公开(公告)号：DE19525187A1

公开(公告)日：1997-01-16

申请号：DE19525187

申请日：1995-07-11

Applicant: BASF AG

Inventor： BREITSCHEIDEL BORIS DR ,  POLANEK PETER DR ,  VOIT GUIDO DR ,  WITZEL TOM DR ,  LINDEN GERD DR ,  HESSE MICHAEL DR

IPC: B01J23/889 ,  B01J27/185 ,  B01J27/187 ,  C07C209/48 ,  C07C209/52

Abstract: Cobalt catalysts (I) are claimed, in which the active material contains 55-98 wt% Co, 0.2-15 wt% P, 0.2-15 wt% Mn and 0.05-5 wt% alkali metal, calcd. as oxide. The calcined catalyst is reduced in a stream of hydrogen at final temps. of 200-400[deg]C and then surface-oxidised in a stream of air at final temps. of 20-60[deg]C. Also claimed is a process for the hydrogenation of organic nitriles and/or imines at 60-150[deg]C and 50-300 bar using (I) as catalyst.

公开(公告)号：DE4325847A1

公开(公告)日：1995-02-02

申请号：DE4325847

申请日：1993-07-31

Applicant: BASF AG

Inventor： BREITSCHEIDEL BORIS DR ,  POLANEK PETER DR ,  IRGANG MATTHIAS DR ,  PETERSEN HERMANN DR ,  LINDEN GERD DR ,  VOIT GUIDO DR ,  WITZEL TOM DR

IPC: B01J23/889 ,  B01J27/185 ,  B01J27/187 ,  B01J37/08 ,  C07B61/00 ,  C07C209/48 ,  C07C209/50 ,  C07C211/36 ,  B01J23/74 ,  C07C209/52

Abstract: Cobalt catalysts whose catalitically active composition consists of from 55 to 98% by wt. of cobalt, from 0.2 to 15% by wt. of phosphorus, from 0.2 to 15% by wt. of manganese and from 0.2 to 15% by wt. of alkali, calculated as oxide, by calcining the catalyst composition in a first step at final temperatures of from 550 to 750 DEG C and in a second step at final temperatures of from 800 to 1000 DEG C and also a process for hydrogenating organic nitriles and/or imines by use of the new cobalt catalysts.

公开(公告)号：ES2126818T3

公开(公告)日：1999-04-01

申请号：ES95112478

申请日：1995-08-09

Applicant: BASF AG

Inventor： KOHLER ULRICH DR ,  PAPE FRANK-FRIEDRICH DR ,  IRGANG MATTHIAS DR ,  WULFF-DORING JOACHIM DR ,  HESSE MICHAEL DR ,  POLANEK PETER DR

IPC: B01J23/42 ,  B01J23/58 ,  B01J23/40 ,  B01J23/63 ,  C07B61/00 ,  C07C209/16 ,  C07C209/68 ,  C07C209/72 ,  C07C211/45

Abstract: Prodn. of arylamines of formula (I) comprises (a) preparing a cycloalkylamine of formula (II) by the hydrogenative amination of a phenol (III) with NH3/H2 at 100-250 deg.C under 0.01-50 bar pressure in the presence of catalyst (A); and (b) dehydrogenation of (II) at 150-300 deg.C under 0.01-50 bar pressure in the presence of a catalyst (A). (A) comprises: 30-100 wt.% of a Pd component (A1) and 0-70 wt.% alkali- and/or alkaline earth oxide. (A1) comprises Pd (opt. mixed with Pt) on oxides of rare earth and/or Group IVb; or Pt/Pd mixts. on Al2O3. R1-R5 = H, 1-12C alkyl or 3-12C cycloalkyl. Step (b) is independently claimed.

