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公开(公告)号:AT241595T
公开(公告)日:2003-06-15
申请号:AT99104113
申请日:1999-03-02
Applicant: BASF AG
Inventor: KOKEL NICOLAS DR , HAEBERLE KARL DR , KRAUS RUPERT DR
IPC: C07C267/00 , C07C271/10 , C07C271/20 , C07C275/00 , C07C275/04
Abstract: Carbodiimides which are solid at 25 degrees C, containing carbodiimide structures which are attached to non-aromatic carbon atoms, together with urethane and/or urea structures. Independent claims are also included for: (a) a process for the production of these solid carbodiimides from di-isocyanates in which the isocyanate (NCO) groups are not attached to aromatic carbon, by reaction in presence of catalysts to form the carbodiimide with cleavage of carbon dioxide, followed by reaction with compounds containing at least two NCO-reactive groups; (b) another process in which the above stages are reversed and the ratio of NCO groups to NCO-reactive groups used in the first stage is at least 2:1; (c) solid carbodiimides obtained by these processes; (d) mixtures containing compounds with ester units together with these carbodiimides; and (e) mixtures containing these carbodiimides and at least one of the following: polyurethanes with ester units and/or polycondensation products such as polyesters, e.g. polyethylene- or polybutylene- terephthalate, polyether-esters, polyester-esters, polyester-amides, polycaprolactones, unsaturated polyester resins and polyamides.
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公开(公告)号:DE19719925A1
公开(公告)日:1998-11-19
申请号:DE19719925
申请日:1997-05-13
Applicant: BASF AG
Inventor: KOKEL NICOLAS DR , REICHERT ANKE DR , GULBINS ERICH DR
IPC: C08F283/00 , C08G18/08 , C08G18/12 , C08G18/66 , C09D175/04 , C08G18/10 , C08G18/32 , C08G18/38 , C08L75/12 , C09D175/00 , C09J175/12
Abstract: The use of special amines (B) for the production of low-viscosity aqueous dispersions of amino group-containing polyurethanes (amino-PUR) comprises reacting (A) polyurethane(s) with isocyanate function(s) with (B) and dispersing the system in water before or after reaction. (B) comprise amines with only one primary and one secondary amino group, no tertiary amino groups and no hydroxyl groups, or ketimine derivatives obtained by reacting such amines with ketones.
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公开(公告)号:DE19647982A1
公开(公告)日:1998-05-28
申请号:DE19647982
申请日:1996-11-21
Applicant: BASF AG
Inventor: KOKEL NICOLAS DR , GULBINS ERICH DR , RAU MARIA GYOPAR DR , FISCHER GERHARD
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公开(公告)号:DE59905693D1
公开(公告)日:2003-07-03
申请号:DE59905693
申请日:1999-03-02
Applicant: BASF AG
Inventor: KOKEL NICOLAS DR , HAEBERLE KARL DR , KRAUS RUPERT DR
IPC: C07C267/00 , C07C271/10 , C07C271/20 , C07C275/00 , C07C275/04
Abstract: Carbodiimides which are solid at 25 degrees C, containing carbodiimide structures which are attached to non-aromatic carbon atoms, together with urethane and/or urea structures. Independent claims are also included for: (a) a process for the production of these solid carbodiimides from di-isocyanates in which the isocyanate (NCO) groups are not attached to aromatic carbon, by reaction in presence of catalysts to form the carbodiimide with cleavage of carbon dioxide, followed by reaction with compounds containing at least two NCO-reactive groups; (b) another process in which the above stages are reversed and the ratio of NCO groups to NCO-reactive groups used in the first stage is at least 2:1; (c) solid carbodiimides obtained by these processes; (d) mixtures containing compounds with ester units together with these carbodiimides; and (e) mixtures containing these carbodiimides and at least one of the following: polyurethanes with ester units and/or polycondensation products such as polyesters, e.g. polyethylene- or polybutylene- terephthalate, polyether-esters, polyester-esters, polyester-amides, polycaprolactones, unsaturated polyester resins and polyamides.
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公开(公告)号:DE19719924A1
公开(公告)日:1998-11-19
申请号:DE19719924
申请日:1997-05-13
Applicant: BASF AG
Inventor: KOKEL NICOLAS DR
Abstract: A process for the production of storage-stable aqueous dispersions of amino group-containing polyurethane(s) (PUR) comprises reacting: (a) PUR which is largely self-dispersible in water and contains isocyanate function(s) plus anionic group(s) or groups which can be converted into anionic groups by neutralisation, with (b) amine(s) with at least two sec. amine groups and less than 23 carbon atoms, containing no prim. amino groups and with a continuous chain of at least 3 C atoms between the sec. amino groups, and dispersing the system in water before or after reaction.
