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公开(公告)号:CA2442039C
公开(公告)日:2010-10-05
申请号:CA2442039
申请日:2002-03-28
Applicant: BASF AG
Inventor: AHLERS WOLFGANG , PACIELLO ROCCO , VOGT DIETER , HOFMANN PETER
IPC: B01J31/22 , C07F9/00 , B01J31/18 , B01J31/28 , C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C47/02 , C07C253/10 , C07F9/572 , C07F9/655 , C07F9/6558 , C07F9/6584 , C07F9/6596 , C07F9/74 , C07F9/92 , C07F15/00 , C07F15/06
Abstract: Disclosed are pnicogen ligand compounds of the formula I which have two pnicogen-containing groups joined to one another via a xanthene-like or triptycene-like molecular skeleton and in which at least one pyrrole group is covalently bound via its nitrogen atom to each pnicogen atom form complexes with metals of transition group VIII. These compounds are useful as catalysts for the hydroformylation of olefins. (see formula I)
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公开(公告)号:DE50204948D1
公开(公告)日:2005-12-22
申请号:DE50204948
申请日:2002-03-28
Applicant: BASF AG
Inventor: AHLERS WOLFGANG , PACIELLO ROCCO , VOGT DIETER , HOFMANN PETER
IPC: B01J31/22 , B01J31/18 , B01J31/28 , C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C47/02 , C07C253/10 , C07F9/572 , C07F9/655 , C07F9/6558 , C07F9/6584 , C07F9/6596 , C07F15/00 , C07F15/06 , C07F9/00 , C07F9/74 , C07F9/92
Abstract: Pnicogen chelate compounds which have two pnicogen-containing groups joined to one another via a xanthene-like or triptycene-like molecular skeleton and in which at least one pyrrole group is covalently bound via its nitrogen atom to each pnicogen atom form complexes with metals of transition group VIII which are useful as catalysts for the hydroformylation of olefins.
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公开(公告)号:DE50104116D1
公开(公告)日:2004-11-18
申请号:DE50104116
申请日:2001-05-11
Applicant: BASF AG
Inventor: AHLERS WOLFGANG , PACIELLO ROCCO , ROEPER MICHAEL , HOFMANN PETER , TENSFELDT MARKUS , GOETHLICH ALEXANDER
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公开(公告)号:DE50101033D1
公开(公告)日:2004-01-08
申请号:DE50101033
申请日:2001-02-09
Applicant: BASF AG
Inventor: AHLERS WOLFGANG , ROEPER MICHAEL , HOFMANN PETER , WARTH C , PACIELLO ROCCO
IPC: B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07B37/12 , C07C2/50 , C07C13/44 , C07C13/64 , C07C13/68 , C07C45/50 , C07C51/14 , C07C253/10 , C07F9/46 , C07F9/50 , C07F9/6561 , C07F9/6571 , C07F9/6574 , C07F15/00 , C07F15/04 , C07F15/06 , C08F4/42
Abstract: Diaryl-anellated bicyclo[2.2.n] compounds (I) containing phosphorus, arsenic and/or antimony are new. Diaryl-anellated bicyclo[2.2.n] compounds of formula (I), containing phosphorus, arsenic and antimony, are new: [Image] A 1>, A 2>boron (B), nitrogen (N), phosphorus (P) or CR 5>; R 5>hydrogen (H), (cyclo)alkyl or (het)aryl; X : oxygen (O), sulfur (S), NRa or a divalent bridging group; Ra : H, (cyclo)alkyl or aryl; Y 1>, Y 2>groups containing P, arsenic (As) and/or antimony (Sb) atom(s), attached to the phenyl ring directly or by an O atom; R 1>, R 2>, R 3>, R 4>H, (cyclo)alkyl, aryl, alkoxy, halogen, NE 1>E 2>, alkylene-NE 1>E 2>, trifluoromethyl (CF 3), nitro (NO 2), alkoxycarbonyl or cyano (CN); E 1>, E 2>(cyclo)alkyl or aryl. Independent claims are also included for: (a) new catalysts comprising complex(es) of a sub-group VIII metal and ligand(s) (I); (b) preparation of compounds (I).
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公开(公告)号:AT254960T
公开(公告)日:2003-12-15
申请号:AT01907517
申请日:2001-02-09
Applicant: BASF AG
Inventor: AHLERS WOLFGANG , ROEPER MICHAEL , HOFMANN PETER , WARTH DANIEL C M , PACIELLO ROCCO
IPC: B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07B37/12 , C07C2/50 , C07C13/44 , C07C13/64 , C07C13/68 , C07C45/50 , C07C51/14 , C07C253/10 , C07F9/46 , C07F9/50 , C07F9/6561 , C07F9/6571 , C07F9/6574 , C07F15/00 , C07F15/04 , C07F15/06 , C08F4/42
Abstract: Diaryl-anellated bicyclo[2.2.n] compounds (I) containing phosphorus, arsenic and/or antimony are new. Diaryl-anellated bicyclo[2.2.n] compounds of formula (I), containing phosphorus, arsenic and antimony, are new: [Image] A 1>, A 2>boron (B), nitrogen (N), phosphorus (P) or CR 5>; R 5>hydrogen (H), (cyclo)alkyl or (het)aryl; X : oxygen (O), sulfur (S), NRa or a divalent bridging group; Ra : H, (cyclo)alkyl or aryl; Y 1>, Y 2>groups containing P, arsenic (As) and/or antimony (Sb) atom(s), attached to the phenyl ring directly or by an O atom; R 1>, R 2>, R 3>, R 4>H, (cyclo)alkyl, aryl, alkoxy, halogen, NE 1>E 2>, alkylene-NE 1>E 2>, trifluoromethyl (CF 3), nitro (NO 2), alkoxycarbonyl or cyano (CN); E 1>, E 2>(cyclo)alkyl or aryl. Independent claims are also included for: (a) new catalysts comprising complex(es) of a sub-group VIII metal and ligand(s) (I); (b) preparation of compounds (I).
