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公开(公告)号:DE19814874A1
公开(公告)日:1999-10-07
申请号:DE19814874
申请日:1998-04-02
Applicant: BASF AG
Inventor: SCHWALM REINHOLD , BECK ERICH , LOKAI MATTHIAS , MENZEL KLAUS
IPC: C08G18/67 , C08G18/78 , C08G18/79 , C08G18/81 , C09D175/16 , C08G18/10 , C08L75/14 , C09D4/00 , C09D175/14
Abstract: Radiation-curable urethane prepolymers are made from a mixture in which the isocyanate component contains two different trifunctional isocyanates or one tri- and one di-functional isocyanate, or the unsaturated polyol component contains at least two different unsaturated compounds with reactive hydroxyl groups and possibly other hydroxy compounds. A process for the production of radiation-curable, urethane group-containing prepolymers (PU) comprises reacting an isocyanate component (A) containing trifunctional isocyanate(s) (A1) and optionally difunctional isocyanate(s) (A2) with a polyol component (B) containing unsaturated compound(s) with at least one reactive hydroxyl group (B1) and optionally other OH group-containing compounds (B2), in which either (A) contains two different compounds (A1) or one (A1) and one (A2), or component (B) contains at least two different compounds (B1). Independent claims are also included for the following: (1) radiation-curable urethane prepolymers obtained by this process; (2) radiation-curable preparations containing prepolymers (PU) as above and possibly conventional additives etc.; (3) a process for coating substrates by applying PU or preparations containing PU to the substrate, removing any solvent; and hardening with UV or electron beam radiation; (4) coated substrates obtained by this process.
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公开(公告)号:DE19814872A1
公开(公告)日:1999-10-07
申请号:DE19814872
申请日:1998-04-02
Applicant: BASF AG
Inventor: SCHWALM REINHOLD , KOENIGER RAINER , BECK ERICH , MENZEL KLAUS , PAULUS WOLFGANG , ENENKEL PETER
IPC: C08F2/48 , C08F2/46 , C08F220/36 , C08F222/10 , C08F290/00 , C08F290/06 , C08F290/14 , C08G18/28 , C08G18/67 , C08G18/79 , C08G18/81 , C09D4/00 , C09D4/06 , C09D133/04 , C09D175/16 , B05D7/16 , C08G18/10 , C09D161/32
Abstract: A radiation curable composition (I) comprises: (A) a prepolymer containing at least two olefinic double bonds per molecule; and (B) a diester of an alpha , beta -ethylenically unsaturated carboxylic acids with diols, having a linear 7-14C alkylene chain. Independent claims are included for: (i) a process for coating a substrate by application of (I) and curing by UV or electron beam irradiation; and (ii) the resulting coated substrate.
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公开(公告)号:CA1338177C
公开(公告)日:1996-03-26
申请号:CA600064
申请日:1989-05-18
Applicant: BASF AG
Inventor: SCHWALM REINHOLD , BINDER HORST
IPC: G03F7/023 , C08L61/08 , G03F7/004 , G03F7/039 , H01L21/027
Abstract: A radiation sensitive mixture useful for producing relief patterns contains (a) a polymeric binder which is insoluble in water but soluble in aqueous alkaline solutions and (b) an organic compound whose solubility in an aqueous alkaline developer is increased by the action of acid and which contains at least one acid cleavable group and also a group which on irradiation forms a strong acid, wherein the polymeric binder (a) contains from 5 to 40 mol % of monomer units having groups in copolymerized or cocondensed form or the groups introduced by polymer analogous reaction, with the proviso that the radical R contains from 5 to 9 carbon atoms.
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公开(公告)号:CA1334059C
公开(公告)日:1995-01-24
申请号:CA598317
申请日:1989-05-01
Applicant: BASF AG
Inventor: SCHWALM REINHOLD , BINDER HORST , BOETTCHER ANDREAS
Abstract: A radiation sensitive mixture suitable for producing relief patterns contains (a) a polymeric binder which is insoluble in water but soluble in aqueous alkaline solutions and (b) an organic compound whose solubility in an aqueous alkaline developer is increased by the action of acid and which contains at least one acid cleavable group and additionally a group which forms a strong acid on irradiation, wherein the polymeric binder (a) contains from 5 to 35 mol % of monomer units having acid labile groups as copolymerized or cocondensed units or acid labile groups introduced by polymer analogous reaction.
