公开(公告)号：DE10334001A1

公开(公告)日：2005-02-10

申请号：DE10334001

申请日：2003-07-25

Applicant: BASF AG

Inventor： BOEHLING RALF ,  WETTLING THOMAS ,  HEIDEMANN THOMAS ,  ULONSKA ARMIN ,  BRODHAGEN ANDREAS ,  FUNKE FRANK

IPC: C07C2/10 ,  C07C6/04 ,  C07C45/50 ,  C08F6/00 ,  C08F10/10 ,  C08F110/10 ,  C07C6/02 ,  C07C47/02 ,  C08F6/26

Abstract: Production of polyisobutene (I) from a starting 4C hydrocarbon stream (II), containing isobutene, 1-butene and 2-butene, includes: (a) distillatively separating (II) into a more volatile fraction (F1) (containing most of the isobutene and 1-butene in (II)) and a less volatile fraction (F2) (containing most of the 2-butene); and (b) subjecting the 1-butene in (F1) to chemically selective reaction and separating the reaction products from the remaining components of (F1).

公开(公告)号：ES2198995T3

公开(公告)日：2004-02-01

申请号：ES99971784

申请日：1999-11-10

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUER STEFAN ,  DIETRICH ULF

IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G1/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31

Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O,  I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.

公开(公告)号：AU2003246619A1

公开(公告)日：2004-01-23

申请号：AU2003246619

申请日：2003-06-27

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  SIEBENHAAR URSULA

IPC: C07C2/08 ,  C07C11/08 ,  C07C2/10

Abstract: Process for oligomerizing an alkene stream over a solid catalyst comprising sulfur and nickel, in which the oligomerization is carried out in two or more successive catalyst zones and the molar ratio of sulfur to nickel in the first catalyst zone is less than 0.5 and that in the last catalyst zone is 0.5 or more and, in the case of further catalyst zones between the first and last catalyst zones, the molar ratio of sulfur to nickel in each catalyst zone is not less than that in the immediately preceding catalyst zone, based on the main flow direction of the feed stream.

公开(公告)号：ES2197684T3

公开(公告)日：2004-01-01

申请号：ES99953337

申请日：1999-05-10

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  WANJEK HERBERT

IPC: B01J27/198 ,  B01J35/00 ,  B01J37/02 ,  C07D307/89

Abstract: Phthalic anhydride is prepared by catalytic gas-phase oxidation of xylene and/or naphthalene by a gas comprising molecular oxygen in a fixed bed at elevated temperature and using at least three coated catalysts arranged in superposed zones, which catalysts have a layer of catalytically active metal oxides applied to a core of support material. In the process described, the catalyst activity rises from zone to zone from the gas inlet end to the gas outlet end and the activity of the catalysts of the individual zones is set such that the least active catalyst comprises a lower amount of active composition and, if desired, additionally more alkali metal selected from the group consisting of potassium, rubidium and cesium as dopant than the catalyst of the next zone and the subsequent even more active catalyst comprises the same amount of active composition and even less alkali metal as dopant or a greater amount of active composition and, if desired, less alkali metal as dopant than the catalyst of the second zone, with further conditions.

公开(公告)号：DE10206845A1

公开(公告)日：2003-08-28

申请号：DE10206845

申请日：2002-02-19

Applicant: BASF AG

Inventor： ROEPER MICHAEL ,  STEPHAN JUERGEN ,  SCHINDLER GOETZ-PETER ,  TROPSCH JUERGEN ,  HEIDEMANN THOMAS ,  PRINZ MARTINA

IPC: C07B61/00 ,  C07C2/00 ,  C07C2/06 ,  C07C2/10 ,  C07C6/04 ,  C07C11/02 ,  C07C11/107 ,  C07C29/141 ,  C07C29/16 ,  C07C31/125 ,  C07C41/03 ,  C07C45/50 ,  C07C47/21 ,  C07C29/00 ,  C11D1/12 ,  C07H15/04 ,  C08B37/00 ,  C07C303/24 ,  C07F9/09

