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公开(公告)号:DE3045719A1
公开(公告)日:1982-07-08
申请号:DE3045719
申请日:1980-12-04
Applicant: BASF AG
Inventor: GOETZ NORBERT DIPL CHEM DR , JACOBS PETER DIPL CHEM DR , HUPFER LEOPOLD DIPL CHEM DR , TOUSSAINT HERBERT DIPL CHEM DR , REISS WOLFGANG DIPL CHEM DR
IPC: C07B61/00 , B01J21/00 , B01J23/00 , B01J23/44 , B01J23/56 , B01J23/58 , B01J23/63 , B01J23/89 , B01J27/00 , B01J29/00 , C07C67/00 , C07C209/00 , C07C209/16 , C07C209/18 , C07C209/26 , C07C209/68 , C07C209/72 , C07C211/16 , C07C211/46 , C07C211/47 , C07C213/02 , C07C85/06 , C07C87/34 , C07C87/50 , C07C87/64
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公开(公告)号:DE3027889A1
公开(公告)日:1982-03-11
申请号:DE3027889
申请日:1980-07-23
Applicant: BASF AG
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公开(公告)号:DE3027269A1
公开(公告)日:1982-03-04
申请号:DE3027269
申请日:1980-07-18
Applicant: BASF AG
Inventor: GRAMLICH WALTER DIPL CHEM DR , HOFFMANN WERNER DIPL CHEM DR , HUPFER LEOPOLD DIPL CHEM DR , MEISSNER BERND DIPL CHEM DR , PAETSCH JUERGEN DIPL CHEM DR
IPC: C07C29/17 , C07C29/38 , C07C29/40 , C07C31/02 , C07C31/125 , C07C33/02 , C07C33/03 , C07C33/04 , C07C33/042 , C07C33/048 , C07C69/145 , C11B9/00 , C07C33/48 , C11D3/50 , C11D9/44
Abstract: 3,6-Dimethyl-3-hydroxy-oct-1-ynes and -oct-1-enes and their esters with lower alkanoic acids, of the general formula I (I) where X and Y are H or the two X's and/or the two Y's together are a further bond between the carbon atoms on which they are present, and R is H, -CO-CH3, -CO-C2H5 or -CO-C3H7, their use as scents, and a process for the preparation of 3,6-dimethyl-3-hydroxy-octane. The novel compounds exhibit interesting, predominantly floral, woody, herbal and fruity notes. The alcohols of the formula I are of particular importance because they serve as intermediates for a novel and particularly advantageous method of obtaining 3,6-dimethyl-3-hydroxy-octane, a compound required in large amounts as a fragrance for soaps and detergents.
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公开(公告)号:DE2914646A1
公开(公告)日:1980-11-13
申请号:DE2914646
申请日:1979-04-11
Applicant: BASF AG
IPC: C07D295/02 , B01J23/44 , C07B61/00 , C07D205/04 , C07D207/06 , C07D207/08 , C07D211/14 , C07D223/04 , C07D265/30 , C07D295/023 , C07D227/02
Abstract: Prepn. of aralkylamines of formula (I) by reacting a sec. amine of formula (II) with a carbonyl cpd. of formula (III) is effected in presence of hydrogen and a hydrogenation catalyst consisting of (a) platinum, (b) zinc, cadmium, manganese and/or a rare earth metal oxide, on (c) an inert carrier. (R1 is H, 1-10C aliphatic gp., 5-7C cycloaliphatic gp. or 1-6C alkoxy; A is -(CHX5)n-, -CHX6-N(X7)-CHX8- or -CHX9-O-CHX10-; R2-R4 and X1-X10 are H or 1-4C alkyl; n is 2, 3 or 4; the dotted line in (III) is an optional double bond).
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公开(公告)号:DE2830998A1
公开(公告)日:1980-01-31
申请号:DE2830998
申请日:1978-07-14
Applicant: BASF AG
IPC: C07D265/30 , B01J23/44 , B01J23/63 , B01J23/68 , B01J23/755 , B01J27/16 , C07B61/00 , C07D295/02 , C07D295/027
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公开(公告)号:DE2646379A1
公开(公告)日:1978-04-27
申请号:DE2646379
申请日:1976-10-14
Applicant: BASF AG
Inventor: DECKER MARTIN DIPL CHEM DR , HOFFMANN HERWIG DIPL CHEM DR , HUPFER LEOPOLD DIPL CHEM DR , TOUSSAINT HERBERT DIPL CHEM DR
IPC: C07C209/18 , C07C87/62 , C07C85/06
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公开(公告)号:DE3219355A1
公开(公告)日:1983-11-24
申请号:DE3219355
申请日:1982-05-22
Applicant: BASF AG
Abstract: Process for the preparation of pyruvic acid by oxidising methylglyoxal in aqueous solution with bromine.
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公开(公告)号:DE3027890A1
公开(公告)日:1982-03-04
申请号:DE3027890
申请日:1980-07-23
Applicant: BASF AG
Inventor: MERGER FRANZ DIPL CHEM DR , MIESEN ERNEST DIPL ING , BROECKER FRANZ JOSEF DIPL CHEM , SCHROEDER WOLFGANG DIPL CHEM D , BAER KARL DIPL CHEM DR , PAETSCH JUERGEN DIPL CHEM DR , HUPFER LEOPOLD DIPL CHEM DR
IPC: C07C29/14 , B01J23/00 , B01J23/72 , B01J35/02 , C07B61/00 , C07C27/00 , C07C29/141 , C07C31/20 , C07C67/00
Abstract: Hydrogenation catalysts, which have a specific surface area of from 50 to 150 square meters per gram, solely or partially contain crystals having a spinel structure and copper in the form of copper oxide, and have been obtained by precipitating copper and aluminum in a ratio of from 0.25 to 3 atoms of copper per atom of aluminum from their compounds in the presence of a carbonate at a pH of from 4.5 to 9 and calcining the resulting precipitate at from 300 DEG to 800 DEG C., for the catalytic preparation of propanediols by hydrogenating hydroxypropionaldehydes at not more than 300 bar pressure and from 50 DEG to 200 DEG C., and processes for the preparation of propanediols by the use of such catalysts. The propanediols obtainable by the process of the invention, in particular 2,2-dimethylpropane-1,3-diol, are valuable starting materials for the preparation of lubricants, plastics, surface coatings and synthetic resins, for example corresponding polyesters.
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公开(公告)号:DE2940709A1
公开(公告)日:1981-04-16
申请号:DE2940709
申请日:1979-10-08
Applicant: BASF AG
Inventor: GRAF FRITZ DIPL CHEM DR , HUPFER LEOPOLD DIPL CHEM DR
IPC: C07D233/54 , C07D233/58 , C07D233/60 , C07D233/61 , C07D233/64 , C07D521/00
Abstract: A process for the preparation of 1-substituted imidazoles by reacting an alpha -dicarbonyl compound with ammonia, an aldehyde and a primary amine in an aqueous medium, in a single stage, at 20 DEG -150 DEG C.
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公开(公告)号:DE2932712A1
公开(公告)日:1981-03-26
申请号:DE2932712
申请日:1979-08-13
Applicant: BASF AG
Inventor: HUPFER LEOPOLD DIPL CHEM DR , GRAF FRITZ DIPL CHEM DR , EBERHARD PETER DIPL CHEM DR , WICKENHAEUSER GERHARD DIPL ING , SCHLUETER LOTHAR DIPL ING DR
IPC: C07D233/58 , C07D233/54
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