公开(公告)号：JP2002308816A

公开(公告)日：2002-10-23

申请号：JP2002035329

申请日：2002-02-13

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  PACIELLO ROCCO ,  VOGT DIETER ,  DER VLUGT JARL IVAR VAN

IPC: B01J31/24 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  C07F9/145 ,  C07F9/50

Abstract: PROBLEM TO BE SOLVED: To provide an improved method for the hydroformylation of a compound having at least ethylenically unsaturated double bond. SOLUTION: The hydroformylation method uses at least one kind of a complex of a metal of VIII sub-group having at least one kind of a phosphorus- containing compound, which has two groups each having one P atom bonded to the respective phenyl rings of a molecular skeleton derived from bisphenol A, as a ligand.

公开(公告)号：WO0222261A2

公开(公告)日：2002-03-21

申请号：PCT/EP0110735

申请日：2001-09-17

Applicant: BASF AG ,  AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

CPC classification number: C07F9/65746 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/22 ,  B01J2231/321 ,  B01J2531/0266 ,  B01J2531/80 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/845 ,  C07C45/50 ,  C07F9/65522 ,  C07F9/65719 ,  C07C47/02

Abstract: The invention relates to a method for the hydroformylation of ethylenically unsaturated compounds, whereby at least one complex of a metal of subgroup VIII is used as the hydroformylation catalyst, having at least one compound containing phosphorus, arsenic, or antimony as a ligand. Each compound comprises two groups having a P, As, or Sb atom and at least two other heteroatoms, said groups being bound to a xanthene-type molecular structure. The invention also relates to novel compounds of this type and catalysts comprising at least one complex of a metal of subgroup VIII having at least one such compound as a ligand.

Abstract translation: 本发明涉及用于烯属不饱和化合物的加氢甲酰化过程中，被用作羰基化催化剂包括VIII的金属中的至少一种配合物。具有至少一个磷，砷或含锑化合物作为配体的亚组，该化合物为二P- 含有基团As或Sb原子和至少两个另外的杂原子附接至具有呫吨状分子骨架。 本发明还涉及到这种类型和催化剂包括VIII的金属中的至少一种配合物的新化合物。与作为配体的至少一个这样的化合物亚类。

公开(公告)号：ES2253552T3

公开(公告)日：2006-06-01

申请号：ES02761895

申请日：2002-03-28

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  PACIELLO ROCCO ,  VOGT DIETER ,  HOFMANN PETER

IPC: B01J31/22 ,  B01J31/18 ,  B01J31/28 ,  C07B61/00 ,  C07C29/141 ,  C07C29/16 ,  C07C31/125 ,  C07C45/50 ,  C07C47/02 ,  C07C253/10 ,  C07F9/572 ,  C07F9/655 ,  C07F9/6558 ,  C07F9/6584 ,  C07F9/6596 ,  C07F15/00 ,  C07F15/06 ,  C07F9/00 ,  C07F9/74 ,  C07F9/92

Abstract: Ligandos de quelato de pnicógeno de la fórmula general I en la que A1 y A2 significan, independientemente entre sí, O, S, SiRaRb, NRc o CRdRe, donde Ra, Rb y Rc significan, independientemente entre sí, hidrógeno, alquilo, cicloalquilo, heterocicloalquilo, arilo o hetarilo, Rd y Re significan, independientemente entre sí, hidrógeno, alquilo, cicloalquilo, heterocicloalquilo, arilo o hetarilo o el grupo Rd forma junto con otro grupo Rd o el grupo Re forma junto con otro grupo Re un grupo de puente D intramolecular, significa un grupo de puente con dos enlaces, elegido entre los grupos en los cuales R9 y R10 significan, independientemente entre sí, hidrógeno, alquilo, cicloalquilo, arilo, halógeno, triflúormetilo, carboxilo, carboxilato o ciano o están enlazados entre sí a través de un puente de alquileno con 3 a 4 átomos de carbono, R11, R12, R13 y R14 significan, independientemente entre sí, hidrógeno, alquilo, cicloalquilo, arilo, halógeno, triflúormetilo, COOH, carboxilato, ciano, alcoxi,SO3H, sulfonato, NE1E2, alquileno-NE1E2E3+X-, acilo o nitro, c significa 0 o 1, Y significa un enlace químico, R5, R6, R7 y R8 significan, independientemente entre sí, hidrógeno, alquilo, cicloalquilo, heterocicloalquilo, arilo, hetarilo, COORf, COO-M+, SO3Rf, SO33M+, NE1E2, NE1E2E3+X-, alquileno-NE1E2E3+X-, ORf, SRf, (CHRgCH2O)x Rf, (CH2N(E1))xRf, (CH2CH2N(E1))xRf, halógeno, triflúormetilo, nitro, acilo o ciano, donde Rf, E1, E2 y E3 significan restos respectivamente iguales o diferentes elegidos entre hidrógeno, alquilo, cicloalquilo o arilo, Rg significa hidrógeno, metilo o etilo, M+ significa un catión.

