公开(公告)号：DE10151559A1

公开(公告)日：2003-04-30

申请号：DE10151559

申请日：2001-10-23

Applicant: BASF AG

Inventor： ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN

IPC: B01J37/18 ,  B01J23/745 ,  B01J23/889 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  B01J23/76 ,  C07B43/04 ,  C07C255/58

Abstract: The iron-containing catalyst suitable for use as a catalyst contains a) iron or a mixture containing iron and an iron-based compound. The iron has an average crystallite size ranging from 1-35 nm measured by X-ray diffraction.

公开(公告)号：BR0110452A

公开(公告)日：2003-03-11

申请号：BR0110452

申请日：2001-04-30

Applicant: BASF AG

Inventor： OHLBACH FRANK ,  WINTERLING HELMUT ,  ANSMANN ANDREAS ,  FISCHER ROLF-HARTMUTH ,  MELDER JOHANN-PETER ,  MAIXNER STEFAN ,  BASSLER PETER ,  LUYKEN HERMANN

IPC: C08J5/18 ,  C08G69/04 ,  C08G69/14 ,  C08G69/16

Abstract: A process for preparing a polymer, which comprisesa) reacting a mixture (I) containing 6-aminocapronitrile and water in the presence of a catalyst to obtain a mixture (II) containing caprolactam, ammonia, water, high boilers and low boilers, thenb) removing ammonia from mixture (II) to obtain a mixture (III) containing caprolactam, water, high boilers and low boilers, thenc) removing all or some of the water from mixture (III) to obtain a mixture (IV) containing caprolactam, high boilers and low boilers and thend) feeding mixture (IV) to a polymerization reaction, and also the polymer obtainable by this process, the use of the polymer for producing fibers, sheetlike structures and moldings, and also fibers, sheetlike structures and moldings obtainable using such a polymer.

公开(公告)号：CA2407813A1

公开(公告)日：2002-10-30

申请号：CA2407813

申请日：2001-04-30

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  OHLBACH FRANK ,  BASSLER PETER ,  ANSMANN ANDREAS ,  MELDER JOHANN-PETER ,  MAIXNER STEFAN ,  LUYKEN HERMANN

IPC: C07D223/10 ,  C07B61/00 ,  C07D201/08 ,  C07D207/263 ,  C07D211/76 ,  C07D225/02

Abstract: The invention relates to a method for producing cyclic lactams of the formul a (II), wherein n and m may each represent 0, 1, 2, 3, 4, 5, 6, 7, 8 and 9 and the sum of n + m is at least 3, preferably at least 4, R1 and R2 represent C 1- C6 alkyl, C5-C7 cycloalkyl or C6-C12 aryl groups, by reacting a compound of the formula (I), wherein R1, R2, m and n have the meaning indicated above, a nd R represents nitrile groups, carboxylic acid amide groups and carboxylic aci d groups, with water vapor in the gaseous phase. The inventive method is furth er characterized in that a) the compound (I) is reacted with water vapor in the gaseous phase, adding an organic diluent (III) before or after the reaction, which diluent has a miscibility gap under certain quantitative, pressure and temperature conditions, said reaction resulting in a mixture (IV) that contains a lactam (II), b) adjusting the mixture (IV) before or after the removal of ammonia to quantitative, pressure and temperature conditions unde r which the diluent (III) and water are present in a liquid form and have a miscibility gap, and obtaining a two-phase system consisting of a phase (V) that has a higher proportion of diluent (III) than water, and a phase (VI) that has a higher proportion of water than diluent (III), c) separating phas e (V) fromphase (VI) and, d) removing from phase (V) the diluent (III) and optionally by-products selected from the group of the low-boilers, high- boilers and unreacted compound (I), and obtaining a lactam (II).

公开(公告)号：CA2505359C

公开(公告)日：2011-02-01

申请号：CA2505359

申请日：2003-11-11

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  ANSMANN ANDREAS ,  BENISCH CHRISTOPH ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MAIXNER STEFAN ,  MELDER JOHANN-PETER

IPC: C07D201/16 ,  C07D201/08

Abstract: The invention relates to a method for purifying crude caprolactam that has been obtained by: 1) reacting a mixture (I) containing 6-aminocapronitrile and water to form a mixture (II) containing caprolactam, ammonia, water, high boilers and low boilers in the presence of a catalyst followed by; 2) removing ammonia from mixture (II) while obtaining a mixture (III) that contains caprolactam, water, high boilers and low boilers, after which; 3) water is entirely or partially removed from mixture (III) while obtaining a crude caprolactam (IV) that contains caprolactam, high boilers and low boilers. The inventive method is characterized in that: a) the crude caprolactam and an inorganic acid, which has a boiling point higher that that of caprolactam under distillation conditions in accordance with subsequent steps b) to h), are fed to a first distillation device K1; b) the crude caprolactam and the inorganic acid are distilled in the first distillation device K1 during which a first partial flow in the bottom area and a second partial flow in the top area are withdrawn from the distillation device K1; c) the second partial flow from step b) is fed to a second distillation device K2; d) the second partial flow from step b) is distilled in the second distillation device K2 during which a first partial flow in the bottom area and a second partial flow in the top area are withdrawn from the distillation device K2; e) a first partial flow from step d) is fed to a third distillation device K3; f) the first partial flow from step d) is distilled in the third distillation device K3 during which a first partial flow in the bottom area and purified caprolactam in the top area are withdrawn from the distillation device K3, and; g) the first partial flow from step f) is fed to the first distillation device K1.