公开(公告)号：DE59208990D1

公开(公告)日：1997-12-04

申请号：DE59208990

申请日：1992-07-03

Applicant: BASF AG

Inventor： POLANEK PETER DR ,  POSSELT DIETMAR DR ,  SCHREYER PETER DR

IPC: B01J23/40 ,  C07B61/00 ,  C07C5/05 ,  C07C11/08

Abstract: A method for the selective hydrogenation of butadiene to butenes in the liquid or trickle phase on firmly arranged noble metal supported catalysts, in which a C4 stream rich in butadiene having a butadiene content of 20 to 80 % by weight, relative to the C4 stream, is hydrogenated in two reaction zones connected in series such that the hydrogenation product of the first reaction zone contains 0.1 to 20 % by weight and the hydrogenation product of the second reaction zone contains 0.005 to 1 % by weight of residual butadiene relative to the C4 stream, with the proviso that the butadiene content of the hydrogenation product from the second reaction zone is reduced by at least the factor 5 compared to the butadiene content of the hydrogenation product from the first reaction zone.

公开(公告)号：DE19608241A1

公开(公告)日：1997-09-18

申请号：DE19608241

申请日：1996-03-04

Applicant: BASF AG

Inventor： VICARI MAXIMILIAN DR ,  WALTER MARC DR ,  SCHWAB EKKEHARD DR ,  MUELLER HANS-JOACHIM DR ,  KONS GERMAIN ,  DILLING STEPHAN ,  POLANEK PETER DR

IPC: B01J23/755 ,  C10G45/36 ,  C10G67/02 ,  C07B35/02 ,  C07B63/00

Abstract: In the process for the selective hydrogenation of dienes in supply flows containing them, such a flow is hydrogenated on a nickel-containing precipitating catalyst at a temperature of between 40 and 100 DEG C, a pressure of between 3 and 20 bar and a WHSV (weight hourly space velocity) of between 1 and 10 kg/(lxh) in the presence of free hydrogen.

公开(公告)号：DE59402754D1

公开(公告)日：1997-06-19

申请号：DE59402754

申请日：1994-03-15

Applicant: BASF AG

Inventor： POLANEK PETER DR ,  SCHWAHN HARALD DR ,  IRGANG MATTHIAS DR ,  FREIRE-ERDBRUEGGER CHRISTINA D

IPC: B01J23/755 ,  B01J37/03 ,  C07B35/02 ,  C07B61/00 ,  C07C5/02 ,  C10G45/46 ,  C10G45/48 ,  C10G73/44

Abstract: Catalyst suitable for hydrogenation of organic cpds., comprises (all based on total wt. of catalyst); (a) 80 wt.% nickel (calculated as nickel oxide); (b) 10-25 wt.% of silicon (calculated as zirconium oxide; and (d) 0-10 wt.% of aluminium (calculated as aluminium oxide). The amt. of silicon dioxide and aluminium oxide is at least 15 wt.%. The catalyst is prepd. by; (2) adding an acidic aq. soln. of nickel-, zirconium- and opt. aluminium salts to a basic aq. soln. or suspension of silicon cpds. (and opt. aluminium cpds.), so that the pH of the resulting mixt. drops to at least 6.5; (2) adding a further basic soln. to bring the pH to 7-8; and (3) isolating the pptd. solid, which is then dried, formed and calcined.

公开(公告)号：DE4123246A1

公开(公告)日：1993-01-14

申请号：DE4123246

申请日：1991-07-13

Applicant: BASF AG

Inventor： POLANEK PETER DR ,  POSSELT DIETMAR DR ,  SCHREYER PETER DR

IPC: B01J23/40 ,  C07B61/00 ,  C07C5/05 ,  C07C11/08

Abstract: A method for the selective hydrogenation of butadiene to butenes in the liquid or trickle phase on firmly arranged noble metal supported catalysts, in which a C4 stream rich in butadiene having a butadiene content of 20 to 80 % by weight, relative to the C4 stream, is hydrogenated in two reaction zones connected in series such that the hydrogenation product of the first reaction zone contains 0.1 to 20 % by weight and the hydrogenation product of the second reaction zone contains 0.005 to 1 % by weight of residual butadiene relative to the C4 stream, with the proviso that the butadiene content of the hydrogenation product from the second reaction zone is reduced by at least the factor 5 compared to the butadiene content of the hydrogenation product from the first reaction zone.

