公开(公告)号：DE3818868A1

公开(公告)日：1989-12-14

申请号：DE3818868

申请日：1988-06-03

Applicant: BASF AG

Inventor： AUWETER HELMUT DR ,  NUBER ADOLF DR ,  TSCHANG CHUNG-JI DR ,  SANNER AXEL DR

IPC: C08F2/24 ,  C08F212/08

Abstract: The invention relates to a specific method of polymerisation for preparing a very cloudy aqueous dispersion of a polymer composed of 10 to 40% by weight of N-vinylpyrrolidone and 90 to 60% by weight of styrene, which is sedimentation-resistant in water and ethanol.

公开(公告)号：DE3642633A1

公开(公告)日：1988-06-23

申请号：DE3642633

申请日：1986-12-13

Applicant: BASF AG

Inventor： NUBER ADOLF DR ,  DENZINGER WALTER ,  SANNER AXEL DR

IPC: C08F2/10 ,  C08F2/38 ,  C08F4/28 ,  C08F4/34 ,  C08F26/10 ,  C08F26/08

Abstract: Hydrazine-free vinlypyrrolidone polymers which dissolve in water and organic solvents to give a clear solution are prepared by polymerization using di-tert-butyl peroxide in an aqueous medium.

公开(公告)号：AT163915T

公开(公告)日：1998-03-15

申请号：AT95108201

申请日：1995-05-30

Applicant: BASF AG

Inventor： REICH WOLFGANG DR ,  BECK ERICH DR ,  KEIL EDMUND ,  ERHARDT ULRICH DR ,  NUBER ADOLF DR

IPC: C08F20/26 ,  C07C67/08 ,  C07C67/26 ,  C07C67/60 ,  C07C69/54 ,  C08F2/46 ,  C08F2/48 ,  C08F290/00 ,  C08F299/02 ,  C08G59/17 ,  C08G63/47

Abstract: The prodn. of radiation-curable acrylates comprises (1) reaction of hydroxy cpds. with (meth)acrylic acid followed by (2) reaction with peroxide cpds. in presence of quat. ammonium or phosphonium cpds. of formula (I) or (II) as catalysts: X = counter-ion; R -R = 1-18C alkyl (opt. substd. with 1 or 2 Ph gps.) or 6-12C aryl (opt. substd. with 1 or 2 1-6C alkyl gps.). Also claimed are curable acrylates (A) obtd. by this process, and radiation-curable prepns. (B) contg. (A) and an isocyanate cpd. with at least 2 NCO gps. for subsequent crosslinking, pref. in amts. of 0.05-30 wt.%.

公开(公告)号：DE59102717D1

公开(公告)日：1994-10-06

申请号：DE59102717

申请日：1991-06-19

Applicant: BASF AG

Inventor： LANG REINHARD DR ,  BECK ERICH DR ,  KEIL EDMUND ,  NUBER ADOLF DR ,  PETERSEN HARRO DR ,  RENZ HANS DR ,  SCHMIDT HORST DR ,  WEISS WOLFRAM DR

IPC: C08F299/02 ,  C08F290/00 ,  C08F290/14 ,  C08G12/40 ,  C08G12/42 ,  C08G14/12 ,  C09D161/00 ,  C09D161/34

公开(公告)号：DE3778606D1

公开(公告)日：1992-06-04

申请号：DE3778606

申请日：1987-08-08

Applicant: BASF AG

Inventor： NUBER ADOLF DR ,  SANNER AXEL DR ,  VOGEL FRIEDRICH DR ,  MASS DIETRICH

IPC: A61K8/00 ,  A61K8/34 ,  A61K8/41 ,  A61K8/81 ,  A61Q5/06 ,  C08F20/26 ,  C08F26/10 ,  C08F220/00 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F220/12 ,  C08F220/26 ,  C08F220/28 ,  C08F220/54 ,  C08F220/56 ,  C08F226/10 ,  A61K7/11

Abstract: Copolymer (I) for use as hair fixative is obtd. by free radical polymerisation of (A) 20-60 (wt)% vinyl-pyrrolidone (II), (B) 20-60% N-mono- or di-alkylated acrylamide(s) (III) with 1-8C alkyl gp(s), (C) 5-60% 1-4 C-alkyl or 2-4C hydroxyalkyl (meth)acrylate(s) (IV) or 3-12% (meth)acrylic acid (V) and opt. 2-48% (IV). (I) is soluble in 1-4C alcohols and has a K value of 15-75. (I) is prepd. from 30-50% (II), 30-50%(III) and 20-40% (IV) or 5-10% (V) and opt. 15-35% (IV) and has a K value of 20-50. 50-100% of the free COOH gps. in (I) are neutralised with a 2-9C mono-, di- or trialkanolamine. The hair fixative contains 0.5-5, esp. 1.0-5.0% (I), pref. together with 50-75% solvent and 25-50% propellant gas.

