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公开(公告)号:JPH06191829A
公开(公告)日:1994-07-12
申请号:JP35646791
申请日:1991-12-25
Applicant: AGENCY IND SCIENCE TECHN
Inventor: SHIBAZAKI YASUO , WATAMURA SHINJI , MIYAWAKI RITSURO , SAMEJIMA SOICHIRO , OSAKI YASUSHI , YOSHIDA SETSUO , SATOKAWA SHIGEO
IPC: C01B33/26 , C04B35/00 , C04B35/18 , C04B35/626 , D21H17/63
Abstract: PURPOSE:To produce spherical kaolinite having a high rate of formation, excellent in slurrying characteristics and compacting characteristics and incapable of production by the conventional method. CONSTITUTION:Spherical synthetic kaolinite having >=95% rate of formation is produced by hydrothermally treating uniformly mixed silica-alumina gel in two stages at 220 deg.C. The objective spherical synthetic kaolinite having a high rate of formation and applicable to ceramics, paper, pharmaceuticals, etc., can be produced.
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公开(公告)号:JPH05170428A
公开(公告)日:1993-07-09
申请号:JP35646891
申请日:1991-12-25
Applicant: AGENCY IND SCIENCE TECHN , JINKOU NENDO GOSEI GIJUTSU KEN
Inventor: SHIBAZAKI YASUO , WATAMURA SHINJI , MIYAWAKI RITSURO , OSAKI YASUSHI , YOSHIDA SETSUO , SAMEJIMA SOICHIRO , SATOKAWA SHIGEO
Abstract: PURPOSE:To provide a producing method for a high dispersible synthetic kaolinite excellent in molderability, slurry property and less in cohesion. CONSTITUTION:The high dispersible synthetic kaolinite having
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公开(公告)号:JPH02311311A
公开(公告)日:1990-12-26
申请号:JP13366389
申请日:1989-05-26
Applicant: AGENCY IND SCIENCE TECHN , JINKOU NENDO GOSEI GIJUTSU KEN
Inventor: MIYAWAKI RITSURO , WATAMURA SHINJI , MIZUTA HIROYUKI , MAEDA MASAKI , SHIBAZAKI YASUO , MARUYAMA SHINICHI , SAMEJIMA SOICHIRO
IPC: C01B33/26
Abstract: PURPOSE:To obtain a kaolinite having high plasticity and imparted with crystallinity and particle size similar to those of natural clay by adding Li ion to a mixture of amorphous silica and amorphous alumina and subjecting the mixture to hydrothermal synthesis. CONSTITUTION:An aqueous solution containing 0.05 to 0.5 mol/1 of Li ion is added to a powdery raw material consisting of a mixture of amorphous silica and amorphous alumina and the obtained mixture is subjected to hydrothermal synthesis in a pressure vessel at 150 to 300 deg.C for 1 to 30 days to obtain an Li-containing kaolinite containing lattice defects in the lamination plane, having mitigated strain between a tetrahedral layer and an octahedral layer similar to a kaolinite having ideal chemical composition and having promoted lamination structure.
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14.
公开(公告)号:JPH08257338A
公开(公告)日:1996-10-08
申请号:JP9169595
申请日:1995-03-24
Applicant: AGENCY IND SCIENCE TECHN
Inventor: HORIO MASAKAZU , SUZUKI KENJI , WATAMURA SHINJI , INUKAI KEIICHI
Abstract: PURPOSE: To provide a ceramic separating material for separating nitrogen from carbon dioxide in the high temperature state. CONSTITUTION: In the investigation performed for the nitrogen/carbon dioxide separation function of nitrated magnesium-ion-exchange sepiolite, it is found that both elements can be separated sufficiently in the high temperature state. Also it is found that the separation function of the nitrated magnesium-ion- exchange sepiolite is more improved than that of a raw material or untreated sepiolite.
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公开(公告)号:JPS6434447A
公开(公告)日:1989-02-03
申请号:JP19031587
申请日:1987-07-31
Applicant: AGENCY IND SCIENCE TECHN , NICHIBI KK , OSAWA TAIKA KK , TAIMEI KAGAKU KOGYO KK
Inventor: SHIBAZAKI YASUO , WATAMURA SHINJI , MIZUTA HIROYUKI , OSAWA TADASHI , IZAWA YUICHI , MIYAMATSU NORIHISA
IPC: B01J23/00 , B01J23/74 , B01J23/755 , B01J35/04 , B01J37/30
Abstract: PURPOSE:To extend an effective surface area and to improve heat resistance and physical strength, by bonding an active catalyst component to a carrier in a pore through a spinel-structure layer comprising Al and the metal of the active catalyst component, so as to form a multilayer thereof over the pore surface. CONSTITUTION:An aluminum compound and water are added to ion exchange fibers containing catalytic metal ions, and the resulting mixture is formed into a desired shape and calcined at a temperature not lower than 1,000 deg.C, thereby preparing a heat-resistant porous catalyst. This heat-resistant porous catalyst 1 comprises alpha-alumina as a carrier and a metal or its oxide as an active catalyst component. At least in a pore 4, the active catalyst component is so bonded to the carrier, through a spinel-structure layer 2 comprising aluminum and the metal of the active catalyst component, as to form a multilayer thereof over the pore surface.
