公开(公告)号：DE2833991A1

公开(公告)日：1980-02-21

申请号：DE2833991

申请日：1978-08-03

Applicant: BASF AG

Inventor： PERNER JOHANNES DIPL CHEM DR ,  STOECKIGT DIETER ING GRAD ,  DIESSEL PAUL ING GRAD ,  MERGER FRANZ DIPL CHEM DR ,  PAETSCH JUERGEN DIPL CHEM DR

IPC: C11D3/20

公开(公告)号：DE2453284A1

公开(公告)日：1976-05-20

申请号：DE2453284

申请日：1974-11-09

Applicant: BASF AG

Inventor： NEUMAYR FRANZ DIPL CHEM DR ,  DECKER MARTIN DIPL CHEM DR ,  PAETSCH JUERGEN DIPL CHEM DR

IPC: C07D319/12 ,  C07C68/02 ,  C07C69/96 ,  C07D323/00

公开(公告)号：DE3027889A1

公开(公告)日：1982-03-11

申请号：DE3027889

申请日：1980-07-23

Applicant: BASF AG

Inventor： BROECKER FRANZ JOSEF DIPL CHEM ,  HUPFER LEOPOLD DIPL CHEM DR ,  MERGER FRANZ DIPL CHEM DR ,  MIESEN ERNEST DIPL ING ,  PAETSCH JUERGEN DIPL CHEM DR ,  ZIRKER GUENTER DIPL CHEM DR

IPC: C07C29/14 ,  B01J23/00 ,  B01J23/80 ,  C07B61/00 ,  C07C27/00 ,  C07C29/141 ,  C07C31/20 ,  C07C31/27 ,  C07C33/26 ,  C07C67/00

公开(公告)号：DE3027269A1

公开(公告)日：1982-03-04

申请号：DE3027269

申请日：1980-07-18

Applicant: BASF AG

Inventor： GRAMLICH WALTER DIPL CHEM DR ,  HOFFMANN WERNER DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR ,  MEISSNER BERND DIPL CHEM DR ,  PAETSCH JUERGEN DIPL CHEM DR

IPC: C07C29/17 ,  C07C29/38 ,  C07C29/40 ,  C07C31/02 ,  C07C31/125 ,  C07C33/02 ,  C07C33/03 ,  C07C33/04 ,  C07C33/042 ,  C07C33/048 ,  C07C69/145 ,  C11B9/00 ,  C07C33/48 ,  C11D3/50 ,  C11D9/44

Abstract: 3,6-Dimethyl-3-hydroxy-oct-1-ynes and -oct-1-enes and their esters with lower alkanoic acids, of the general formula I (I) where X and Y are H or the two X's and/or the two Y's together are a further bond between the carbon atoms on which they are present, and R is H, -CO-CH3, -CO-C2H5 or -CO-C3H7, their use as scents, and a process for the preparation of 3,6-dimethyl-3-hydroxy-octane. The novel compounds exhibit interesting, predominantly floral, woody, herbal and fruity notes. The alcohols of the formula I are of particular importance because they serve as intermediates for a novel and particularly advantageous method of obtaining 3,6-dimethyl-3-hydroxy-octane, a compound required in large amounts as a fragrance for soaps and detergents.

公开(公告)号：DE2346309A1

公开(公告)日：1975-04-03

申请号：DE2346309

申请日：1973-09-14

Applicant: BASF AG

Inventor： DATOW JOACHIM DIPL ING DR ,  WINDERL SIEGFRIED DIPL CHEM DR ,  MERKEL KARL DR ,  TOUSSAINT HERBERT DIPL CHEM DR ,  PAETSCH JUERGEN DIPL CHEM DR ,  HOFFMANN HERWIG DIPL CHEM DR

IPC: C07C69/96 ,  C07C68/02

公开(公告)号：DE3027890A1

公开(公告)日：1982-03-04

申请号：DE3027890

申请日：1980-07-23

Applicant: BASF AG

Inventor： MERGER FRANZ DIPL CHEM DR ,  MIESEN ERNEST DIPL ING ,  BROECKER FRANZ JOSEF DIPL CHEM ,  SCHROEDER WOLFGANG DIPL CHEM D ,  BAER KARL DIPL CHEM DR ,  PAETSCH JUERGEN DIPL CHEM DR ,  HUPFER LEOPOLD DIPL CHEM DR

IPC: C07C29/14 ,  B01J23/00 ,  B01J23/72 ,  B01J35/02 ,  C07B61/00 ,  C07C27/00 ,  C07C29/141 ,  C07C31/20 ,  C07C67/00

Abstract: Hydrogenation catalysts, which have a specific surface area of from 50 to 150 square meters per gram, solely or partially contain crystals having a spinel structure and copper in the form of copper oxide, and have been obtained by precipitating copper and aluminum in a ratio of from 0.25 to 3 atoms of copper per atom of aluminum from their compounds in the presence of a carbonate at a pH of from 4.5 to 9 and calcining the resulting precipitate at from 300 DEG to 800 DEG C., for the catalytic preparation of propanediols by hydrogenating hydroxypropionaldehydes at not more than 300 bar pressure and from 50 DEG to 200 DEG C., and processes for the preparation of propanediols by the use of such catalysts. The propanediols obtainable by the process of the invention, in particular 2,2-dimethylpropane-1,3-diol, are valuable starting materials for the preparation of lubricants, plastics, surface coatings and synthetic resins, for example corresponding polyesters.

公开(公告)号：DE2834073A1

公开(公告)日：1980-02-28

申请号：DE2834073

申请日：1978-08-03

Applicant: BASF AG

Inventor： PERNER JOHANNES DIPL CHEM DR ,  DIESSEL PAUL ING GRAD ,  STOECKIGT DIETER ING GRAD ,  MERGER FRANZ DIPL CHEM DR ,  PAETSCH JUERGEN DIPL CHEM DR

IPC: C11D3/20

Abstract: A method for regulating the viscosity of aqueous detergent and cleanser slurries, in which there are added to the slurries, as viscosity regulators, dihydric, trihydric or tetrahydric aliphatic alcohols, monobasic aliphatic carboxylic acids, hydroxycarboxylic acids, esters of the said alcohols and the said acids or mixtures of these, in which compounds the alcohols, carboxylic acids and hydroxycarboxylic acids, and the individual components of the esters, are of 5 to 9 carbon atoms, of which one is a quaternary atom, the alcohols and hydroxycarboxylic acids carry exclusively primary alcohol groups, and the carboxylic acids and hydroxycarboxylic acids have the carboxyl group bonded to the quaternary carbon atom.

公开(公告)号：DE2819593A1

公开(公告)日：1979-11-08

申请号：DE2819593

申请日：1978-05-05

Applicant: BASF AG

Inventor： HERRMANN GUENTER DIPL ING DR ,  FROMMER ELMAR DIPL CHEM DR ,  PAETSCH JUERGEN DIPL CHEM DR ,  REISS WOLFGANG DIPL CHEM DR ,  WINDERL SIEGFRIED DIPL CHEM DR

IPC: C07C29/149 ,  C07C31/20 ,  C07C29/00

Abstract: H3PO4 or a phosphate ester is added to 6 C mono- and/or dicarboxylic acids, esp. the acid mixts. obtd. as by-prods. in cyclohexane oxidn. to cyclohexanone, before their hydrogenation to 6 C alpha, omega-diols. Phosphoric acid or phosphate quantity added may be 10-100 ppm. w.r.t. aq. solns. The phosphates may be derived from 1-20 C alcohols. The formation of residues, i.e. 'cork' formation, causing clogging of plant, is prevented.