公开(公告)号：WO2011150263A2

公开(公告)日：2011-12-01

申请号：PCT/US2011/038216

申请日：2011-05-26

Applicant: KEMET ELECTRONICS CORPORATION ,  CHACKO, Antony P. ,  MCCONNELL, John E. ,  LESSNER, Philip M. ,  HAHN, Randolph S. ,  BULTITUDE, John

Inventor： CHACKO, Antony P. ,  MCCONNELL, John E. ,  LESSNER, Philip M. ,  HAHN, Randolph S. ,  BULTITUDE, John

IPC: H01G9/04 ,  H01G9/012

CPC classification number: H01G9/012 ,  H01G9/0425 ,  H01G9/15 ,  Y02E60/13 ,  Y10T29/43

Abstract: A solid electrolytic capacitor with an anode and a dielectric on the anode. A cathode is on the dielectric and a conductive coating on said dielectric. A cathode lead is electrically connected to the conductive coating by an adhesive selected from the group consisting of a transient liquid phase sinterable material and polymer solder.

Abstract translation: 在阳极上具有阳极和电介质的固体电解电容器。 电介质上的阴极和所述电介质上的导电涂层。 阴极引线通过选自瞬态液相可烧结材料和聚合物焊料的粘合剂电连接到导电涂层。

公开(公告)号：WO2008131018A2

公开(公告)日：2008-10-30

申请号：PCT/US2008/060503

申请日：2008-04-16

Applicant: KEMET ELECTRONICS CORPORATION ,  QIU, Yongjian ,  CHEN, Qingping ,  LESSNER, Philip M. ,  HAHN, Randy S. ,  PRINCE, Cynthia L. ,  BRENNEMAN, Keith R.

Inventor： QIU, Yongjian ,  CHEN, Qingping ,  LESSNER, Philip M. ,  HAHN, Randy S. ,  PRINCE, Cynthia L. ,  BRENNEMAN, Keith R.

IPC: H01G9/028 ,  C08G61/12

CPC classification number: H01G9/0036 ,  H01G9/028 ,  H01G9/15 ,  H01G11/48 ,  H01G11/56 ,  H01G11/82 ,  Y02E60/13 ,  Y10T29/417

Abstract: A method for maintaining quality of monomer during a coating process for intrinsically conductive polymer which suppresses unwanted by-products. A neutralization process using a base or anion exchange resin is used batch-wise or continuous.

Abstract translation: 在用于抑制不需要的副产物的本征导电聚合物的涂布过程中维持单体质量的方法。 分批或连续使用使用碱或阴离子交换树脂的中和过程。

公开(公告)号：WO0236858A2

公开(公告)日：2002-05-10

申请号：PCT/US0132640

申请日：2001-10-25

Applicant: KEMET ELECTRONICS CORP ,  HAHN RANDOLPH S ,  LESSNER PHILIP M ,  MELODY BRIAN J ,  KINARD JOHN T

Inventor： HAHN RANDOLPH S ,  LESSNER PHILIP M ,  MELODY BRIAN J ,  KINARD JOHN T

IPC: B05D5/12 ,  B05D7/14 ,  H01B1/12 ,  C25D

CPC classification number: B05D7/14 ,  B05D5/12 ,  B05D2350/00 ,  H01B1/127 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13

Abstract: An intrinsically conductive polymer is prepared with a chemical oxidative process. The polymer is prepared by first dipping or coating a substrate with an Fe(III)-containing oxidizer solution and drying. The substrate is then dipped or coated with a monomer, such as 3,4-ethylenedioxythiophene solution and reacted to form the conductive polymer. The monomer is dissolved in a solvent in which it has a high solubility but in which the Fe(III)-containing oxidizer has low solubility. This minimizes cross-contamination of the monomer and oxidizer dipping solutions thereby making this process suitable for high volume production. Dissolving the monomer in a solvent allows control over the stoichiometric ration of monomer to oxidizer and prevents an excess of monomer thereby facilitating the removal of any unreacted monomer by water. The substrate is then dipped in an aqueous solution of para-toluenesulfonic acid to facilitate the removal of Fe(II) byproducts by enhancing their solubility in water and then the substrate may be washed with an aqueous solution of pure water. The process produces low ESR and low leakage valve metal capacitors with conductive polymer cathodes.