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公开(公告)号:DE19714514A1
公开(公告)日:1998-10-15
申请号:DE19714514
申请日:1997-04-08
Applicant: BASF AG
Inventor: KOKEL NICOLAS DR , GANS HELMUT , WEGENER STEFAN DR
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公开(公告)号:ES2207880T3
公开(公告)日:2004-06-01
申请号:ES99107086
申请日:1999-04-12
Applicant: BASF AG
Inventor: BOLLMANN HEINZ , HABERLE KARL DR , KOKEL NICOLAS DR , THARIGEN RAINA
IPC: C08G18/08 , C07C267/00 , C07C271/20 , C08G18/02 , C08G18/28 , C08G18/38 , C08G18/79 , C08G18/80 , C08K5/29 , C08L75/06 , C09K15/18
Abstract: Carbodiimides based on 1,3-bis(1-methyl-1-isocyanatoethyl)benzene contain from 12 to 40% by weight of ethylene oxide units ¢-CH2-CH2-O-!, based on the weight of the carbodiimides.
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公开(公告)号:ES2201580T3
公开(公告)日:2004-03-16
申请号:ES99104113
申请日:1999-03-02
Applicant: BASF AG
Inventor: KOKEL NICOLAS DR , HABERLE KARL DR , KRAUS RUPERT DR
IPC: C07C267/00 , C07C271/10 , C07C271/20 , C07C275/00 , C07C275/04
Abstract: Carbodiimides which are solid at 25 degrees C, containing carbodiimide structures which are attached to non-aromatic carbon atoms, together with urethane and/or urea structures. Independent claims are also included for: (a) a process for the production of these solid carbodiimides from di-isocyanates in which the isocyanate (NCO) groups are not attached to aromatic carbon, by reaction in presence of catalysts to form the carbodiimide with cleavage of carbon dioxide, followed by reaction with compounds containing at least two NCO-reactive groups; (b) another process in which the above stages are reversed and the ratio of NCO groups to NCO-reactive groups used in the first stage is at least 2:1; (c) solid carbodiimides obtained by these processes; (d) mixtures containing compounds with ester units together with these carbodiimides; and (e) mixtures containing these carbodiimides and at least one of the following: polyurethanes with ester units and/or polycondensation products such as polyesters, e.g. polyethylene- or polybutylene- terephthalate, polyether-esters, polyester-esters, polyester-amides, polycaprolactones, unsaturated polyester resins and polyamides.
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公开(公告)号:DE59906922D1
公开(公告)日:2003-10-16
申请号:DE59906922
申请日:1999-04-12
Applicant: BASF AG
Inventor: BOLLMANN HEINZ , HAEBERLE KARL DR , KOKEL NICOLAS DR , THAERIGEN RAINA
IPC: C08G18/08 , C07C267/00 , C07C271/20 , C08G18/02 , C08G18/28 , C08G18/38 , C08G18/79 , C08G18/80 , C08K5/29 , C08L75/06 , C09K15/18
Abstract: Carbodiimides based on 1,3-bis(1-methyl-1-isocyanatoethyl)benzene contain from 12 to 40% by weight of ethylene oxide units ¢-CH2-CH2-O-!, based on the weight of the carbodiimides.
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公开(公告)号:ES2138405T3
公开(公告)日:2000-01-01
申请号:ES97101241
申请日:1997-01-28
Applicant: BASF AG
Inventor: KOKEL NICOLAS DR , HABERLE KARL DR , BEUTLER KUNO , REICHERT JURGEN DR , WEYLAND PETER DR , DRALLE-VOSS GABRIELE DR
IPC: B05D7/12 , B32B27/40 , C08G18/08 , C08G18/10 , C08G18/34 , C08G18/42 , C08G18/66 , C08G18/68 , C08L75/00 , C08L75/04 , C09D175/00 , C09D175/04 , C09J175/00 , C09J175/04
Abstract: Aqueous dispersions (AD) containing a polyurethane (PU) derived from (a) 4-30C di-isocyanates, (b) diol(s), of which (b1) 10-100 mole% have a mol. wt. of 500-5000 and are derived from (b1.1) (4-30C alkyl and/or alkenyl)-succinic acid, (b1.2) 0-60 mole% (based on b1.1) of another dicarboxylic acid and (b1.3) a diol with a mol. wt. of 60-500, (b2) 0-90 mole% have a mol. wt. of 60-500 and (b3) 0-90 mole% are diol(s) other than (b1.1) with a mol. wt. of 500-5000, (c) monomers other than (a) and (b) with two isocyanate (NCO) groups or two NCO-reactive groups and also one hydrophilic or potentially hydrophilic group to confer water-dispersibility on the PU, (d) optionally multifunctional compounds other than (a)-(c) with reactive alcoholic hydroxyl, primary or secondary amino, or NCO groups, and (e) optionally mono-functional compounds other than (a)-(c) with one reactive group as in (d). Also claimed are articles of leather, paper, textiles, plastics or metal, coated or adhesively bonded with (AD).
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