Abstract: Production of surfactant alcohols or their ethers by derivatization of 10-20C olefins or mixtures, comprises: (i) metathesizing a 4C olefin mixture; (ii) removing the 5-8C olefins; (iii) dimerizing the separated olefins to a 10-16C olefin mixture; (iv) derivatizing the mixture to a mixture of surfactant alcohols; and optionally (v) alkoxylating the alcohols. Production of surfactant alcohols or their ethers by derivatization of 10-20C olefins or mixtures, comprises: (i) metathesizing a 4C olefin mixture of 1-butene/2-butene ratio at least 1.2; (ii) removing the 5-8C olefins; (iii) dimerizing the separated olefins (optionally in admixture) to a 10-16C olefin mixture; (iv) derivatizing the mixture to a mixture of surfactant alcohols (optionally after fractionation); and optionally (v) alkoxylating the alcohols. Independent claims are also included for: (1) the novel olefin mixtures obtained by steps (i) - (iii) above; and (2) the novel surfactant alcohols and their alkoxylates obtained by steps (i) - (iv) and optionally also step (v) above.

公开(公告)号：DE59904460D1

公开(公告)日：2003-04-10

申请号：DE59904460

申请日：1999-05-10

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  ARNOLD HEIKO ,  HEFELE GERHARD ,  WANJEK HERBERT

IPC: C07D307/89 ,  C07C51/265 ,  C07C51/31 ,  C07C63/16

Abstract: In a process for preparing phthalic anhydride by catalytic gas-phase oxidation of o-xylene/naphthalene mixtures by molecular oxygen, use is made of a catalyst I in a first zone on the gas inlet side which makes up from 25 to 75 percent by volume of the total catalyst volume, comprising, in each case based on the catalytically active composition, from 1 to 10% by weight of vanadium oxide (calculated as V205), from 1 to 10% by weight of antimony oxide (calculated as Sb203) and from 80 to 98% by weight of titanium dioxide of the anatase type having a BET surface area of from 13 to 28 m2/g and also from 0.05 to 1% by weight of cesium (calculated as Cs) applied to a steatite support and a catalyst II in a second zone which makes up the remaining 75 to 25 percent by volume of the total catalyst volume, comprising, in each case based on the catalytically active composition, from 1 to 10% by weight of vanadium oxide (calculated as V205), from 1 to 10% by weight of antimony oxide (calculated as Sb203) and from 80 to 98% by weight of titanium dioxide of the anatase type having a BET surface area of from 13 to 28 m2/g and from 0.01 to 1% by weight of phosphorus oxide (calculated as P) and also from 0.01 to 0.2% by weight of cesium (calculated as Cs) applied to a steatite support, wherein the cesium content of the catalyst II is less than 15% by weight of the cesium content of the catalyst I and the catalyst I and the catalyst II have been prepared without addition of compounds of niobium.

公开(公告)号：DE10022103A1

公开(公告)日：2001-11-15

申请号：DE10022103

申请日：2000-05-08

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUER STEFAN ,  DIETRICH ULF ,  BECKENHAUPT VERA

IPC: B01J23/68 ,  B01J27/198 ,  C01G31/00 ,  C07C45/36 ,  C07C51/265 ,  C07C51/31 ,  C01G1/02 ,  C01B25/45 ,  C07B41/06 ,  C07B41/08 ,  C07B41/10 ,  C07C47/54 ,  C07C63/06 ,  C07D307/89