公开(公告)号：AU1225002A

公开(公告)日：2002-03-26

申请号：AU1225002

申请日：2001-09-17

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

Abstract: In a process for the hydroformylation of ethylenically unsaturated compounds, at least one complex of a metal of transition group VIII. with at least one phosphorus-, arsenic- or antimony-containing compound as ligand is used as hydroformylation catalyst, where the compound used as ligand in each case comprises two groups which comprise a P, As or Sb atom and at least two further hetero atoms and are bound to a xanthene-like molecular framework. New compounds of this type and catalysts which comprise at least one complex of a metal of transition group VIII. with at least one such compound as ligand are also provided.

公开(公告)号：ES2241884T3

公开(公告)日：2005-11-01

申请号：ES01980398

申请日：2001-09-17

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

Abstract: Procedimiento para el hidroformilado, empleándose como catalizador de hidroformilado al menos un complejo de un metal del grupo secundario VIII con al menos un ligando, que es seleccionado entre compuestos de la fórmula general I. donde A1 y A2, independientemente entre sí, representan O, S, SiRaRb, NRc o CR5R6, representando Ra, Rb, Rc, R5 y R6, independientemente entre sí, hidrógeno, alquilo, cicloalquilo, arilo o hetarilo, Y1 e Y2, independientemente entre sí, representan respectivamente un resto de la fórmula OP(OR7) (OR8), donde R7 y R8, independientemente entre sí, representan alquilo, cicloalquilo, arilo o hetarilo, que presentan, en caso dado, uno, dos o tres substituyentes seleccionados entre alquilo, cicloalquilo, arilo, het arilo, COORf, COO-M+, SO3Rf, SO-3M+, NE4E5, alquilen-NE4E5, NE4E5E6+X-, alquilen-NE4E5E6+X-, ORf, SRf, (CHRgCH2O)yRf, (CH2N(E4))yRf, (CH2CH2N(E4))yRf, halógeno, trifluormetilo, nitro, acilo o ciano.

公开(公告)号：DE50106337D1

公开(公告)日：2005-06-30

申请号：DE50106337

申请日：2001-09-17

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

Abstract: In a process for the hydroformylation of ethylenically unsaturated compounds, at least one complex of a metal of transition group VIII. with at least one phosphorus-, arsenic- or antimony-containing compound as ligand is used as hydroformylation catalyst, where the compound used as ligand in each case comprises two groups which comprise a P, As or Sb atom and at least two further hetero atoms and are bound to a xanthene-like molecular framework. New compounds of this type and catalysts which comprise at least one complex of a metal of transition group VIII. with at least one such compound as ligand are also provided.

公开(公告)号：DE10046025A1

公开(公告)日：2002-03-28

申请号：DE10046025

申请日：2000-09-18

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  BARTSCH MICHAEL ,  KUNSMANN-KEITEL DAGMAR PASCAL ,  HADERLEIN GERD ,  SIEGEL WOLFGANG ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J23/755 ,  B01J31/18 ,  B01J31/24 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  B01J31/12 ,  C07F15/04

