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    13.
    发明专利
    未知

    公开(公告)号：DE59913099D1

    公开(公告)日：2006-04-13

    申请号：DE59913099

    申请日：1999-07-07

    Applicant: BASF AG

    Inventor： ZHAO CHENG-LE ,  DITTRICH UWE ,  SCHWARTZ MANFRED ,  HUEMMER WOLFGANG

    IPC: C09D151/00 ,  C08F265/04 ,  C08F265/06 ,  C08F291/00 ,  C09D17/00

    Abstract: An essentially solventless pigmented aqueous formulation which comprises:i) at least one polymer A in the form of polymer particles in disperse distribution, said particles comprising,from 80 to 99.9% by weight, based on the overall weight of the polymer A, of a water-insoluble polymer 1 having a glass transition temperature Tg1 in the range from -50 to +40° C., built up from ethylenically unsaturated monomers M1, andfrom 0.1 to 20% by weight, based on the overall weight of the polymer A, of one or more water-insoluble polymers i having a glass transition temperature Tgi of more than 50° C., built up from ethylenically unsaturated monomers Mi,ii) at least one pigment and, if desired, one or more extenders.

    14.
    发明专利
    未知

    公开(公告)号：DE50011602D1

    公开(公告)日：2005-12-22

    申请号：DE50011602

    申请日：2000-04-20

    Applicant: BASF AG

    Inventor： ZHAO CHENG-LE ,  DITTRICH UWE ,  SCHWARTZ MANFRED ,  FRANZMANN GERNOT

    IPC: B05D7/24 ,  C09D5/02 ,  C09D133/06 ,  C09D133/08 ,  C09D133/10

    Abstract: An aqueous, pigmented coating material contains (i) a film-forming polymer dispersion based on 80-99.95 wt% 2-20C alkyl or 5 cycloalkyl (meth)acrylate(s), 0.05-10 wt% unsaturated carboxylic, sulfonic or phosphonic acid and optionally other monomers, (ii inorganic pigment and optional fillers and (iii) 0.05-0.3 wt% non-polymerizable photoinitiator. An aqueous, pigment-containing coating material with a pigment volume concentration of at least 10 and essentially free fro volatile organic compounds (VOC), containing (i) aqueous polymer dispersion(s) which are film-forming at room temperature, containing polymer(s) (P) derived from (A) 80-99.95 wt% (meth)acrylate esters of 2-20C alkanols or 5-10C cycloalkanols, (B) 0.05 wt% unsaturated carboxylic, sulfonic or phosphonic acid(s) and/or their salts and (C) 0-20 wt% monomers other than (A) and (B), inorganic pigment(s) and optionally inorganic or organic fillers, (iii) non-polymerizable photoinitiator(s) in amounts of betwee 0.05 and less than 0.3 wt% based on (P) and (iv) water and conventional auxiliary substances. An Independent claim is also inclu for a process for coating substrates by applying the above coating material to the substrate.

    Aqueous polymer dispersion
    15.
    发明专利
    Aqueous polymer dispersion 未知

    公开(公告)号：AU776730B2

    公开(公告)日：2004-09-23

    申请号：AU7150800

    申请日：2000-11-10

    Applicant: BASF AG

    Inventor： SANDOR MARIO ,  ZHAO CHENG-LE ,  ROCKEL HARALD ,  DITTRICH UWE

    IPC: C08F2/22 ,  C08F2/38 ,  C08F212/08 ,  C08F265/06 ,  C09D133/08 ,  C08F220/14 ,  C08F220/18 ,  C08J5/18 ,  C09D133/12

    Abstract: An aqueous polymer dispersion having a minimum film-forming temperature of below +65° C. comprising at least one film-forming polymer in the form of dispersed polymer particles comprising a polymer phase P1 and a different polymer phase P2, the polymer dispersion being obtainable by free-radical aqueous emulsion polymerization comprising the following steps: i) polymerization of a first monomer charge M1 to give a polymer P1 having a theoretical glass transition temperature Tg (according to Fox) and ii) polymerization of a second monomer charge M2 to give a polymer P2 having a theoretical glass transition temperature Tg (according to Fox) which is different from Tg in the aqueous dispersion of the polymer P1, at least one chain transfer reagent being used either in the polymerization of the monomer charge M1 or in the polymerization of the monomer charge M2; a process for preparing the aqueous polymer dispersion; and a pigmented and/or filled coating composition comprising as a binder the aqueous polymer dispersion.