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公开(公告)号:JPS6389416A
公开(公告)日:1988-04-20
申请号:JP23014486
申请日:1986-09-30
Applicant: SHOWA KAGAKU KOGYO KK , AGENCY IND SCIENCE TECHN
Inventor: SHIBAZAKI YASUO , WATAMURA SHINJI , MAEDA TAKEHISA , KUROHIJI SETSUO , TASHIRO ATSUHIKO , NOGUCHI YASUHIKO
IPC: C01B33/26
Abstract: PURPOSE:To obtain a diatomaceous earth having plasticity without losing porosity and to make a white filler obtainable from even a lower quality diatomaceous earth by adding the specified amt. of aq. soln. of aluminum compd. to the diatomaceous earth and subjecting the mixture to hydrothermal processing to kaolinize the diatomaceous earth. CONSTITUTION:The diatomaceous earth is added with the aq. soln. of aluminum compd. to make the ratio of Al/Si to =0.5hr at 100-300 deg.C.
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公开(公告)号:JP2000176276A
公开(公告)日:2000-06-27
申请号:JP37581498
申请日:1998-12-18
Applicant: AGENCY IND SCIENCE TECHN , YKK CORP
Inventor: AIKAWA KAZUO , FUKUSHIMA KYOKO , AKAIKE KAZUMOTO , SHIBAZAKI YASUO , WATAMURA SHINJI
Abstract: PROBLEM TO BE SOLVED: To provide a gas adsorbing and desorbing material and its producing method so that the material can not only adsorb or adsorb and desorb an objective gas but also can drastically adsorb or desorb under a specified vapor pressure (relative humidity), and that a vapor pressure to initiate the drastic adsorption and/or desorption can be controlled as desired. SOLUTION: An acid or alkali aq. soln. is added or a soln. containing S2- ion is added to a metal salt aq. soln. to precipitate amorphous particles of metal hydroxides or metal sulfides, which are dried or heat treated at temperatures of 80 to 1,000 deg.C. The gas adsorbing and desorbing material is obtd. by this method and it consists of a dry powder or heat-treated powder having minute vacancies among the particles in amorphous molecular aggregate particles of the metal hydroxides or metal sulfides. As for the metal hydroxides or metal sulfides, at least one kind of metal hydroxide or sulfide selected from among Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Nb and Mo is used.
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公开(公告)号:JPH1179731A
公开(公告)日:1999-03-23
申请号:JP28629597
申请日:1997-09-04
Applicant: AGENCY IND SCIENCE TECHN
Inventor: SUZUKI MASAYA , WATAMURA SHINJI , MAEDA MASAKI , INUKAI KEIICHI , OHASHI FUMIHIKO , SHIBAZAKI YASUO
Abstract: PROBLEM TO BE SOLVED: To synthesize aluminosilicate in a large amt. in a short time while suppressing energy consumption by mixing a silicon compd. soln. of high concn. and an aluminum compd. soln., dropping an alkali soln. into the mixture to neutralize, and separating and collecting a solid content produced at room temp. SOLUTION: A silicon compd. soln. of 10 to 500 mmol, and an aluminum compd. soln. of 10 to 100 mmol are mixed with 0.5 to 2.0 molar ratio of silicon/ aluminum, and then an alkali soln. is dropped into the mixture soln. by 0.5 to 2 mol/min rate to neutralize and to produce a solid content at room temp. The produced solid content is separated by filtering and with a centrifugal separating machine, then cleaned, and dried to obtain spherical aluminosilicate. The obtd. spherical aluminosilicate is a highly functional porous material having 1 to 10 nm particle diameter, >=70 m /g specific surface area by nitrogen adsorption, and 0.5 to 2.0 silicon/aluminum ratio, and can be synthesized in a large amt. at room temp.
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公开(公告)号:JPH0819722A
公开(公告)日:1996-01-23
申请号:JP30593493
申请日:1993-11-10
Applicant: AGENCY IND SCIENCE TECHN
Inventor: HORIO MASAKAZU , SUZUKI KENJI , MORI TOSHIAKI , INUKAI KEIICHI , WATAMURA SHINJI
Abstract: PURPOSE:To obtain a thermally stable separating material which can separate high temperature nitrogen and carbon dioxide by using ceramics prepared by a method in which sepiolite, after being ion-exchanged with zinc ion, is heat- treated as a separating material. CONSTITUTION:Sepiolte, a clay mineral, is added into an aqueous solution of zinc nitrate etc., and the mixture is stirred adequately and allowed to stand at room temperature so that sepiolite is ion-exchanged with zinc ion. The sepiolite is dried and heat-treated at 800 deg.C or below. When the separating material thus obtained is contacted with high temperature exhaust gas from fixed sources such as factories, nitrogen or carbon dioxide, after being adsorbed on the ceramics for the respective lengths of retention time, are desorbed. In this way, nitrogen and carbon dioxide are separated to contribute to the global environmental preservation.
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20.
公开(公告)号:JPH05178608A
公开(公告)日:1993-07-20
申请号:JP35646991
申请日:1991-12-25
Applicant: AGENCY IND SCIENCE TECHN , JINKOU NENDO GOSEI GIJUTSU KEN
Inventor: SHIBAZAKI YASUO , WATAMURA SHINJI , MIYAWAKI RITSURO , SATOKAWA SHIGEO , OSAKI YASUSHI
Abstract: PURPOSE:To provide a synthetic kaolinite uniform in particle diameter, high in crystallinity and purity. CONSTITUTION:In the objective synthetic kaolinite, >=80% of the powder has 0.4-0.7mum particle diameter in measuring particle diameter distribution, and >=300Angstrom crystalline diameter in measuring X-ray diffraction, and the impurity contained in analyzing the composition is
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