公开(公告)号：DE59504619D1

公开(公告)日：1999-02-04

申请号：DE59504619

申请日：1995-08-09

Applicant: BASF AG

Inventor： KOEHLER ULRICH DR ,  PAPE FRANK-FRIEDRICH DR ,  IRGANG MATTHIAS DR ,  WULFF-DOERING JOACHIM DR ,  HESSE MICHAEL DR ,  POLANEK PETER DR ,  GAA PETER

IPC: B01J23/40 ,  B01J23/42 ,  B01J23/58 ,  B01J23/63 ,  C07B61/00 ,  C07C209/16 ,  C07C209/68 ,  C07C209/72 ,  C07C211/45

Abstract: Prodn. of arylamines of formula (I) comprises (a) preparing a cycloalkylamine of formula (II) by the hydrogenative amination of a phenol (III) with NH3/H2 at 100-250 deg.C under 0.01-50 bar pressure in the presence of catalyst (A); and (b) dehydrogenation of (II) at 150-300 deg.C under 0.01-50 bar pressure in the presence of a catalyst (A). (A) comprises: 30-100 wt.% of a Pd component (A1) and 0-70 wt.% alkali- and/or alkaline earth oxide. (A1) comprises Pd (opt. mixed with Pt) on oxides of rare earth and/or Group IVb; or Pt/Pd mixts. on Al2O3. R1-R5 = H, 1-12C alkyl or 3-12C cycloalkyl. Step (b) is independently claimed.

公开(公告)号：AT174897T

公开(公告)日：1999-01-15

申请号：AT95112478

申请日：1995-08-09

Applicant: BASF AG

Inventor： KOEHLER ULRICH DR ,  PAPE FRANK-FRIEDRICH DR ,  IRGANG MATTHIAS DR ,  WULFF-DOERING JOACHIM DR ,  HESSE MICHAEL DR ,  POLANEK PETER DR ,  GAA PETER

IPC: B01J23/40 ,  B01J23/42 ,  B01J23/58 ,  B01J23/63 ,  C07B61/00 ,  C07C209/16 ,  C07C209/68 ,  C07C209/72 ,  C07C211/45

Abstract: Prodn. of arylamines of formula (I) comprises (a) preparing a cycloalkylamine of formula (II) by the hydrogenative amination of a phenol (III) with NH3/H2 at 100-250 deg.C under 0.01-50 bar pressure in the presence of catalyst (A); and (b) dehydrogenation of (II) at 150-300 deg.C under 0.01-50 bar pressure in the presence of a catalyst (A). (A) comprises: 30-100 wt.% of a Pd component (A1) and 0-70 wt.% alkali- and/or alkaline earth oxide. (A1) comprises Pd (opt. mixed with Pt) on oxides of rare earth and/or Group IVb; or Pt/Pd mixts. on Al2O3. R1-R5 = H, 1-12C alkyl or 3-12C cycloalkyl. Step (b) is independently claimed.

公开(公告)号：DE19704128A1

公开(公告)日：1998-08-06

申请号：DE19704128

申请日：1997-02-04

Applicant: BASF AG

Inventor： VICARI MAXIMILIAN DR ,  WALTER MARC DR ,  DILLING STEPHAN ,  POLANEK PETER DR

IPC: B01J23/755 ,  C10G45/48 ,  C10G65/08

Abstract: Process for dearomatising aromatic hydrocarbons into injection streams containing aromatic hydrocarbons is claimed, in which the injection stream is hydrogenated over a Ni-containing catalyst at 50-300 degrees C, 20-80 bar pressure, and using a catalyst charge of 1-6 kg/(l x h) in the presence of free hydrogen.