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公开(公告)号:DE58904764D1
公开(公告)日:1993-07-29
申请号:DE58904764
申请日:1989-04-05
Applicant: BASF AG
Inventor: SCHWALM REINHOLD
Abstract: The invention relates to a radiation-sensitive mixture for light- sensitive coating materials, and also to a process for obtaining relief patterns and images. … The radiation-sensitive mixture contains… a) a water-insoluble polymeric binder which is soluble in aqueous alkaline solutions, and… b) an organic compound whose solubility in an aqueous alkaline developer is increased by exposure to acid and which contains at least one acid-cleavable grouping,… the polymeric binder (a) being a copolymer containing o-nitrobenzyl groupings. … The radiation-sensitive mixture according to the invention is suitable, in particular, for obtaining photoresists.
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公开(公告)号:AU1070788A
公开(公告)日:1988-09-01
申请号:AU1070788
申请日:1988-01-22
Applicant: BASF AG
Inventor: SCHWALM REINHOLD , BINDER HORST
IPC: G03C1/72 , C08F20/34 , C08F30/08 , C08F220/26 , C08F220/36 , C08F222/22 , C08F230/08 , G03F7/004 , G03F7/039 , G03F7/095 , G03F7/11 , H01L21/027 , H01L21/30 , C08F220/08 , H01L21/02 , G03F7/10 , G03F7/26 , G03C1/68 , G03C1/70
Abstract: Copolymers useful in particular for producing two-layer resists and fabricating semiconductor devices contain from 5 to 50 mol % of monomers having o-nitrocarbinol ester groups, from 95 to 50 mol % of an olefinically unsaturated silicon-containing organic compound, from 0 to 20 mol % of an olefinically unsaturated carboxylic acid and from 0 to 25 mol % of other copolymerizable monomers.
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公开(公告)号:DK362488D0
公开(公告)日:1988-06-30
申请号:DK362488
申请日:1988-06-30
Applicant: BASF AG
Inventor: SCHWALM REINHOLD , BOETTCHER ANDREAS , BINDER HORST
Abstract: A radiation-sensitive mixture consists of a polymeric binder which is insoluble in water but soluble in aqueous alkaline solutions, and of an organic compound whose solubility in an aqueous alkaline developer is increased by the action of an acid and which contains both one or more acid-cleavable groups and a group which forms a strong acid under the action of radiation. The radiation-sensitive mixture is suitable for use in photosensitive coating materials for the production of relief patterns and relief images.
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公开(公告)号:DK362388D0
公开(公告)日:1988-06-30
申请号:DK362388
申请日:1988-06-30
Applicant: BASF AG
Inventor: SCHWALM REINHOLD , BOETTCHER ANDREAS
IPC: C07D333/46 , C07C67/00 , C07C69/96 , C07C325/00 , C07C381/12 , C07F7/08 , C07F7/18 , C08F2/50 , C08F4/00 , C09D7/12 , G03F7/004 , G03F7/029 , G03F7/031 , G03F7/26 , C07C149/46 , C07C148/00
Abstract: Sulphonium salts of the formula … … in which R , R and R are identical to or different from one another and represent aliphatic and/or aromatic radicals which may contain heteroatoms, or two of the radicals R to R are linked to one another to form a ring, with the proviso that at least one of the radicals R to R contains at least one grouping cleavable by acid or one of the radicals R to R is linked to one or more further sulphonium salt radicals, if desired via groupings cleavable by acid, and X denotes a non-nucleophilic counterion… are suitable as photoinitiators for cationic polymerisation.
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公开(公告)号:DE3642184A1
公开(公告)日:1988-06-23
申请号:DE3642184
申请日:1986-12-10
Applicant: BASF AG
Inventor: SCHWALM REINHOLD , BINDER HORST
IPC: C08F12/00 , C08F20/34 , C08F22/32 , C08F212/14 , C08F220/36 , C08F222/00 , C08F222/22 , C08F222/32 , G03F7/00 , G03F7/004 , G03F7/039 , C08F220/34 , C08F224/00 , C08F226/06 , G03C1/72 , G03F7/10
Abstract: Copolymers containing from 5 to 50 mol % of monomers having o-nitrocarbinol ester groups, from 95 to 50 mol % of O-substituted p-hydroxystyrene and from 0 to 30 mol % of other copolymerizable monomers are useful for producing positive-working photoresists and light-sensitive coating materials.
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公开(公告)号:AU6079486A
公开(公告)日:1987-02-05
申请号:AU6079486
申请日:1986-08-01
Applicant: BASF AG
Inventor: KOCH HORST , LOERZER THOMAS , BOETTCHER ANDREAS , SCHULZ GUENTHER , SCHWALM REINHOLD
IPC: C07D213/89 , C07D405/12 , C08F2/48 , C08F2/50 , G03F7/004 , G03F7/025 , G03F7/027 , G03F7/038 , C07D221/08 , C07D241/12 , C07D417/06 , C07F9/58 , G03C1/70
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