaction of the hydroperoxide with the organic compound to give a mixture comprising the reacted organic compound and unreacted hydroperoxide,(ii) separation of the unreacted hydroperoxide from the mixture resulting from step (i),(iii) reaction of the hydroperoxide separated off in step (ii) with the organic compound.

公开(公告)号：AT261919T

公开(公告)日：2004-04-15

申请号：AT01105436

申请日：1997-08-06

Applicant: BASF AG

Inventor： BARTH THOMAS ,  RIEBER NORBERT ,  GOLD RANDALL EVAN ,  DRESSEL JUERGEN ,  ERHARDT KLAUS ,  RITTINGER STEFAN ,  HORCHLER LOCQUENGHIEN KLAUS VON ,  LEIBOLD EDGAR

IPC: C05F3/00 ,  C05G3/00 ,  C05G3/90 ,  C05G5/00 ,  C07D231/12 ,  C07D231/16 ,  C07D321/12 ,  C07D521/00 ,  C05G3/08

Abstract: The use of inorganic or organic poly acids is claimed for treating mineral fertilisers containing a nitrification inhibitor. The use of compounds of formula (I) is claimed as nitrification inhibitors. R1 = H, halo or 1-4C alkyl; R2 = 1-4C alkyl; R3 = H or CH2OH, and when R3 = H, the compound may be converted to a phosphoric acid salt. A mineral fertiliser containing a poly acid and optionally (I) is also claimed. 3,4-dimethylpyrazole (Ia), 4-chloro-3-methyl-pyrazole (Ib), N-hydroxymethyl-3,4-dimethylpyrazole (Ic), N-hydroxymethyl-4-chloro-3-methylpyrazole (Id), acid addition salts of (Ic) and (Id), and mixtures of two or more of (Ia)-(d) are new.

公开(公告)号：DE59810556D1

公开(公告)日：2004-02-12

申请号：DE59810556

申请日：1998-06-05

Applicant: BASF AG

Inventor： GROSCH HEINRICH ,  MUELLER ULRICH ,  WALCH ANDREAS ,  RIEBER NORBERT ,  HARDER WOLFGANG

IPC: B01J29/90 ,  B01J38/12 ,  B01J38/20 ,  C07B41/00 ,  C07C29/48 ,  C07C45/27 ,  C07C51/265 ,  C07D301/12

Abstract: A process for regenerating a zeolite catalyst comprises the following stages: (I) Heating a partially or completely deactivated catalyst to 250-600° C. in an atmosphere which contains less than 2% by volume of oxygen, (II) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from 0.1 to 4% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof, and (III) treating the catalyst at from 250 to 800° C., preferably from 350 to 600° C., with a gas stream which contains from more than 4 to 100% by volume of an oxygen-donating substance or of oxygen or of a mixture of two or more thereof.