Abstract translation: 用化学氧化法制备固有导电的聚合物。 通过首先用含Fe（III）的氧化剂溶液浸渍或涂覆基底并干燥来制备聚合物。 然后将基材浸渍或涂覆单体如3,4-亚乙基二氧噻吩溶液并反应形成导电聚合物。 将单体溶解在其溶解度高的溶剂中，其中含有Fe（III）的氧化剂具有低溶解度。 这使得单体和氧化剂浸渍溶液的交叉污染最小化，从而使得该方法适合于大批量生产。 将单体溶解在溶剂中允许控制单体对氧化剂的化学计量比，并防止过量的单体，从而便于通过水除去任何未反应的单体。 然后将底物浸入对甲苯磺酸的水溶液中以促进通过增加其在水中的溶解度来除去Fe（II）副产物，然后可以用纯水的水溶液洗涤底物。 该过程产生低导电聚合物阴极的低ESR和低泄漏阀金属电容器。

公开(公告)号：WO2009079026A2

公开(公告)日：2009-06-25

申请号：PCT/US2008/063830

申请日：2008-05-16

Applicant: KEMET ELECTRONICS CORPORATION ,  CHEN, Qingping ,  BRENNEMAN, Keith, R. ,  MA, Yuhong ,  QIU, Yongjian ,  LESSNER, Philip, M. ,  HAHN, Randy, S.

Inventor： CHEN, Qingping ,  BRENNEMAN, Keith, R. ,  MA, Yuhong ,  QIU, Yongjian ,  LESSNER, Philip, M. ,  HAHN, Randy, S.

IPC: H01B1/12

CPC classification number: H01G9/0036 ,  H01G9/15

Abstract: A process for forming a capacitor. The process includes providing an anode; providing a dielectric on the anode; exposing the anode to a polymer precursor solution comprising monomer, conjugated oligomer and optionally solvent and polymerizing the polymer precursor. The ratio between monomer and conjugated oligomer ranges from 99.9/0.1 to 75/25 b y weight. The solvent content in the polymer precursor solution is from 0 to 99 % by weight.

Abstract translation: 一种形成电容器的工艺。 该方法包括提供阳极; 在阳极上提供电介质; 将阳极暴露于包含单体，共轭低聚物和任选溶剂的聚合物前体溶液并聚合聚合物前体。 单体和共轭低聚物之间的比例范围为99.9 / 0.1至75 / 25b重量。 聚合物前体溶液中的溶剂含量为0至99重量％。

公开(公告)号：WO2008048338A2

公开(公告)日：2008-04-24

申请号：PCT/US2007/001605

申请日：2007-01-22

Applicant: KEMET ELECTRONICS CORPORATION ,  MELODY, Anita ,  CHACKO, Antony P. ,  CHEN, Qingping ,  HAHN, Randy S. ,  KINARD, John T. ,  LESSNER, Philip M.

Inventor： CHACKO, Antony P. ,  CHEN, Qingping ,  HAHN, Randy S. ,  KINARD, John T. ,  LESSNER, Philip M. ,  MELODY, Brian J.

IPC: H01G9/012 ,  H01G9/042

CPC classification number: H01G9/012 ,  H01G9/028 ,  H01G9/0425 ,  H01G9/08 ,  Y10T29/417 ,  Y10T29/435

Abstract: An improved capacitor with an anode (11) with an anode wire and an oxide layer (12) on the surface of the anode (11). A cathode layer is exterior to the oxide layer. A carbon conductive layer (14) is exterior to the cathode layer wherein the cathode layer comprises 5-75 wt% resin and 25-95 wt% conductor. The conductor has carbon nanotubes. An anode lead is in electrical contact with the anode wire and a cathode lead is in electrical contact with the carbon conductive layer (14).

