Abstract:
Rhodium-spinel catalysts with activity for efficiently catalyzing the net partial oxidation of methane at high selectivities for CO and H2 products are disclosed, along with their method of making. A syngas production process employing such catalysts for the net catalytic partial oxidation of a C1-C5 hydrocarbon (e.g., natural gas or methane) to a product gas mixture comprising CO and H2 is also disclosed. Preferred reaction conditions include maintaining the catalyst at a temperature of about 400-1,200null C., superatmospheric pressure, and flow rate sufficient to pass the reactant gas mixture over the catalyst at space velocities of at least about 100,000-25,000,000 hrnull1.
Abstract:
The present invention relates to improved catalyst compositions, as well as methods of making and using such compositions. In particular, preferred embodiments of the present invention comprise rare earth catalyst supports, catalyst compositions having rare earth supports, and methods of preparing and using the catalysts and supports. Accordingly, the present invention also encompasses an improved method for converting a hydrocarbon containing gas and an oxygen containing gas to a gas mixture comprising hydrogen and carbon monoxide, i.e., syngas, using the rare earth catalyst supports in accordance with the present invention. In addition, the present invention contemplates an improved method for converting hydrocarbon gas to liquid hydrocarbons using the novel syngas catalyst supports and compositions described herein.
Abstract:
A method and an apparatus for fault-tolerant computing in a parallel processing environment. Intermediate data points are determined from a set of input data by a plurality of processing elements operating in parallel. Preferably, the resolution of the intermediate data points is greater than the resolution required in an output imaging data set. The intermediate data points are spatially re-gridded to the resolution required in the output imaging data set, ignoring any missing data as a result of a processing element failing.
Abstract:
A defined catalyst withdrawal and replacement program for optimizing the productivity and the economics of catalyst consumption in a multi-reactor system is disclosed. Catalyst cost is reduced by minimizing removal of the newest catalyst and maximizing removal of older catalyst to achieve an overall reduction of catalyst age in the multi-reactor system.
Abstract:
Methods and apparatus for separating liquid products and catalyst fines from a slurry used in a Fischer-Tropsch reactor. A settling system continuously or intermittently removes catalyst fines from the slurry and is coupled with catalyst-liquid separation system that separates liquid products from the slurry. The preferred separation system produces a sub-particle rich stream and a catalyst-lean stream that are removed from the system. The systems of the present invention act to reduce the concentration of catalyst fines in the reactor, thereby increasing the effectiveness of a catalyst-liquid separation system.
Abstract:
A method and system which deal with the evaluation of the impact of political risk on forecast and value of a project. Key macro political risks are identified and quantified. Project specific political risk events that can result from changes in macro political uncertainties are identified and the probabilities quantified. The relationship of the macro political risks and project specific political risk events are defined. The key project economic parameters susceptible to political uncertainties are identified and the threshold or changes in economic parameters upon the occurrence of a risk event are quantified. The data is assembled into a computer system and a Monte Carlo analysis can be preformed to forecast the probable value of the project taking into account potential political risks.
Abstract:
A method for the recovery of rhodium from spent supported catalysts. In one embodiment, a method for recovering rhodium from a host material includes roasting the host material in air at a temperature sufficient to convert at least a portion of rhodium to Rh2O3, leaching the host material in a solution with a leaching constituent which is reactive with Rh2O3 to form a first intermediate species, reacting the first intermediate species in a solution with an acidifying constituent or complexing agent to form a second intermediate species, and purifying the second intermediate species. Preferably, the roasting temperature is approximately from 600null C. to 800null C. for 0.5 to 10 hours. In some embodiments, the host material is ground to particles in the range of 0.1 to 10 mm.
Abstract translation:从废负载型催化剂中回收铑的方法。 在一个实施方案中,从主体材料回收铑的方法包括在足以将至少一部分铑转化为Rh 2 O 3的温度下在空气中焙烧主体材料,将主体材料浸入溶液中,浸出成分与 Rh 2 O 3以形成第一中间物质,使溶液中的第一中间物质与酸化成分或络合剂反应以形成第二中间物质,并纯化第二中间物质。 优选地,焙烧温度为约600℃至800℃,持续0.5至10小时。 在一些实施方案中,将主体材料研磨至0.1至10mm范围内的颗粒。
Abstract:
A method and system for the combined underground storage and production of petroleum. A wellbore is drilled such that the surface is in fluid communication with an oil bearing and a salt bearing formation. Salt is leached from the salt bearing formation to form a cavern. The oil bearing formation is placed in condition for production. The pressure in the salt bearing formation is maintained below the pressure in the oil bearing formation and oil is collected in the cavern. Periodically, oil is displaced from the cavern to the surface. The system includes a wellbore connecting the surface, an oil bearing formation and a cavern in fluid communication, a check valve is placed within the wellbore to permit the one way flow of oil from the oil bearing formation to the cavern. A wellhead tree seals the wellbore through which passes a conduit to inject gas into the wellbore. Also passing through the welltree is a conduct which extends into the cavern through which oil may be displaced. The present invention is particularly useful for offshore oil production.
Abstract:
Embodiments include a method and apparatus for converting a hydrocarbon and oxygen feed stream to a product stream such as syngas, including multiple serially aligned reaction zones and multiple hydrocarbon feeds. The first reaction zone catalyzes the net partial oxidation of the feed hydrocarbon. The subsequent zones catalyze reactions such as the stream or dry reforming of hydrocarbons or the water gas shift reaction, depending on the stream composition in the vicinity of the zone, and the desired product stream composition.