公开(公告)号：DE3768588D1

公开(公告)日：1991-04-18

申请号：DE3768588

申请日：1987-08-29

Applicant: BASF AG

Inventor： NUBER ADOLF DR ,  SANNER AXEL DR ,  URBAN DIETER DR

IPC: B01D15/00 ,  C08F6/00 ,  C08F6/10 ,  C08F26/10

Abstract: Vinylpyrrolidone is removed from its polymers by a process in which an aqueous or alcoholic solution of the polymer is treated with an adsorbent, the adsorbents used preferably being active carbon, zeolites and especially acidic ion exchangers.

公开(公告)号：DE3627969A1

公开(公告)日：1988-02-25

申请号：DE3627969

申请日：1986-08-18

Applicant: BASF AG

Inventor： NUBER ADOLF DR ,  SANNER AXEL DR ,  VOGEL FRIEDRICH DR ,  MASS DIETRICH

IPC: A61K8/00 ,  A61K8/34 ,  A61K8/41 ,  A61K8/81 ,  A61Q5/06 ,  C08F20/26 ,  C08F26/10 ,  C08F220/00 ,  C08F220/04 ,  C08F220/06 ,  C08F220/10 ,  C08F220/12 ,  C08F220/26 ,  C08F220/28 ,  C08F220/54 ,  C08F220/56 ,  C08F226/10 ,  C08F220/18 ,  A61K7/11

Abstract: Copolymers of vinylpyrrolidone, acrylamides which are monoalkylated or dialkylated on the N atom and alkyl or hydroxyalkyl esters of (meth)acrylic acid, with or without (meth)acrylic acid, or (meth)acrylic acid are used as and in hair fixatives.

公开(公告)号：DE59501588D1

公开(公告)日：1998-04-16

申请号：DE59501588

申请日：1995-05-30

Applicant: BASF AG

Inventor： REICH WOLFGANG DR ,  BECK ERICH DR ,  KEIL EDMUND ,  ERHARDT ULRICH DR ,  NUBER ADOLF DR

IPC: C08F20/26 ,  C07C67/08 ,  C07C67/26 ,  C07C67/60 ,  C07C69/54 ,  C08F2/46 ,  C08F2/48 ,  C08F290/00 ,  C08F299/02 ,  C08G59/17 ,  C08G63/47

Abstract: The prodn. of radiation-curable acrylates comprises (1) reaction of hydroxy cpds. with (meth)acrylic acid followed by (2) reaction with peroxide cpds. in presence of quat. ammonium or phosphonium cpds. of formula (I) or (II) as catalysts: X = counter-ion; R -R = 1-18C alkyl (opt. substd. with 1 or 2 Ph gps.) or 6-12C aryl (opt. substd. with 1 or 2 1-6C alkyl gps.). Also claimed are curable acrylates (A) obtd. by this process, and radiation-curable prepns. (B) contg. (A) and an isocyanate cpd. with at least 2 NCO gps. for subsequent crosslinking, pref. in amts. of 0.05-30 wt.%.

公开(公告)号：DE4420012A1

公开(公告)日：1995-12-14

申请号：DE4420012

申请日：1994-06-08

Applicant: BASF AG

Inventor： REICH WOLFGANG DR ,  BECK ERICH DR ,  KEIL EDMUND ,  ERHARDT ULRICH DR ,  NUBER ADOLF DR

IPC: C08F20/26 ,  C07C67/08 ,  C07C67/26 ,  C07C67/60 ,  C07C69/54 ,  C08F2/46 ,  C08F2/48 ,  C08F290/00 ,  C08F299/02 ,  C08G59/17 ,  C08G63/47 ,  C08F20/28 ,  C08F20/32 ,  C08L67/07

Abstract: The prodn. of radiation-curable acrylates comprises (1) reaction of hydroxy cpds. with (meth)acrylic acid followed by (2) reaction with peroxide cpds. in presence of quat. ammonium or phosphonium cpds. of formula (I) or (II) as catalysts: X = counter-ion; R -R = 1-18C alkyl (opt. substd. with 1 or 2 Ph gps.) or 6-12C aryl (opt. substd. with 1 or 2 1-6C alkyl gps.). Also claimed are curable acrylates (A) obtd. by this process, and radiation-curable prepns. (B) contg. (A) and an isocyanate cpd. with at least 2 NCO gps. for subsequent crosslinking, pref. in amts. of 0.05-30 wt.%.

公开(公告)号：AT61594T

公开(公告)日：1991-03-15

申请号：AT87112626

申请日：1987-08-29

Applicant: BASF AG

Inventor： NUBER ADOLF DR ,  SANNER AXEL DR ,  URBAN DIETER DR

IPC: B01D15/00 ,  C08F6/00 ,  C08F6/10 ,  C08F26/10