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    11.
    发明专利
    未知

    公开(公告)号：DE59104561D1

    公开(公告)日：1995-03-23

    申请号：DE59104561

    申请日：1991-03-21

    Applicant: BASF AG

    Inventor： MERGER FRANZ DR ,  PRIESTER CLAUS-ULRICH DR ,  KLOPPENHOEFER GERHARD DR ,  HARDER WOLFGANG DR ,  WITZEL TOM DR ,  LERMER HELMUT DR ,  KOEHLER ULRICH DR

    IPC: B01J23/40 ,  B01J23/74 ,  B01J29/06 ,  C07B61/00 ,  C07C209/00 ,  C07C209/26 ,  C07C209/48 ,  C07C211/36

    Abstract: Process for the preparation of 2-(3-aminopropyl)cycloalkylamines of the general formula I in which the index n is an integer from 1 to 4, from 2-(2-cyanoethyl)cycloalkanones of the general formula II in which the index n has the abovementioned meaning, by carrying out the following steps in two reaction spaces spatially separated from one another: a) reacting the 2-(2-cyanoethyl)cycloalkanones of the formula II in a first reaction space with excess ammonia over acidic heterogeneous catalysts at temperatures of 20 to 150 DEG C and pressures of 15 to 500 bar and b) hydrogenating the reaction products in a second reaction space with hydrogen in the presence of excess ammonia over cobalt-, nickel-, ruthenium- and/or other noble metal-containing catalysts which may contain basic components or are present on neutral or basic supports at temperatures of 60 to 150 DEG C and pressures of 100 to 500 bar, and also the novel compound 2-(3-aminopropyl)cyclopentylamine.

    12.
    发明专利
    未知

    公开(公告)号：ES2063805T3

    公开(公告)日：1995-01-16

    申请号：ES89123437

    申请日：1989-12-19

    Applicant: BASF AG

    Inventor： MERGER FRANZ DR ,  FISCHER ROLF DR ,  PRIESTER CLAUS-ULRICH DR

    IPC: C07D201/08

    Abstract: Caprolactam is prepared by heating a 6-aminocaproic ester in liquid phase in the presence of water to 230 DEG -350 DEG C. under superatmospheric pressure in a reaction medium comprising a liquid aromatic hydrocarbon having a boiling point of from 80 DEG to 240 DEG C. which is inert under reaction conditions, and isolating caprolactam from the reaction mixture.

    15.
    发明专利
    未知

    公开(公告)号：ES2077092T3

    公开(公告)日：1995-11-16

    申请号：ES91104410

    申请日：1991-03-21

    Applicant: BASF AG

    Inventor： MERGER FRANZ DR ,  PRIESTER CLAUS-ULRICH DR ,  WITZEL TOM DR ,  KOPPENHOEFER GERHARD DR ,  SCHUSTER LUDWIG DR

    IPC: B01J23/40 ,  B01J23/74 ,  B01J29/06 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C08G69/00 ,  C08G73/02

    Abstract: Process for the preparation of 2,2-disubstituted pentane-1,5-diamines of the general formula I … … in which the substituents R and R , independently of one another, denote C1- to C10-alkyl, C2- to C10-alkenyl or together represent a C4- to C7-alkylene chain which is unsubstituted or substituted by one to five C1- to C4-alkyl groups, from 2,2-disubstituted 4-cyanobutanals of the general formula II … … in which the substituents R and R have the abovementioned meanings, by carrying out the reaction in two reaction spaces spatially separated from one another by …… a) reacting the 4-cyanobutanals of the formula II in a first reaction space with excess ammonia over acidic heterogeneous catalysts at temperatures of 20 to 150 DEG C and pressures of 15 to 500 bar and … b) hydrogenating the reaction products formed in a second reaction space with excess hydrogen in the presence of excess ammonia over cobalt-, nickel-, ruthenium- and/or other noble metal-containing catalysts, which may contain basic components or are arranged on basic or neutral supports at temperatures of 60 to 150 DEG C and pressures of 50 to 500 bar, and novel 2,2-disubstituted pentane-1,5-diamines of the general formula I' …… … in which the substituents R and R , independently of one another, denote C1- to C10-alkyl, C2- to C10-alkenyl or together represent a C4- to C7-alkylene chain which is unsubstituted or substituted by one to five C1- to C4-alkyl groups with the proviso that R and R do not simultaneously denote methyl.