Abstract translation: 一种具有在阳极（11）的表面上具有阳极线和氧化物层（12）的阳极（11）的改进的电容器。 阴极层在氧化物层的外部。 导电层（14）位于阴极层的外部，其中阴极层包含5-75重量％的树脂和25-95重量％的导体。 导体具有碳纳米管。 阳极引线与阳极线电接触，阴极引线与碳导电层（14）电接触。

公开(公告)号：WO2007075714A2

公开(公告)日：2007-07-05

申请号：PCT/US2006/048472

申请日：2006-12-19

Applicant: MOTOROLA, INC. ,  KEMET ELECTRONICS CORPORATION ,  DUNN, Gregory J., ,  CHELINI, Remy J., ,  CROSWELL, Robert T., ,  LESSNER, Philip M., ,  PREVALLET, Michael D., ,  PRYMAK, John D.,

Inventor： DUNN, Gregory J., ,  CHELINI, Remy J., ,  CROSWELL, Robert T., ,  LESSNER, Philip M., ,  PREVALLET, Michael D., ,  PRYMAK, John D.,

IPC: H01G9/00

CPC classification number: H01G9/045 ,  H01G9/0032 ,  H01G9/055 ,  H01G9/15 ,  H05K1/162 ,  H05K3/383 ,  H05K3/429 ,  H05K2201/0355 ,  H05K2201/09309 ,  H05K2201/09509 ,  H05K2201/09718 ,  H05K2203/0315

Abstract: Embedded capacitors comprise a bimetal foil (500) that includes a first copper layer (205) and an aluminum layer (210) on the first copper layer. The aluminum layer has a smooth side adjacent the first copper layer and a high surface area textured side (215) opposite the first copper layer. The bimetal foil further includes an aluminum oxide layer (305) on the high surface area textured side of the aluminum layer, a conductive polymer layer (420) on the aluminum oxide layer, and a second copper layer (535) overlying the aluminum oxide layer. The bimetal foil may be embedded in a circuit board (700) to form high value embedded capacitors.

Abstract translation: 嵌入式电容器包括在第一铜层上包括第一铜层（205）和铝层（210）的双金属箔（500）。 铝层具有与第一铜层相邻的光滑侧和与第一铜层相对的高表面积纹理侧（215）。 双金属箔进一步包括位于铝层的高表面积纹理侧上的氧化铝层（305），位于氧化铝层上的导电聚合物层（420）以及位于氧化铝层上的第二铜层（535） 。 双金属箔可嵌入电路板（700）中以形成高价值的嵌入式电容器。

公开(公告)号：WO2002036858A3

公开(公告)日：2002-05-10

申请号：PCT/US2001/032640

申请日：2001-10-25

Applicant: KEMET ELECTRONICS CORPORATION ,  HAHN, Randolph, S. ,  LESSNER, Philip, M. ,  MELODY, Brian, J. ,  KINARD, John, T.

Inventor： HAHN, Randolph, S. ,  LESSNER, Philip, M. ,  MELODY, Brian, J. ,  KINARD, John, T.

IPC: H01G9/025

Abstract: An intrinsically conductive polymer is prepared with a chemical oxidative process. The polymer is prepared by first dipping or coating a substrate with an Fe(III)-containing oxidizer solution and drying. The substrate is then dipped or coated with a monomer, such as 3,4-ethylenedioxythiophene solution and reacted to form the conductive polymer. The monomer is dissolved in a solvent in which it has a high solubility but in which the Fe(III)-containing oxidizer has low solubility. This minimizes cross-contamination of the monomer and oxidizer dipping solutions thereby making this process suitable for high volume production. Dissolving the monomer in a solvent allows control over the stoichiometric ration of monomer to oxidizer and prevents an excess of monomer thereby facilitating the removal of any unreacted monomer by water. The substrate is then dipped in an aqueous solution of para-toluenesulfonic acid to facilitate the removal of Fe(II) byproducts by enhancing their solubility in water and then the substrate may be washed with an aqueous solution of pure water. The process produces low ESR and low leakage valve metal capacitors with conductive polymer cathodes.

公开(公告)号：WO2012112680A2

公开(公告)日：2012-08-23

申请号：PCT/US2012/025238

申请日：2012-02-15

Applicant: KEMET ELECTRONICS CORPORATION ,  CHEN, Qingping ,  ZHANG, Hong ,  CHACKO, Antony P. ,  LESSNER, Philip M. ,  HAHN, Randolph S. ,  QIU, Yongjian ,  BRENNEMAN, Keith R.

