公开(公告)号：WO0222261A2

公开(公告)日：2002-03-21

申请号：PCT/EP0110735

申请日：2001-09-17

Applicant: BASF AG ,  AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

CPC classification number: C07F9/65746 ,  B01J31/185 ,  B01J31/1865 ,  B01J31/22 ,  B01J2231/321 ,  B01J2531/0266 ,  B01J2531/80 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/845 ,  C07C45/50 ,  C07F9/65522 ,  C07F9/65719 ,  C07C47/02

Abstract: The invention relates to a method for the hydroformylation of ethylenically unsaturated compounds, whereby at least one complex of a metal of subgroup VIII is used as the hydroformylation catalyst, having at least one compound containing phosphorus, arsenic, or antimony as a ligand. Each compound comprises two groups having a P, As, or Sb atom and at least two other heteroatoms, said groups being bound to a xanthene-type molecular structure. The invention also relates to novel compounds of this type and catalysts comprising at least one complex of a metal of subgroup VIII having at least one such compound as a ligand.

Abstract translation: 本发明涉及用于烯属不饱和化合物的加氢甲酰化过程中，被用作羰基化催化剂包括VIII的金属中的至少一种配合物。具有至少一个磷，砷或含锑化合物作为配体的亚组，该化合物为二P- 含有基团As或Sb原子和至少两个另外的杂原子附接至具有呫吨状分子骨架。 本发明还涉及到这种类型和催化剂包括VIII的金属中的至少一种配合物的新化合物。与作为配体的至少一个这样的化合物亚类。

公开(公告)号：AU1225002A

公开(公告)日：2002-03-26

申请号：AU1225002

申请日：2001-09-17

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

Abstract: In a process for the hydroformylation of ethylenically unsaturated compounds, at least one complex of a metal of transition group VIII. with at least one phosphorus-, arsenic- or antimony-containing compound as ligand is used as hydroformylation catalyst, where the compound used as ligand in each case comprises two groups which comprise a P, As or Sb atom and at least two further hetero atoms and are bound to a xanthene-like molecular framework. New compounds of this type and catalysts which comprise at least one complex of a metal of transition group VIII. with at least one such compound as ligand are also provided.

公开(公告)号：DE10046026A1

公开(公告)日：2002-03-28

申请号：DE10046026

申请日：2000-09-18

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574 ,  C07F15/00 ,  B01J31/12 ,  C07F9/6561 ,  C07F9/74 ,  C07F9/90 ,  C07B41/06 ,  C07B45/02 ,  C07B31/00

Abstract: The invention relates to a method for the hydroformylation of ethylenically unsaturated compounds, whereby at least one complex of a metal of subgroup VIII is used as the hydroformylation catalyst, having at least one compound containing phosphorus, arsenic, or antimony as a ligand. Each compound comprises two groups having a P, As, or Sb atom and at least two other heteroatoms, said groups being bound to a xanthene-type molecular structure. The invention also relates to novel compounds of this type and catalysts comprising at least one complex of a metal of subgroup VIII having at least one such compound as a ligand.

公开(公告)号：MY137740A

公开(公告)日：2009-03-31

申请号：MYPI20014205

申请日：2001-09-06

Applicant: BASF AG

Inventor： AHLERS WOLFGANG DR ,  WIEBELHAUS DAG DR ,  PACIELLO ROCCO DR ,  BARTSCH MICHAEL DR ,  BAUMANN ROBERT DR ,  VOGT DIETER PROF DR ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

Abstract: IN A PROCESS FOR THE HYDROFORMYLATION OF ETHYLENICALLY UNSATURATED COMPOUNDS, AT LEAST ONE COMPLEX OF A METAL OF TRANSITION GROUP VIII. WITH AT LEAST ONE PHOSPHORUS-, ARSENIC-OR ANTIMONY-CONTAINING COMPOUND AS LIGAND IS USED AS HYDROFORMYLATION CATALYST, WHERE THE COMPOUND USED AS LIGAND IN EACH CASE COMPRISES TWO GROUPS WHICH COMPRISE A P, AS OR SB ATOM AND AT LEAST TWO FURTHER HETERO ATOMS AND ARE BOUND TO A XANTHENE-LIKE MOLECULAR FRAMEWORK. NEW COMPOUNDS OF THIS TYPE AND CATALYSTS WHICH COMPRISE AT LEAST ONE COMPLEX OF A METAL OF TRANSITION GROUP VIII. WITH AT LEAST ONE SUCH COMPOUND AS LIGAND ARE ALSO PROVIDED.

公开(公告)号：DE50106337D1

公开(公告)日：2005-06-30

申请号：DE50106337

申请日：2001-09-17

Applicant: BASF AG

Inventor： AHLERS WOLFGANG ,  WIEBELHAUS DAG ,  PACIELLO ROCCO ,  BARTSCH MICHAEL ,  BAUMANN ROBERT ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J31/18 ,  B01J31/22 ,  C07C45/50 ,  C07F9/655 ,  C07F9/6571 ,  C07F9/6574

Abstract: In a process for the hydroformylation of ethylenically unsaturated compounds, at least one complex of a metal of transition group VIII. with at least one phosphorus-, arsenic- or antimony-containing compound as ligand is used as hydroformylation catalyst, where the compound used as ligand in each case comprises two groups which comprise a P, As or Sb atom and at least two further hetero atoms and are bound to a xanthene-like molecular framework. New compounds of this type and catalysts which comprise at least one complex of a metal of transition group VIII. with at least one such compound as ligand are also provided.

公开(公告)号：DE10046025A1

公开(公告)日：2002-03-28

申请号：DE10046025

申请日：2000-09-18

Applicant: BASF AG

Inventor： BAUMANN ROBERT ,  BARTSCH MICHAEL ,  KUNSMANN-KEITEL DAGMAR PASCAL ,  HADERLEIN GERD ,  SIEGEL WOLFGANG ,  VOGT DIETER ,  HEWAT ALISON

IPC: B01J23/755 ,  B01J31/18 ,  B01J31/24 ,  C07C253/10 ,  C07C253/30 ,  C07C255/04 ,  B01J31/12 ,  C07F15/04

Abstract: Production of adiponitrile from butadiene and hydrogen cyanide uses a catalyst comprising a Group VIII metal complex having at least one tricyclic bifunctional phosphorus, arsenic or antimony ligand. Production of adiponitrile by: (a) reacting butadiene with hydrogen cyanide in the presence of a catalyst, (b) optionally catalytically isomerizing the resulting mixture of pentenonitriles to covert branched nitriles to linear nitriles, and (c) reacting the nitrile mixture with hydrogen cyanide in the presence of a catalyst comprises performing steps (a), (b) and/or (c) in the presence of a catalyst comprising a Group VIII metal complex having at least one ligand of formula (I). A , A = O, Si, SiRR, NR or CRR; R = H, alkyl, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; Y , Y = groups comprising one or more P, As or Sb atoms, each directly bonded to at least two O, S or NR' heteroatoms; R' = H, alkyl, cycloalkyl or aryl; R -R = R, COOR', COOM, SO2R', SO3M, N(R')2, N(R')3 X , OR', SR', (CHR''CH2O)xR', (CH2NR')xR', (CH2CH2NR')xR', halogen, CF3, NO2, acyl or CN, or R and/or R can form fused ring systems with 1-3 rings; R = H, Me or Et; M = a cation; X = an anion; x = 1-120. An Independent claim is also included for a process for isomerizing branched aliphatic monoalkenonitriles to linear aliphatic monoalkenonitriles using such a catalyst.