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公开(公告)号：DE3137824A1
公开(公告)日：1983-03-31
申请号：DE3137824
申请日：1981-09-23
Applicant: BASF AG
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公开(公告)号：DE3132218A1
公开(公告)日：1983-03-03
申请号：DE3132218
申请日：1981-08-14
Applicant: BASF AG
IPC: C23C14/14 , B01J31/22 , C08K5/00 , C23C18/16 , C23C18/31 , C23C18/34 , C23C18/38 , C23C18/44 , C23C18/52 , C23C20/02 , C25D5/56 , H01L31/00 , H05K1/03 , H05K3/18 , C23C3/02 , H01L31/18 , B01J31/26 , G11C11/21
Abstract: A process for depositing metals onto electrically conductive, polymeric carriers, wherein a finely divided metal M having a standard potential Eo of >-2 V is deposited, from a solution of a metal cation compound of the formula (I) Ml'Lm1Ln2Lo3Lp4 (I) where M', L1, L2, L3, L4, l, m, n, o, and p are as defined in the claims, in an aprotic polar or non-polar solvent, onto a polymeric, electrically conductive carrier of the formula (II) [My''(P)]x (II) where M'' is Li, Na, K, Rb or Cs, P is P=-CH-, -C6H4-, -C4H2S-, -C6H4S-, -C4H2O-, -C4H2NH- -C6H4O- or -C5H3N- y is from 0.001 to 0.6 and x is from 5 to 1,000, or onto a polymeric, electrically conductive carrier of the formula (III) [(P)(X)y]x (III) where P is one of the groups listed for formula (II), X is ClO4(-), AsF6(-), PF6(-), SbF6(-), BF4(-), HSO4(-), CF3SO3(-) or Br(-), y is from 0.001 to 0.6 and x is from 5 to 1,000, by reduction, preferably at from -100 DEG to +100 DEG C. The electrically conductive, polymeric systems can be employed in the electrical industry for the production of solar cells, for converting and fixing radiation, and for the production of electric and magnetic switches and electrical storage devices, and can also be used as heterogeneous catalysts and to provide an antistatic finish on plastics.
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公开(公告)号：DE3226780A1
公开(公告)日：1983-02-10
申请号：DE3226780
申请日：1982-07-17
Applicant: BASF AG
Abstract: The invention relates to a process for the preparation of electrically conductive polyaromatics; in which the polyaromatics are treated with 0.5 to 5% by weight of a strong Lewis acid having pks values from -10 to +4, with the exclusion of aqueous moisture and of oxygen, and in which the polyaromatics used are compounds having conjugated pi -systems in which at least two polyene chains of the formula (I) and (II): in which n = 1 to 100 and m = 0 to 50 run in parallel. Suitable polyaromatics are quarterylene, quinquerylene, sesquicylene or dianthracene. The electrically conductive polyaromatics can be used in electrical engineering for the production of solar cells, for the conversion and fixation of radiation, for the preparation of electrical and magnetic switches and electrical memories and for the antistatic finishing of plastics.
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公开(公告)号：DE3200073A1
公开(公告)日：1982-08-12
申请号：DE3200073
申请日：1982-01-05
Applicant: BASF AG
Inventor： NAARMANN HERBERT DIPL CHEM DR , MUENCH VOLKER DIPL CHEM DR , PENZIEN KLAUS DIPL CHEM DR , NAEGELE DIETER DIPL CHEM DR , SCHLAG JOHANNES DIPL PHYS DR
IPC: C08F4/06 , C08F38/00 , C08L49/00 , H01B1/12 , H01L51/30 , C08F138/00 , C08F132/06 , C08F138/02 , C08L47/00 , H01L31/04
Abstract: The invention relates to a process for the preparation of electroconductive polymers by polymerisation of acetylene and derivatives of acetylene, and of polycyclic aromatic compounds at temperatures of from -200 to +50 DEG C in the presence of an oxidising Lewis acid in amounts of from 1 to 50 % by weight. The oxidising Lewis acid may be a mixture of a cationic catalyst and a gaseous oxidant or a compound from groups VI-VIII and the subgroups of the Periodic Table of the Elements and/or a combination of Lewis acids from groups III to VI and from the subgroups of the Periodic Table of the Elements with auxiliary oxidants from groups V-VIII and from the subgroups of the Periodic Table of the Elements, and preferably acts on thin films of the monomers to be polymerised. The electroconductive polymers prepared can be used in electrical engineering for the production of solar cells, for the conversion and fixation of radiation, for the production of electrical and magnetic switches and for the antistatic finishing of plastics.
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Patent Agency Ranking
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公开(公告)号：DE3212925A1
公开(公告)日：1983-10-13
申请号：DE3212925
申请日：1982-04-07
Applicant: BASF AG
Inventor： HAMBRECHT JUERGEN DIPL CHEM DR , NAARMANN HERBERT DIPL CHEM DR , MUENCH VOLKER DIPL CHEM DR , BRANDT HERMANN DIPL ING DR , SWOBODA JOHANN DIPL CHEM DR
IPC: C08G65/44
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公开(公告)号：DE3148149A1
公开(公告)日：1983-06-09
申请号：DE3148149
申请日：1981-12-05
Applicant: BASF AG
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公开(公告)号：DE3139958A1
公开(公告)日：1983-04-28
申请号：DE3139958
申请日：1981-10-08
Applicant: BASF AG
Inventor： HAMBRECHT JUERGEN DIPL CHEM DR , MUENCH VOLKER DIPL CHEM DR , NAARMANN HERBERT DIPL CHEM DR , BRANDSTETTER FRANZ DIPL CHEM D , BOEHLKE KLAUS DIPL CHEM DR
Abstract: Self-extinguishing thermoplastic moulding compositions based on styrene polymers, polyphenylene ethers and polymeric organophosphorus compounds containing phosphorus in the polymer chain in an oxidation state of +3 and having a number average molecular weight Mn of
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公开(公告)号：DE3140448A1
公开(公告)日：1983-04-21
申请号：DE3140448
申请日：1981-10-12
Applicant: BASF AG
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