Abstract:
PURPOSE: A continuous polytetrafluoroethylene(PTFE) pyrolysis apparatus and a method for preparing PTFE using the apparatus are provided, to obtain tetrafluoroethylene of high purity massively with low cost. CONSTITUTION: The apparatus comprises at least two PTFE main tanks(10) which stores PTFE powder or particle and can be operated alternatively; a PTFE auxiliary tank(11) which is connected with the main PTFE main tanks(10) through a ball valve(24) and a transparent hose(12) for vacuum and stores PTFE supplied from the main tanks(10) temporarily before PTFE is applied to the process; a vertical-type screw feeder(13) which is operated by a motor and a magnetic driver, whose rotation number can be controlled, and which injects the PTFE supplied from the auxiliary tank(11) into a pyrolysis reactor through a cooler(15); and a vertical-type pyrolysis reactor(14) which pyrolyzes the PTFE supplied from the screw feeder(13) to generate tetrafluoroethylene gas and delivers the generated tetrafluoroethylene gas to a tetrafluoroethylene condensation tank.
Abstract:
PURPOSE: A continuous preparation of perfluoroethyliodide denoted by C2F5I is accomplished under activate liquid catalyst. The compound is used in a variety of water/oil repellent process or contaminant-resistant agents and high performance surfactant. CONSTITUTION: A continuous preparation of perfluoroethyliodide is performed by using iodide, pentafluoroiodide, tetrafluoroethylene(TFE) and reaction catalyst. The preparation comprises further continuously introducing TFE under room pressure and in the presence of antimony pentafluoride (SbF5) reaction catalyst in liquid state to produce perfluoroethyliodide product. The iodide and iodide pentafluoride is admixed together in a reaction molar ratio (I2/IF5) of 0.02-5 and the reaction catalyst SbF5 is dissolved under stirring at room temperature to 50 deg.C.
Abstract:
PURPOSE: Disclosed is a separation membrane containing perfluoroalkyl chain for selective separation of mixed gas of CO2, N2, O2, CH4, H2, NH3, H2O, hydrocarbon, or volatile organic compounds. CONSTITUTION: The separation membrane, C(W)(CF2)n(X)OCOC(Z)=CH2, where W is F3, F2Cl or F2H, X is (CH2)m, CON(Y)(CH2)m, SO2N(Y)(CH2)m, or CH2CH(Y)(CH2)m, Y is H, OH, CH3, C2H5, C3H7, or OCOCH3, Z is H or CH3, n is an integer of 1-20, and m is an integer of 0 or 1-4, is prepared by the polymerization of perfluoroalkyl acrylate monomer or the copolymerization of other comonomer. The phase transfer method or the preparation method of composite membrane are employed to present alkyl chain,£C(W)(CF2)n-|and to have a critical surface tension of 8-20 dynes/cm, a contact angle of 110-120°to water and of 66-100°to diiodomethane. The employed polymers have a molecular weight of 10,000-100,000 and inorganic materials such as polymer, ceramic, or zeolite may be used.
Abstract:
PURPOSE: A film used for green house and agriculture needs properties such as good light permeability, pollution resistance from soil dust, and good defogging ability. CONSTITUTION: The invention is disclosed a defogging agent prepared from random copolymerization of 20-70 weight % of compound containing perfluoro-alkyl group, and 10-50 weight % of silicone compound, and 5-30 % weight of a cross-linking monomer having substituted or unsubstituted hydroxyl group and alkyl group. The defogging agent is added to films used in agriculture such as polyvinyl film, polyethylene film, ethylene-vinylacetate film, and polyester film. The properties of film like light permeability, defogging ability, and pollution resistance to soil dust is improved by the defogging agent.
Abstract:
본 발명은 수용성 및 생분해성 금속 이온포착제를 이용한 토양 정화방법에 관한 것으로서, 더욱 상세하게는 에스신(Escin)을 금속 이온포착제로 사용하여 중금속으로 오염된 토양을 정화할 수 있을 뿐만 아니라 이들이 수용성 및 생분해성 특성을 지니고 있어 자연환경으로 방출시에도 2차적인 환경오염을 발생시키지 않고, 또한 재활용이 가능하며 경제적으로도 유용한 수용성 및 생분해성 금속 이온포착제를 이용한 토양 정화방법에 관한 것이다.
Abstract:
PURPOSE: Provided is a fluorine-based water-dispersive polyurethane excellent in antifouling property, water repellent property, and oil repellent property and soft, which can be used as a coating agent for fiber, paper, and building industries. CONSTITUTION: The water-dispersive polyurethane is produced by copolymerizing a fluorine-based macromonomer containing a perfluoroalkyl group, a diisocyanate, and a hydrophilic diol, wherein the fluorine-based macromonomer is produced by using a monomer (formula 1:XCnF2n-(Y)-OCOCR1=CH2) containing the perfluoroalkyl group and a comonomer having an unsaturated double bond, such as acrylic acid and methacrylic acid, in the weight ratio of 95/5-5/95. In the formula, Y is -(CH)2-, -(CH2)m-, -CH2CH(OH)(CH2)m-, or -SO2NR2(CH2)m-, R1 is H or -CH3, R2 is C1-C4 alkyl, X is H or halogen, m is an integer of 2-6, and n is an integer of 3-21.