Abstract: Multi-metal oxides based on silver, vanadium and optionally other metal(s) also contain phosphorus, arsenic, antimony and/or bismuth. Multi-metal oxides consisting essentially of compounds of formula Aga-cQbMcV2Od.eH2O (I), in which a = 0.3-1.9; Q = phosphorus, arsenic, antimony and/or bismuth; b = 0.001-0.3; M = lithium, sodium, potassium, rubidium, cesium, thallium, magnesium, calcium, strontium, barium, copper, zinc, cadmium, lead, chromium, gold, aluminum, iron, cobalt, nickel and/or molybdenum; c = 0-0.5; (a-c) = not less than 0.1; d = a number determined by the valency and occurrence of elements other than oxygen; e = 0-20. The powder X-ray patterns of these oxides (I) show diffraction lines at lattice plane separations (d) of 15.23 \! 0.6, 12.16 \! 0.4, 10.68 \! 0.3, 3.41 \! 0.04, 3.09 \! 0.04, 3.02 \! 0.04, 2.36 \! 0.04 and 1.80 \! 0.04 Angstrom . Independent claims are also included for: (a) a method for the production of (I) by heating a suspension of vanadium pentoxide in a liquid with a solution of silver salt and the element Q or a compound of Q, optionally with the addition of a compound of M; (b) pre-catalysts for the production of shell catalysts for the partial gas-phase oxidation of aromatic hydrocarbons with molecular oxygen-containing gas, comprising an inert, non-porous support coated with one or more layers of (I); (c) shell catalysts for the above application, made from (I) and an inert support, in which the catalytically active material in the shell(s) contains 30-100 wt% silver-vanadium bronze(s) with an Ag:V atom ratio of 0.15-0.95 and a BET surface of 2-100 m /g; (d) a process for the production of aldehydes, carboxylic acids and/or anhydrides by partial oxidation of aromatic hydrocarbons (see above) using shell catalysts as in (c) in the presence or absence of other shell catalysts for this application containing vanadium pentoxide and anatase as active components (which are, if present, used in a combined catalyst bed).

公开(公告)号：DE10015250A1

公开(公告)日：2001-10-04

申请号：DE10015250

申请日：2000-03-28

Applicant: BASF AG

Inventor： HEIKO ARNOLD ,  FREIRE ERDBRUEGGER CRISTINA ,  HEIDEMANN THOMAS ,  MEYER GERALD ,  UNVERRICHT SIGNE ,  FRENZEL ANDREA ,  WULFF-DOERING JOACHIM ,  ANSMANN ANDREAS

IPC: B01J35/06 ,  B01J23/42 ,  B01J23/44 ,  B01J23/48 ,  B01J23/50 ,  B01J23/70 ,  B01J23/755 ,  B01J37/02 ,  C07B61/00 ,  C07C5/02 ,  C07C5/03 ,  C07C5/08 ,  C07C7/163 ,  C07C7/167 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  B01J35/02 ,  B01J23/38 ,  C07C7/148 ,  C07B35/02 ,  C07B63/00

Abstract: The invention relates to a shell catalyst with a core and at least one shell surrounding the core, said core being composed of an inert carrier material, and the at least one shell being composed of a porous carrier substance. The shell is physically adhered to the core and the at least one shell contains a catalytically active metal selected from the group of metals of the 10 and 11 group of the periodic table of elements in a finely divided form, or a precursor of the catalytically active metal in a uniformly divided form. The inventive shell catalyst is suitable for reducing unsaturated hydrocarbons and allows for better selectivities in comparison with shell catalysts known so far. The invention further relates to a method for producing the inventive shell catalyst.

公开(公告)号：BR9915227A

公开(公告)日：2001-07-31

申请号：BR9915227

申请日：1999-11-10

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  HIBST HARTMUT ,  BAUER STEFAN ,  DIETRICH ULF

IPC: C07D307/89 ,  B01J23/68 ,  B01J35/06 ,  B01J37/02 ,  C01G1/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31

Abstract: A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O,  I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.

公开(公告)号：DE19839001A1

公开(公告)日：2000-03-02

申请号：DE19839001

申请日：1998-08-27

Applicant: BASF AG

Inventor： HEIDEMANN THOMAS ,  BAUER STEFAN ,  LINDEN GERD ,  PETERSEN HERMANN

IPC: B01J23/22 ,  B01J27/198 ,  B01J37/02 ,  C07B61/00 ,  C07C51/265 ,  C07C51/31 ,  C07D307/89 ,  C07B41/10

Abstract: Shell catalyst for catalytic gaseous phase oxidation of aromatic hydrocarbons, which contains in an inert non-porous support a catalytically active material with a given content of vanadium oxide, titanium oxide, a cesium compound, a phosphorus compound and antimony oxide, wherein the catalytically active material is applied in two or more layers and wherein the outer layers have 50 to 100 % less antimony oxide content than the inner layer or layers and wherein the amount of catalytically active material of the inner layer or layers accounts for 10 to 90 % by weight of the overall amount of total catalytically active material. The invention also relates to a method for the production of said catalysts and to a method for the production of carboxylic acids and/or carboxylic acid anhydrides and especially phthalic acid anhydride using said catalysts.