公开(公告)号：DE19631522A1

公开(公告)日：1998-02-05

申请号：DE19631522

申请日：1996-08-03

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PACIELLO ROCCO DR ,  ROEPER MICHAEL PROF DR ,  SCHNURR WERNER DR

IPC: B01J23/44 ,  B01J23/46 ,  B01J23/75 ,  C07B61/00 ,  C07C209/48 ,  C07C209/60 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07C209/24

Abstract: The invention concerns a process for preparing 6-aminocapronitrile or 6-aminocapronitrile-hexamethylene diamine mixtures by: a) reacting 5-formylvaleronitrile with ammonia and hydrogen in the presence of hydrogenation catalysts selected from the group comprising metals or metal compounds of rhenium, copper and elements of the eight subgroups, a hydrogenation discharge product being obtained; and b) extracting from the hydrogenation discharge product 6-aminocapronitrile and optionally hexamethylene diamine, provided that the hydrogenation catalyst does not contain copper, nickel or copper and nickel as its only components.

公开(公告)号：ES2102567T3

公开(公告)日：1997-08-01

申请号：ES93114394

申请日：1993-09-08

Applicant: BASF AG

Inventor： KNEUPER HEINZ-JOSEF DR ,  ROEPER MICHAEL PROF DR ,  PACIELLO ROCCO DR

IPC: C07B61/00 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02

Abstract: Process for the preparation of aldehydes by the hydroformylation of olefins having more than 7 carbon atoms, comprising the stage of hydroformylation by means of a rhodium catalyst dissolved in homogeneous reaction medium, the separation of the rhodium catalyst from the material discharged from the hydroformylation reaction and the recycling of the rhodium separated from the material discharged from the hydroformylation to the hydroformylation stage, in which the rhodium catalyst is extracted into the aqueous phase from the material discharged from the hydroformylation by means of an aqueous solution of a nitrogen-containing complexing agent from the group consisting of the optionally substituted pyridines, quinolines, 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2''-terpyridines and porphines which are sulphonated or carry sulphonated substituents, and/or from the group consisting of the carboxylated pyridines, the carboxylated quinolines, the optionally substituted 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2''-terpyridines and porphines which are carboxylated or carry carboxylated substituents, and the aqueous, rhodium-containing extract is recycled to the hydroformylation stage.

公开(公告)号：DE4321194A1

公开(公告)日：1995-01-05

申请号：DE4321194

申请日：1993-06-25

Applicant: BASF AG

Inventor： PACIELLO ROCCO DR ,  ROEPER MICHAEL PROF DR ,  KNEUPER HEINZ-JOSEF DR ,  LANGGUTH ERNST DR ,  LORZ PETER MICHAEL DR

IPC: B01J31/28 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  C07F9/6571 ,  C07F9/6574 ,  C07F15/00

Abstract: PCT No. PCT/EP94/01999 Sec. 371 Date Aug. 7, 1995 Sec. 102(e) Date Aug. 7, 1995 PCT Filed Jun. 20, 1994 PCT Pub. No. WO95/00525 PCT Pub. Date Jan. 5, 1995Phosphorus-containing calixarenes of the general formula I I and a process for their preparation are described. Additionally, a process for the preparation of aldehydes by the hydroformylation of C3-C20-olefins by means of rhodium or ruthenium carbonyl complexes, in which the phosphorus-containing calixarenes of the formula I are used as ligands, is described.