    16.
    发明专利
    未知

    公开(公告)号：ES2068412T3

    公开(公告)日：1995-04-16

    申请号：ES91104411

    申请日：1991-03-21

    Applicant: BASF AG

    Inventor： MERGER FRANZ DR ,  PRIESTER CLAUS-ULRICH DR ,  KLOPPENHOEFER GERHARD DR ,  HARDER WOLFGANG DR ,  WITZEL TOM DR ,  LERMER HELMUT DR ,  KOEHLER ULRICH DR

    IPC: B01J23/40 ,  B01J23/74 ,  B01J29/06 ,  C07B61/00 ,  C07C209/00 ,  C07C209/26 ,  C07C209/48 ,  C07C211/36

    Abstract: Process for the preparation of 2-(3-aminopropyl)cycloalkylamines of the general formula I in which the index n is an integer from 1 to 4, from 2-(2-cyanoethyl)cycloalkanones of the general formula II in which the index n has the abovementioned meaning, by carrying out the following steps in two reaction spaces spatially separated from one another: a) reacting the 2-(2-cyanoethyl)cycloalkanones of the formula II in a first reaction space with excess ammonia over acidic heterogeneous catalysts at temperatures of 20 to 150 DEG C and pressures of 15 to 500 bar and b) hydrogenating the reaction products in a second reaction space with hydrogen in the presence of excess ammonia over cobalt-, nickel-, ruthenium- and/or other noble metal-containing catalysts which may contain basic components or are present on neutral or basic supports at temperatures of 60 to 150 DEG C and pressures of 100 to 500 bar, and also the novel compound 2-(3-aminopropyl)cyclopentylamine.

    19.
    发明专利
    未知

    公开(公告)号：DE59106607D1

    公开(公告)日：1995-11-09

    申请号：DE59106607

    申请日：1991-03-21

    Applicant: BASF AG

    Inventor： MERGER FRANZ DR ,  PRIESTER CLAUS-ULRICH DR ,  WITZEL TOM DR ,  KOPPENHOEFER GERHARD DR ,  SCHUSTER LUDWIG DR

    IPC: B01J23/40 ,  B01J23/74 ,  B01J29/06 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C08G69/00 ,  C08G73/02

    Abstract: Process for the preparation of 2,2-disubstituted pentane-1,5-diamines of the general formula I … … in which the substituents R and R , independently of one another, denote C1- to C10-alkyl, C2- to C10-alkenyl or together represent a C4- to C7-alkylene chain which is unsubstituted or substituted by one to five C1- to C4-alkyl groups, from 2,2-disubstituted 4-cyanobutanals of the general formula II … … in which the substituents R and R have the abovementioned meanings, by carrying out the reaction in two reaction spaces spatially separated from one another by …… a) reacting the 4-cyanobutanals of the formula II in a first reaction space with excess ammonia over acidic heterogeneous catalysts at temperatures of 20 to 150 DEG C and pressures of 15 to 500 bar and … b) hydrogenating the reaction products formed in a second reaction space with excess hydrogen in the presence of excess ammonia over cobalt-, nickel-, ruthenium- and/or other noble metal-containing catalysts, which may contain basic components or are arranged on basic or neutral supports at temperatures of 60 to 150 DEG C and pressures of 50 to 500 bar, and novel 2,2-disubstituted pentane-1,5-diamines of the general formula I' …… … in which the substituents R and R , independently of one another, denote C1- to C10-alkyl, C2- to C10-alkenyl or together represent a C4- to C7-alkylene chain which is unsubstituted or substituted by one to five C1- to C4-alkyl groups with the proviso that R and R do not simultaneously denote methyl.

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