公开(公告)号：CA2485077C

公开(公告)日：2010-05-18

申请号：CA2485077

申请日：2003-05-21

Applicant: BASF AG

Inventor： MAIXNER STEFAN ,  BENISCH CHRISTOPH ,  LUYKEN HERMANN ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MELDER JOHANN-PETER ,  ANSMANN ANDREAS

IPC: C07C253/34 ,  C07C209/84 ,  C07C211/09 ,  C07C211/12 ,  C07C255/09 ,  C07C255/24

Abstract: The invention relates to a method for reducing the content of an aliphatic, monounsaturated amine (IV) in a mixture (V) containing an aminonitrile (I) or a diamine (II) or a dinitrile (III) or mixtures thereof and amine (IV), whereby: a) mixture (V) is reacted with an anionic nucleophile (VI) in a quantity ranging from 0.01 to 10 mols per mol of amine (IV) in mixture (V) at a temperature ranging from 50 to 200 ~C while obtaining mixture (VII), and; b) amino nitrile (I) or diamine (II) or dinitrile (III) or mixtures thereof are removed by distillation from mixture (VII) at a temperature ranging from 50 to 200 ~C and under a pressure ranging from 0.1 to 100 kPa while obtaining a bottom product (VIII). The inventive method is characterized in that: c) an amino nitrile (I) or diamine (II) or dinitrile (III) or mixtures thereof are removed by distillation from bottom product (VIII) at a temperature which is lower than that selected in step b).

公开(公告)号：CA2430063C

公开(公告)日：2009-04-28

申请号：CA2430063

申请日：2001-11-29

Applicant: BASF AG

Inventor： FISCHER ROLF-HARTMUTH ,  ANSMANN ANDREAS ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN ,  MAIXNER STEFAN ,  BASSLER PETER ,  OHLBACH FRANK ,  BENISCH CHRISTOPH

IPC: C07C253/34 ,  C07C209/84 ,  C07C211/09 ,  C07C255/24

Abstract: The invention relates to a method for reducing the content of an aliphatic, monounsaturated amine (III) in a mixture (IV) containing an aminonitrile (I) or a diamine (II), or mixtures thereof and an amine (III). Said method is characterised in that a) mixture (IV) is reacted with an anionic nucleophile (V) in a quantity ranging between 0.01 and 10 mol per mol of amine (III) in mixture (IV) to obtain a mixture (VI). The invention is also characterised i n that b) aminonitrile (I) or diamine (II) or mixtures thereof are removed by distillation from mixture (VI), at a temperature ranging between 50 and 170 ~C and a pressure of between 0.5 and 100 kPa.

公开(公告)号：CA2407812C

公开(公告)日：2008-12-02

申请号：CA2407812

申请日：2001-04-30

Applicant: BASF AG

Inventor： MAIXNER STEFAN ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  ANSMANN ANDREAS ,  MELDER JOHANN-PETER ,  LUYKEN HERMANN ,  OHLBACH FRANK

IPC: C07D201/08 ,  C07D223/10 ,  C07D201/16

Abstract: The invention relates to a method for producing cyclic lactams of formula (I I) by reacting a compound (I) of formula (I) with water in the presence of an organic, liquid dilution agent in the liquid phase. In formula (II), n and m respectively can have the values 0, 1, 2, 3, 4, 5, 6, 7, 8 and 9 and the sum of n + m is at least 3, preferably at least 4 and R1 and R2 represent C1-C6 alkyl, C5-C7 cycloalkyl or C6-C12 aryl groups. In formula (I), R1, R2, m and n are defined as above and R represents nitrile, carboxylic acid amide and carboxylic acid groups. The inventive method is characterized in that a) compound (I) is reacted with water in the liquid phase in the presence of an organic, liquid dilution agent (III) to form a mixture (IV) containing a lactam (II) and said mixture (IV) is subjected to an aqueous treatment to obtain a two-phase system.