公开(公告)号：DE4316180A1

公开(公告)日：1994-11-17

申请号：DE4316180

申请日：1993-05-14

Applicant: BASF AG

Inventor： KNEUPER HEINZ-JOSEF DR ,  ROEPER MICHAEL PROF DR ,  PACIELLO ROCCO DR

IPC: C07B61/00 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07C45/45 ,  B01J31/40

Abstract: Process for the preparation of aldehydes by the hydroformylation of olefins having more than seven carbon atoms, comprising the step of hydroformylation by means of a rhodium catalyst dissolved in homogeneous reaction medium, the separation of the rhodium catalyst from the material discharged from the hydroformylation reaction, and the recycling of the rhodium separated off from the material discharged from the hydroformylation in the hydroformylation step by extracting the rhodium catalyst from the material discharged from the hydroformylation by means of an aqueous solution of a nitrogen-containing complexing agent from the group consisting of pyridines, quinolines, 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2''-terpyridines and porphines which are optionally substituted, sulphonated or carry sulphonated substituents and/or from the group consisting of carboxylated pyridines, carboxylated quinolines, and 2,2'-bipyridines, 1,10-phenanthrolines, 2,2'-biquinolines, 2,2',6',2''-terpyridines and porphines which are optionally substituted, carboxylated or carry carboxylated substituents, in the aqueous phase and feeding back the aqueous, rhodium-containing extract to the hydroformylation step.

公开(公告)号：DE4230871A1

公开(公告)日：1994-03-17

申请号：DE4230871

申请日：1992-09-16

Applicant: BASF AG

Inventor： KNEUPER HEINZ-JOSEF DR ,  ROEPER MICHAEL PROF DR ,  PACIELLO ROCCO DR

IPC: C07C45/50 ,  C07C47/02

Abstract: Prodn. of aldehydes (I) involves: (a) hydroformylation of olefins (II) with more than 7C, using a homogeneous soln. of a Rh catalyst (III) in the reaction medium; (b) sepn. of (III) from the reaction mixt. (IV); and (c) recirculation of (III) to stage (a). (III) is extracted from (IV) with an aq. soln. of an N-contg. chelating agent (V), consisting of sulphonated pyridines, sulphonated quinolines, opt. substd., sulphonated or sulphonated-substd. 2,2'-bipyridines, 1,10-phenanthro-lines, 2,2'-biquinolines, 2,2',6',2"-terpyridines and porphines and the aq. extract is recycled to stage (a). USE/ADVANTAGE - The process is esp. suitable for hydroformylation of 7-20C linear or branched alpha-olefins and/or olefins with internal double bonds, e.g. oct-1-ene, dodec-1-ene or propylene trimer and tetramer (giving (I) useful as precursors for plasticiser alcohols) and polymeric olefins, e.g. low mol. polyisobutene (which can be converted by reductive amination into polyisobuteneamine, used as fuel additive). (I) can be produced from long-chain and/or branched (II) using 'naked' Rh as (III), i.e. Rh cpds. free from ligands contg. P, which are thermolabile. Sepg. (III) prevents the deposition of metallic Rh during distn. of (IV), whilst the chelates with (V) decompose in the presence of the CO-H2 gas mixt., giving (III) with the required catalytic properties.

公开(公告)号：MY140689A

公开(公告)日：2010-01-15

申请号：MYPI20044320

申请日：2004-10-20

Applicant: BASF AG

Inventor： VOLLAND MARTIN DR ,  MACKEWITZ THOMAS DR ,  AHLERS WOLFGANG DR ,  SCHAEFER ANSGAR DR ,  RICHTER WOLFGANG DR ,  PACIELLO ROCCO DR