Inventor： CHEN, Qingping ,  ZHANG, Hong ,  CHACKO, Antony P. ,  LESSNER, Philip M. ,  HAHN, Randolph S. ,  QIU, Yongjian ,  BRENNEMAN, Keith R.

IPC: H01G9/042 ,  H01G9/008

CPC classification number: H01G9/0032 ,  B05D1/185 ,  B82Y99/00 ,  H01G9/0036 ,  H01G9/028 ,  H01G9/0425 ,  H01G9/052 ,  H01G9/15 ,  Y10S977/948 ,  Y10T29/417 ,  Y10T29/43

Abstract: A process for preparing a solid electrolytic capacitor comprising application of a non-ionic polyol prior to application of a conducting polymer layer.

Abstract translation: 制备固体电解质电容器的方法，包括在施加导电聚合物层之前施加非离子多元醇。

公开(公告)号：WO2011150263A3

公开(公告)日：2012-02-23

申请号：PCT/US2011038216

申请日：2011-05-26

Applicant: KEMET ELECTRONICS CORP ,  CHACKO ANTONY P ,  MCCONNELL JOHN E ,  LESSNER PHILIP M ,  HAHN RANDOLPH S ,  BULTITUDE JOHN

Inventor： CHACKO ANTONY P ,  MCCONNELL JOHN E ,  LESSNER PHILIP M ,  HAHN RANDOLPH S ,  BULTITUDE JOHN

IPC: H01G9/04 ,  H01G9/012

CPC classification number: H01G9/012 ,  H01G9/0425 ,  H01G9/15 ,  Y02E60/13 ,  Y10T29/43

Abstract: A solid electrolytic capacitor with an anode and a dielectric on the anode. A cathode is on the dielectric and a conductive coating on said dielectric. A cathode lead is electrically connected to the conductive coating by an adhesive selected from the group consisting of a transient liquid phase sinterable material and polymer solder.

Abstract translation: 在阳极上具有阳极和电介质的固体电解电容器。 阴极位于电介质上，并在所述电介质上具有导电涂层。 阴极引线通过选自瞬态液相可烧结材料和聚合物焊料的粘合剂电连接到导电涂层。

公开(公告)号：WO2011150246A2

公开(公告)日：2011-12-01

申请号：PCT/US2011/038197

申请日：2011-05-26

Applicant: KEMET ELECTRONICS CORPORATION ,  MCCONNELL, James, E. ,  BULTITUDE, John ,  PHILLIPS, Reggie ,  HILL, Allen ,  RENNER, Garry, L. ,  LESSNER, Philip, M. ,  CHACKO, Antony, P. ,  BELL, Jeffrey ,  BROWN, Keith

Inventor： MCCONNELL, James, E. ,  BULTITUDE, John ,  PHILLIPS, Reggie ,  HILL, Allen ,  RENNER, Garry, L. ,  LESSNER, Philip, M. ,  CHACKO, Antony, P. ,  BELL, Jeffrey ,  BROWN, Keith

IPC: H01G4/12 ,  H01G4/30 ,  B23K31/02

CPC classification number: H01G4/2325 ,  B23K1/0016 ,  B23K1/0053 ,  B23K1/008 ,  B23K1/203 ,  B23K35/0227 ,  B23K35/3613 ,  B23K2201/42 ,  H01G4/005 ,  H01G4/30 ,  H01L2224/83825 ,  H01L2924/01322 ,  H01L2924/01327 ,  H01L2924/10253 ,  H01L2924/1461 ,  Y10T29/435 ,  H01L2924/00012 ,  H01L2924/00015 ,  H01L2924/00

Abstract: A capacitor has first planer internal electrodes in electrical contact with a first external termination. Second planer internal electrodes are interleaved with the first planer internal electrodes wherein the second planer internal electrodes are in electrical contact with a second external termination. A dielectric is between the first planer internal electrodes and the second planer internal electrodes and at least one of the external terminations comprises a material selected from a polymer solder and a transient liquid phase sintering adhesive.

Abstract translation: 电容器具有与第一外部端子电接触的第一平面内部电极。 第二平面内部电极与第一平面内部电极交错，其中第二平面内部电极与第二外部端子电接触。 电介质在第一平面内部电极和第二平面内部电极之间，并且至少一个外部端子包括选自聚合物焊料和瞬态液相烧结粘合剂的材料。