公开(公告)号：AT372317T

公开(公告)日：2007-09-15

申请号：AT05700737

申请日：2005-01-07

Applicant: BASF AG

Inventor： KNOESCHE CARSTEN ,  SOHN MARTIN ,  PENZEL ULRICH ,  PALLASCH HANS-JUERGEN ,  GEORGI GUNTER ,  MACKENROTH WOLFGANG ,  SCHWARZ HANS VOLKMAR ,  MAIXNER STEFAN ,  MOLZ GERALD ,  STROEFER ECKHARD

IPC: C07C209/84 ,  C07C211/50

Abstract: The invention relates to a process for distillatively preparing TDA from a reactant stream comprising TDA, high boilers and low boilers in a dividing wall column in which a dividing wall is disposed in the longitudinal direction of the column to form an upper combined column region ( 2 ), a lower combined column region ( 3 ), a feed section ( 4 ) having a rectifying section ( 5 ) and stripping section ( 6 ), and also a withdrawal section ( 7 ) having a rectifying section ( 9 ) and stripping section ( 8 ), which comprises the following steps: a. feeding the reactant stream ( 13 ) into the feed section ( 4 ) of the dividing wall column ( 1 ); b. drawing off a low boiler fraction via the top of the column ( 11 ); c. drawing off TDA via a side draw ( 14 ) in the withdrawal section ( 7 ) of the dividing wall column ( 1 ); d. drawing off a low boiler fraction via the bottom of the column ( 12 ).

公开(公告)号：DE102004001456A1

公开(公告)日：2005-08-11

申请号：DE102004001456

申请日：2004-01-08

Applicant: BASF AG

Inventor： KNOESCHE CARSTEN ,  SOHN MARTIN ,  PENZEL ULRICH ,  PALLASCH HANS-JUERGEN ,  GEORGI GUNTER ,  MACKENROTH WOLFGANG ,  SCHWARZ HANS VOLKMAR ,  MAIXNER STEFAN ,  MOLZ GERALD ,  STROEFER ECKHARD

IPC: C07C209/84 ,  C07C211/50

Abstract: The invention relates to a process for distillatively preparing TDA from a reactant stream comprising TDA, high boilers and low boilers in a dividing wall column in which a dividing wall is disposed in the longitudinal direction of the column to form an upper combined column region ( 2 ), a lower combined column region ( 3 ), a feed section ( 4 ) having a rectifying section ( 5 ) and stripping section ( 6 ), and also a withdrawal section ( 7 ) having a rectifying section ( 9 ) and stripping section ( 8 ), which comprises the following steps: a. feeding the reactant stream ( 13 ) into the feed section ( 4 ) of the dividing wall column ( 1 ); b. drawing off a low boiler fraction via the top of the column ( 11 ); c. drawing off TDA via a side draw ( 14 ) in the withdrawal section ( 7 ) of the dividing wall column ( 1 ); d. drawing off a low boiler fraction via the bottom of the column ( 12 ).

公开(公告)号：BR0311251A

公开(公告)日：2005-03-15

申请号：BR0311251

申请日：2003-05-21

Applicant: BASF AG

Inventor： MAIXNER STEFAN ,  BENISCH CHRISTOPH ,  LUYKEN HERMANN ,  BASSLER PETER ,  FISCHER ROLF-HARTMUTH ,  MELDER JOHANN-PETER ,  ANSMANN ANDREAS

IPC: C07C209/84 ,  C07C211/09 ,  C07C211/12 ,  C07C253/34 ,  C07C255/09 ,  C07C255/24

Abstract: A process for reducing the level of an aliphatic monounsaturated amine (IV) in a mixture (V) containing an aminonitrile (I) or a diamine (II) or a dinitrile (III) or mixtures thereof as well as said mine (IV) by a) reacting said mixture (V) with an anionic nucleophile (VI) which contains a nucleophilic atom selected from the group consisting of oxygen, nitrogen and sulfur, which is capable of taking up an H + ion to form an acid having a pK a value in the range from 7 to 11, as measured in water at 25° C., and which has a relative nucleophilicity, as measured in methyl perchlorate/methanol at 25° C., in the range from 3.4 to 4.7 when said nucleophilic atom is oxygen, in the range from 4.5 to 5.8 when said nucleophilic atom is nitrogen, and in the range from 5.5 to 6.8 when said nucleophilic atom is sulfur, in an amount in the range from 0.01 to 10 mol per mole of said amine (IV) in said mixture (V) at a temperature in the range from 50 to 200° C. to obtain a mixture (VII), b) distilling said aminonitrile (I) or said diamine (II) or said dinitrile (III) or mixtures thereof from said mixture (VII) at a temperature in the range from 50 to 200° C. and at a pressure in the range from 0.1 to 100 kPa to obtain a bottom product (VIII), which comprises c) distilling an aminonitrile (I) or diamine (II) or dinitrile (III) or mixtures thereof from said bottom product (VIII) at a temperature which is lower than that chosen in step b).