IPC: C07C45/50 ,  B01J31/18 ,  B01J31/24

Abstract: PROCESS FOR THE CONTINUOUS PREPARATION OF ALDEHYDES HAVING FROM 5 TO 21 CARBON ATOMS BY ISOMERIZING HYDROFORMYLATION IN THE HOMOGENEOUS PHASE OF OLEFIN COMPOSITIONS HAVING FROM 4 TO 20 CARBON ATOMS AND COMPRISING (ALPHA)-OLEFINS AND OLEFINS HAVING INTERNAL DOUBLE BONDS BY MEANS OF SYNTHESIS GAS IN THE PRESENCE OF A HOMOGENEOUS RHODIUM CATALYST COMPLEXED WITH AN OXYGEN- AND/OR NITROGEN-CONTAINING ORGANOPHOSPHORUS LIGAND AND FREE LIGAND AT ELEVATED TEMPERATURE AND ELEVATED PRESSURE IN A MULTISTAGE REACTION SYSTEM COMPRISING AT LEAST TWO REACTION ZONES, IN WHICH THE OLEFIN COMPOSITION IS FIRSTLY REACTED WITH SYNTHESIS GAS HAVING A CO/H2 MOLAR RATIO OF FROM 4:1 TO 1:2 AT A TOTAL PRESSURE OF FROM 10 TO 40 BAR IN A GROUP OF ONE OR MORE FIRST REACTION ZONES TO A CONVERSION OF THE (ALPHA)-OLEFINS OF FROM 40 TO 95AND THE HYDROFORMYLATION MIXTURE FROM THIS GROUP OF ONE OR MORE FIRST REACTION ZONES IS REACTED WITH SYNTHESIS GAS HAVING A CO/H2 MOLAR RATIO OF FROM 1:4 TO 1:1000 AT A TOTAL PRESSURE OF FROM 5 TO 30 BAR IN A GROUP ONE OR MORE DOWNSTREAM REACTION ZONES, WHERE THE TOTAL PRESSURE IN THE ONE OR MORE DOWNSTREAM REACTION ZONES IS IN EACH CASE FROM 1 TO (T1-Tf) BAR LOWER THAN IN THE PRECEDING REACTION ZONE, WHERE T1 IS THE TOTAL PRESSURE IN THE PRECEDING REACTION ZONE AND Tf IS THE TOTAL PRESSURE IN THE REACTION ZONE DOWNSTREAM OF THE ONE OR MORE FIRST REACTION ZONES, WITH THE PROVISO THAT THE DIFFERENCE T1-Tf IS GREATER THAN 1 BAR, AND THE CO PARTIAL PRESSURE IN THE ONE OR MORE DOWNSTREAM REACTION ZONES IS IN EACH CASE LOWER THAN IN THE REACTION ZONE PRECEDING THIS REACTION ZONE.

公开(公告)号：MY137740A

公开(公告)日：2009-03-31

申请号：MYPI20014205

申请日：2001-09-06

Applicant: BASF AG

Inventor： AHLERS WOLFGANG DR ,  WIEBELHAUS DAG DR ,  PACIELLO ROCCO DR ,  BARTSCH MICHAEL DR ,  BAUMANN ROBERT DR ,  VOGT DIETER PROF DR ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

Abstract: IN A PROCESS FOR THE HYDROFORMYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS, AT LEAST ONE COMPLEX OF A METAL OF TRANSITION GROUP VIII. WITH AT LEAST ONE PHOSPHORUS-, ARSENIC-OR ANTIMONY-CONTAINING COMPOUND AS LIGAND IS USED AS HYDROFORMYLATION CATALYST, WHERE THE COMPOUND USED AS LIGAND IN EACH CASE COMPRISES TWO GROUPS WHICH COMPRISE A P, AS OR SB ATOM AND AT LEAST TWO FURTHER HETERO ATOMS AND ARE BOUND TO A XANTHENE-LIKE MOLECULAR FRAMEWORK. NEW COMPOUNDS OF THIS TYPE AND CATALYSTS WHICH COMPRISE AT LEAST ONE COMPLEX OF A METAL OF TRANSITION GROUP VIII. WITH AT LEAST ONE SUCH COMPOUND AS LIGAND ARE ALSO PROVIDED.