Abstract: Production of adiponitrile from butadiene and hydrogen cyanide uses a catalyst comprising a Group VIII metal complex having at least one tricyclic bifunctional phosphorus, arsenic or antimony ligand. Production of adiponitrile by: (a) reacting butadiene with hydrogen cyanide in the presence of a catalyst, (b) optionally catalytically isomerizing the resulting mixture of pentenonitriles to covert branched nitriles to linear nitriles, and (c) reacting the nitrile mixture with hydrogen cyanide in the presence of a catalyst comprises performing steps (a), (b) and/or (c) in the presence of a catalyst comprising a Group VIII metal complex having at least one ligand of formula (I). A , A = O, Si, SiRR, NR or CRR; R = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; Y , Y = groups comprising one or more P, As or Sb atoms, each directly bonded to at least two O, S or NR' heteroatoms; R' = H, alkyl, cycloalkyl or aryl; R -R = R, COOR', COOM, SO2R', SO3M, N(R')2, N(R')3 X , OR', SR', (CHR''CH2O)xR', (CH2NR')xR', (CH2CH2NR')xR', halogen, CF3, NO2, acyl or CN, or R and/or R can form fused ring systems with 1-3 rings; R = H, Me or Et; M = a cation; X = an anion; x = 1-120. An Independent claim is also included for a process for isomerizing branched aliphatic monoalkenonitriles to linear aliphatic monoalkenonitriles using such a catalyst.

公开(公告)号：CA2442039C

公开(公告)日：2010-10-05

申请号：CA2442039

申请日：2002-03-28

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  PACIELLO ROCCO ,  VOGT DIETER ,  HOFMANN PETER

IPC: B01J31/22 ,  C07F9/00 ,  B01J31/18 ,  B01J31/28 ,  C07B61/00 ,  C07C29/141 ,  C07C29/16 ,  C07C31/125 ,  C07C45/50 ,  C07C47/02 ,  C07C253/10 ,  C07F9/572 ,  C07F9/655 ,  C07F9/6558 ,  C07F9/6584 ,  C07F9/6596 ,  C07F9/74 ,  C07F9/92 ,  C07F15/00 ,  C07F15/06

Abstract: Disclosed are pnicogen ligand compounds of the formula I which have two pnicogen-containing groups joined to one another via a xanthene-like or triptycene-like molecular skeleton and in which at least one pyrrole group is covalently bound via its nitrogen atom to each pnicogen atom form complexes with metals of transition group VIII. These compounds are useful as catalysts for the hydroformylation of olefins. (see formula I)

公开(公告)号：DE50204948D1

公开(公告)日：2005-12-22

申请号：DE50204948

申请日：2002-03-28

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  PACIELLO ROCCO ,  VOGT DIETER ,  HOFMANN PETER

IPC: B01J31/22 ,  B01J31/18 ,  B01J31/28 ,  C07B61/00 ,  C07C29/141 ,  C07C29/16 ,  C07C31/125 ,  C07C45/50 ,  C07C47/02 ,  C07C253/10 ,  C07F9/572 ,  C07F9/655 ,  C07F9/6558 ,  C07F9/6584 ,  C07F9/6596 ,  C07F15/00 ,  C07F15/06 ,  C07F9/00 ,  C07F9/74 ,  C07F9/92

Abstract: Pnicogen chelate compounds which have two pnicogen-containing groups joined to one another via a xanthene-like or triptycene-like molecular skeleton and in which at least one pyrrole group is covalently bound via its nitrogen atom to each pnicogen atom form complexes with metals of transition group VIII which are useful as catalysts for the hydroformylation of olefins.

公开(公告)号：CA2442039A1

公开(公告)日：2002-10-24

申请号：CA2442039

申请日：2002-03-28

Applicant: BASF AG

Inventor： PACIELLO ROCCO ,  AHLERS WOLFGANG ,  HOFMANN PETER ,  VOGT DIETER

IPC: B01J31/22 ,  B01J31/18 ,  B01J31/28 ,  C07B61/00 ,  C07C29/141 ,  C07C29/16 ,  C07C31/125 ,  C07C45/50 ,  C07C47/02 ,  C07C253/10 ,  C07F9/572 ,  C07F9/655 ,  C07F9/6558 ,  C07F9/6584 ,  C07F9/6596 ,  C07F15/00 ,  C07F15/06 ,  C07F9/00 ,  C07F9/74 ,  C07F9/92

Abstract: The invention relates to pnicogen chelate compounds that have two groups, which contain pnicogen atoms, and are bound to one another via an xanthene- like or triptycene-like molecular skeleton. At least one pyrrole group is covalently bound via its nitrogen atom to each pnicogen atom. The invention also relates to catalysts consisting of a complex of a metal from subgroup VIII with at least one pnicogen compound serving as a ligand, and to a method for hydroformylating olefins.