    Aqueous preparations
    16.
    发明专利
    Aqueous preparations 未知

    公开(公告)号：AU758568B2

    公开(公告)日：2003-03-27

    申请号：AU4363499

    申请日：1999-05-19

    Applicant: BASF AG

    Inventor： ZHAO CHENG-LE ,  DITTRICH UWE ,  ROSER JOACHIM ,  PAKUSCH JOACHIM ,  ROCKEL HARALD

    IPC: C08L57/00 ,  C08L33/06 ,  C09D5/00 ,  C09D5/02 ,  C09D133/06 ,  C09D157/00 ,  C09D201/00

    Abstract: The present invention relates to aqueous formulations comprising:i. at least one hydrophilic particulate polymer P1, as an aqueous dispersion, composed essentially of monoethylenically unsaturated monomers having a water-solubility in the range from 10 to 100 g/l (at 25° C. and 1 bar), andii. at least one hydrophobic particulate polymer P2, as an aqueous dispersion, composed essentially of ethylenically unsaturated monomers having a water-solubility below 10 g/l (at 25° C. and 1 bar), the glass transition temperature Tg1 of the polymer P1 being less than 10 K different from the glass transition temperature Tg2 of the polymer P2.

    Multi-stage emulsion polymer for use as binder in water-based paint, comprises domains with low and high glass transition point respectively, at least one of which contains styrene and a nitrogen-containing monomer
    17.
    发明专利
    Multi-stage emulsion polymer for use as binder in water-based paint, comprises domains with low and high glass transition point respectively, at least one of which contains styrene and a nitrogen-containing monomer 未知

    公开(公告)号：DE19952671A1

    公开(公告)日：2001-05-03

    申请号：DE19952671

    申请日：1999-11-02

    Applicant: BASF AG

    Inventor： PAKUSCH JOACHIM ,  DITTRICH UWE ,  ROECKEL HARALD ,  SMITH ALAN ,  GULBINS ERICH ,  ZHUO LI

    IPC: C08F2/22 ,  C08F212/04 ,  C08F220/18 ,  C08F265/06 ,  C08F212/00 ,  C08L33/04

    Abstract: Emulsion polymers with domains (1) and (2) with glass transition points of -10 to +40 deg C and +50 to 120 deg C respectively, based on acrylic, vinylaromatic (V-Ar) and other monomers, in which (1) and/or (2) contains a nitrogen-containing coupling monomer, (1) contains at least 10 wt.% V-Ar and/or (2) contains at least 15 wt.% V-Ar and/or alkyl methacrylate. Multi-stage emulsion polymers (I) comprising (1) domain(s) with a glass transition point (Tg) of -10 to +40 deg C and (2) domain(s) with a Tg of +50 to 120 deg C in a wt. ratio of (1):(2) = (90:10)-(50:50), in which (1) contains polymerized units of (1a) 5-60 wt.% methyl and/or ethyl methacrylate (MMA/EMA), (1b) 20-80 wt.% 4-12C alkyl acrylate (Alk-A), (1c) up to 50 wt% vinylaromatics (V-Ar), (1d) 0.1-5 wt.% unsaturated carboxylic acid (USAc), (1e) up to 5 wt.% unsaturated amide (USAm) and (1f) up to 10 wt.% other unsaturated monomers (UM) and (2) contains units of (2a) up to 99.9 wt.% MMA and/or EMA, (2b) up to 99.9 wt.% V-Ar and/or 4-12C alkyl methacrylate (Alk-MA), (2c) 0.1-5 wt% USAc, (2d) up to 10 wt.% USAm and (2e) up to 10 wt.% UM. Domain(s) (1) and/or (2) also contain(s) 0.1-10 wt.% nitrogen-containing, adhesion-promoting monomer (N-A-M), while (1) contains at least 10 wt% V-Ar and/or (2) contains at least 15 wt.% V-Ar and/or Alk-MA. An Independent claim is also included for water-based paint containing (I) and pigment(s).

    Aqueous polymer preparations containing pigments
    19.
    发明专利
    Aqueous polymer preparations containing pigments 未知

    公开(公告)号：AU5033399A

    公开(公告)日：2000-02-01

    申请号：AU5033399

    申请日：1999-07-07

    Applicant: BASF AG

    Inventor： ZHAO CHENG-LE ,  DITTRICH UWE ,  SCHWARTZ MANFRED ,  HUMMER WOLFGANG

    IPC: C08F265/04 ,  C08F265/06 ,  C09D17/00 ,  C09D151/00 ,  C08F291/00

    Abstract: An essentially solventless pigmented aqueous formulation which comprises:i) at least one polymer A in the form of polymer particles in disperse distribution, said particles comprising,from 80 to 99.9% by weight, based on the overall weight of the polymer A, of a water-insoluble polymer 1 having a glass transition temperature Tg1 in the range from -50 to +40° C., built up from ethylenically unsaturated monomers M1, andfrom 0.1 to 20% by weight, based on the overall weight of the polymer A, of one or more water-insoluble polymers i having a glass transition temperature Tgi of more than 50° C., built up from ethylenically unsaturated monomers Mi,ii) at least one pigment and, if desired, one or more extenders.

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