公开(公告)号：DE19710993A1

公开(公告)日：1998-09-24

申请号：DE19710993

申请日：1997-03-17

Applicant: BASF AG

Inventor： KANAND JUERGEN DR ,  PACIELLO ROCCO DR ,  ROEPER MICHAEL PROF DR

IPC: C07C41/54 ,  C07C43/30 ,  C07C41/06

Abstract: The invention relates to a method for producing acetals by reacting allyl ethers with alcohols. According to said method, an allyl ether is reacted with an alcohol in liquid phase in the presence of a homogenous catalyst from an organometallic compound of an element from group VIA and/or VIIIA of the periodic table of elements or in the presence of a heterogeneous catalyst containing one or more elements from the groups IA, VIA, VIIA and/or VIIIA of the periodic table of elements in essentially water-free conditions.

公开(公告)号：DE19631521A1

公开(公告)日：1998-02-05

申请号：DE19631521

申请日：1996-08-03

Applicant: BASF AG

Inventor： FISCHER ROLF DR ,  PACIELLO ROCCO DR ,  ROEPER MICHAEL PROF DR ,  SCHNURR WERNER DR

IPC: B01J31/18 ,  B01J31/24 ,  C07C209/26 ,  C07C253/30 ,  C07C255/24 ,  C07F9/6574 ,  C07C211/12 ,  C07C255/17

Abstract: Manufacture of 6-aminocapronitrile or 6-aminocapronitrile/hexamethylene diamine mixtures, involving a) the reaction of at least one pentennitrile, selected from the group consisting of 2,3 and 4-pentennitrile with carbon monoxide and hydrogen in the presence of catalysts, which contain at least one element of the eighth subgroup as active components, obtaining a hydrogenation formylating discharge (I), b) the optional separation of carbon monoxide, hydrogen and the catalyst from the hydrogenation formylating discharge (I), obtaining a hydrogenation formylating discharge (II), c) the separation of 5-formyl valeronitrile from the hydrogenation formylating discharge (I) or (II), d) the reaction of separated 5-formyl valeronitrile with ammonia and hydrogen in the presence of hydrogenating catalysts, selected from the group consisting of rhenium, copper and its compounds as well as metals and metallic compounds of the eighth group, obtaining a hydrogenation discharge, and e) obtaining 6-aminocapronitrile and if necessary hexamethylene diamine.

公开(公告)号：DE19603201A1

公开(公告)日：1997-07-31

申请号：DE19603201

申请日：1996-01-30

Applicant: BASF AG

Inventor： PACIELLO ROCCO DR ,  KNEUPER HEINZ-JOSEF DR ,  GEISLER BERNHARD DR ,  ROEPER MICHAEL PROF DR

IPC: B01J31/22 ,  B01J31/16 ,  B01J31/18 ,  B01J31/40 ,  C07B61/00 ,  C07C27/22 ,  C07C29/16 ,  C07C31/125 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07D213/38 ,  C07D213/74 ,  C07C31/02 ,  C07D221/00 ,  C08G73/02 ,  C08L23/20

Abstract: A process is proposed for producing aldehydes and alcohols by hydroformylation of olefins with more than three carbon atoms. The process involves a hydroformylation stage, in which the olefin is hydroformylated at a pressure of 50-1000 bar and a temperature of 50-180 DEG C with the aid of a rhodium catalyst dissolved in an homogeneous reaction medium, and a catalyst recovery stage, in which the rhodium catalyst is extracted. The process involves the following steps: (a) hydroformylation carried out in the presence of a rhodium complex containing a ligand in the form of a phosphorous-free multidentate organic nitrogen compound capable of forming complexes with group VIII metals, said nitrogen compound containing in addition at least one tertiary nitrogen rest which can be protonated with a weak acid; (b) extraction of the product from the hydroformylation stage, where appropriate after separation or partial separation of the aldehydes and alcohols, using an aqueous solution of a distillable acid; (c) heat treatment of the aqueous acid extract in the presence of an organic solvent or solvent mixture which is inert under the hydroformylation conditions, the aqueous acid being distilled off, in order to de-protonate the complex and convert it to the organic phase; and (d) recycling of the organic phase containing the catalyst complex into the hydroformylation stage.