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公开(公告)号:CA2442039A1
公开(公告)日:2002-10-24
申请号:CA2442039
申请日:2002-03-28
Applicant: BASF AG
Inventor: PACIELLO ROCCO , AHLERS WOLFGANG , HOFMANN PETER , VOGT DIETER
IPC: B01J31/22 , B01J31/18 , B01J31/28 , C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C47/02 , C07C253/10 , C07F9/572 , C07F9/655 , C07F9/6558 , C07F9/6584 , C07F9/6596 , C07F15/00 , C07F15/06 , C07F9/00 , C07F9/74 , C07F9/92
Abstract: The invention relates to pnicogen chelate compounds that have two groups, which contain pnicogen atoms, and are bound to one another via an xanthene- like or triptycene-like molecular skeleton. At least one pyrrole group is covalently bound via its nitrogen atom to each pnicogen atom. The invention also relates to catalysts consisting of a complex of a metal from subgroup VIII with at least one pnicogen compound serving as a ligand, and to a method for hydroformylating olefins.
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公开(公告)号:AT149538T
公开(公告)日:1997-03-15
申请号:AT94921651
申请日:1994-07-16
Applicant: BASF AG
Inventor: LIPPERT FERDINAND , HOEHN ARTHUR , HOFMANN PETER
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公开(公告)号:AT287894T
公开(公告)日:2005-02-15
申请号:AT01949463
申请日:2001-07-04
Applicant: BASF AG
Inventor: KRISTEN MARC OLIVER , HOFMANN PETER , EISENTRAEGER FRANK
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公开(公告)号:DE10052462A1
公开(公告)日:2002-05-02
申请号:DE10052462
申请日:2000-10-23
Applicant: BASF AG
Inventor: AHLERS WOLFGANG , PACIELLO ROCCO , HOFMANN PETER , WARTH DANIEL
IPC: B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07B37/12 , C07C2/50 , C07C13/44 , C07C13/64 , C07C13/68 , C07C45/50 , C07C51/14 , C07C253/10 , C07F9/46 , C07F9/50 , C07F9/6561 , C07F9/6571 , C07F9/6574 , C07F15/00 , C07F15/04 , C07F15/06 , C08F4/42 , C07F9/6564 , C07F5/02 , B01J31/12 , C07C253/16 , C07C6/00 , C07C45/49 , C07F9/66
Abstract: Diaryl-anellated bicyclo(2.2.n) compounds (I) containing phosphorus, arsenic and/or antimony are new. Diaryl-anellated bicyclo(2.2.n) compounds of formula (I), containing phosphorus, arsenic and antimony, are new: A , A = boron (B), nitrogen (N), phosphorus (P) or CR ; R = hydrogen (H), (cyclo)alkyl or (het)aryl; X = oxygen (O), sulfur (S), NRa or a divalent bridging group; Ra = H, (cyclo)alkyl or aryl; Y , Y = groups containing P, arsenic (As) and/or antimony (Sb) atom(s), attached to the phenyl ring directly or by an O atom; R , R , R , R = H, (cyclo)alkyl, aryl, alkoxy, halogen, NE E , alkylene-NE E , trifluoromethyl (CF3), nitro (NO2), alkoxycarbonyl or cyano (CN); E , E = (cyclo)alkyl or aryl. Independent claims are also included for: (a) new catalysts comprising complex(es) of a sub-group VIII metal and ligand(s) (I); (b) preparation of compounds (I).
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公开(公告)号:AU3546101A
公开(公告)日:2001-08-20
申请号:AU3546101
申请日:2001-02-09
Applicant: BASF AG
Inventor: AHLERS WOLFGANG , ROPER MICHAEL , HOFMANN PETER , WARTH DANIEL C M , PACIELLO ROCCO
IPC: B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07B37/12 , C07C2/50 , C07C13/44 , C07C13/64 , C07C13/68 , C07C45/50 , C07C51/14 , C07C253/10 , C07F9/46 , C07F9/50 , C07F9/6561 , C07F9/6571 , C07F9/6574 , C07F15/00 , C07F15/04 , C07F15/06 , C08F4/42
Abstract: Diaryl-anellated bicyclo[2.2.n] compounds (I) containing phosphorus, arsenic and/or antimony are new. Diaryl-anellated bicyclo[2.2.n] compounds of formula (I), containing phosphorus, arsenic and antimony, are new: [Image] A 1>, A 2>boron (B), nitrogen (N), phosphorus (P) or CR 5>; R 5>hydrogen (H), (cyclo)alkyl or (het)aryl; X : oxygen (O), sulfur (S), NRa or a divalent bridging group; Ra : H, (cyclo)alkyl or aryl; Y 1>, Y 2>groups containing P, arsenic (As) and/or antimony (Sb) atom(s), attached to the phenyl ring directly or by an O atom; R 1>, R 2>, R 3>, R 4>H, (cyclo)alkyl, aryl, alkoxy, halogen, NE 1>E 2>, alkylene-NE 1>E 2>, trifluoromethyl (CF 3), nitro (NO 2), alkoxycarbonyl or cyano (CN); E 1>, E 2>(cyclo)alkyl or aryl. Independent claims are also included for: (a) new catalysts comprising complex(es) of a sub-group VIII metal and ligand(s) (I); (b) preparation of compounds (I).
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