UV-CROSSLINKABLE MATERIALS BASED ON ISOAMYL (METH)ACRYLATE COPOLYMERS

    公开(公告)号:CA2000736A1

    公开(公告)日:1990-04-30

    申请号:CA2000736

    申请日:1989-10-16

    Applicant: BASF AG

    Abstract: O.Z. 0050/40301 Materials which are crosslinkable by ultraviolet radiation under atmospheric oxygen and are based on (meth)acrylate copolymers having a X value of from 10 to 100 are obtained by free radical polymerization, in the presence or absence of a solvent, of a) from 5 to 97.4% by weight of isoamyl acrylate and/or isoamyl methacrylate, b) from 0 to 89.9% by weight of (meth)acrylates whose homopolymers have a glass transition temperature below -30.degree.C, c) from 2.5 to 30% by weight of .alpha.,.beta.-monoolefinically unsaturated compounds whose homopolymers have a glass transition temperature above -30.degree.C, d) from 0 to 10% by weight of monoolefinically unsaturated acids and/or their anhydrides and e) from 0 to 20% by weight of further olefinically unsaturated monomers having one or more of the following functional groups: hydroxyl, amide, epoxide, ether, ester, urethane, urea, primary, secondary and tertiary amine and ether groups, and f) from 0.1 to 5% by weight of a copolymerizable benzophenone derivative or acetophenone derivative, the sum of the percentages by weight X (= a + b + c + d + f) being 100 in each case.

    17.
    发明专利
    未知

    公开(公告)号:FI895024A0

    公开(公告)日:1989-10-23

    申请号:FI895024

    申请日:1989-10-23

    Applicant: BASF AG

    Abstract: Compositions which can be crosslinked under an atmospheric oxygen atmosphere by means of ultraviolet irradiation and are based on (meth)acrylate copolymers having a K value of from 10 to 100, obtained by free-radical polymerisation in solid phase or solution of a) 5 to 97.4% by weight of i-amyl acrylate and/or i-amyl methacrylate and b) 0 to 89.9% by weight of (meth)acrylates whose hompolymers have a glass transition temperature of below -30 DEG C, c) 2.5 to 30% by weight of alpha , beta -monoolefinically unsaturated compounds whose homopolymers have a glass transition temperature of above - 30 DEG C, d) 0 to 10% by weight of monoolefinically unsaturated acids and/or anhydrides thereof, e) 0 to 20% by weight of further olefinically unsaturated monomers containing at least one of the following functional groups: hydroxyl, amide, epoxide, ether, ester, urethane, urea, primary, secondary or tertiary amine and ether, and f) 0.1 to 5% by weight of a copolymerisable benzophenone or acetophenone derivative, the sum of the percentages by weight x = a + b + c + d + f in each case being 100.

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