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    Process for the preparation of acylphosphine oxides
    1.
    发明专利
    Process for the preparation of acylphosphine oxides 未知

    公开(公告)号：DE3139984A1

    公开(公告)日：1983-04-28

    申请号：DE3139984

    申请日：1981-10-08

    Applicant: BASF AG

    Inventor： HENNE ANDREAS DIPL CHEM DR

    IPC: C07F9/53 ,  C07F9/32

    Abstract: The invention relates to a process for the preparation of acylphosphine oxides of the formula in which R and/or R represent an alkyl, cyclohexyl, cyclopentyl, phenyl, substituted thienyl, pyrrolyl, pyridyl or phenyl radical or R represents an alkoxy, aryloxy or arylalkoxy radical, R represents a tertiary alkyl radical, a tertiary cycloalkyl radical or a thienyl, pyrrolyl, furyl, pyridyl, phenyl or naphthyl radical, which may carry halogen, alkyl, alkylthio, alkoxy, cycloalkyl or phenyl groups, by reaction of an acid halide of the formula in which X represents Cl or Br, with an alkoxyphosphine of the formula in which R represents an alkyl or cycloalkyl radical, at 20 to 150 DEG C, if desired in the presence of an inert organic solvent and a tertiary amine. The acylphosphine oxides prepared according to the invention are suitable as photoinitiators.

    Process for the preparation of di-(2-subst.-1-aryl) alkoxyphosphines
    2.
    发明专利
    Process for the preparation of di-(2-subst.-1-aryl) alkoxyphosphines 未知

    公开(公告)号：DE3201424A1

    公开(公告)日：1982-12-09

    申请号：DE3201424

    申请日：1982-01-19

    Applicant: BASF AG

    Inventor： HENNE ANDREAS DIPL CHEM DR

    IPC: C07F9/46

    Abstract: The invention relates to the preparation of di-(2-subst.-1-aryl) alkoxyphosphines (R is an organic radical which is inert to Grignard compounds; R is C1-C6-alkyl or C5-C6-cycloalkyl and, if desired, further inert substituents on the phenyl group Ph) by reacting a phosphite II P(-O-R )3 II with a Grignard compound III (Hal is chlorine, bromine or iodine). The invention furthermore relates to the novel compounds I where R is C1-C4-alkyl or C2-C4-alkoxy; R is C1-C4-alkyl and one of the specific radicals R is present on Ph as further substituent.

    Acylphosphine compounds
    4.
    发明专利
    Acylphosphine compounds 未知

    公开(公告)号：DE3212926A1

    公开(公告)日：1983-10-13

    申请号：DE3212926

    申请日：1982-04-07

    Applicant: BASF AG

    Inventor： HENNE ANDREAS DIPL CHEM DR ,  HESSE ANTON DIPL CHEM DR

    IPC: C07F9/30 ,  C07F9/40 ,  C08F2/50 ,  G03F7/029

    Abstract: Acylphosphine compounds of the formula Ia X is oxygen, sulphur or an electron pair, R is R or OR , R is -OM where M = metal cation or ammonium cation, R is a tertiary alkyl radical or cycloalkyl radical or a phenyl radical which is only substituted in one ortho-position to the carbonyl group, R is hydrogen, or an alkyl or aryl radical. The acylphosphine compounds are highly effective photoinitiators for photopolymerisable materials, such as coating compositions, paints, printing inks, unsaturated polyesters, recording materials and, preferably, aqueous polymer dispersions or solutions.

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