公开(公告)号：CA2478858C

公开(公告)日：2010-12-14

申请号：CA2478858

申请日：2003-03-07

Applicant: BASF AG

Inventor： GERLACH TILL ,  FUNKE FRANK ,  MELDER JOHANN-PETER ,  ISELBORN STEFAN ,  RUDLOFF MARTIN ,  HUELLMANN MICHAEL

IPC: B01J23/755 ,  C07D295/02 ,  B01J23/70 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023

Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.

公开(公告)号：DE10333598A1

公开(公告)日：2005-02-17

申请号：DE10333598

申请日：2003-07-24

Applicant: BASF AG

Inventor： VICARI MAXIMILIAN ,  RUDLOFF MARTIN ,  KRAMER ANDREAS ,  DREWS RONALD

IPC: C07C29/42 ,  C07C33/042

Abstract: In the production of propargyl alcohol (I) by conversion of an aqueous formaldehyde solution containing acetylene in presence of a catalyst containing copper acetylide at 1-15 (preferably 3-7) bars and 70-120[deg]C without formation of a coherent gas phase, the aqueous formaldehyde solution contains an organic solvent for acetylene and the catalyst is arranged in a fluidized bed.

公开(公告)号：AU2003215639A1

公开(公告)日：2003-09-22

申请号：AU2003215639

申请日：2003-03-07

Applicant: BASF AG

Inventor： FUNKE FRANK ,  MELDER JOHANN-PETER ,  ISELBORN STEFAN ,  RUDLOFF MARTIN ,  HULLMANN MICHAEL ,  GERLACH TILL

IPC: C07D295/02 ,  B01J23/70 ,  B01J23/755 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023 ,  C07C209/00

Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO 2 , 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.

公开(公告)号：DE10004909A1

公开(公告)日：2001-08-09

申请号：DE10004909

申请日：2000-02-04

Applicant: BASF AG

Inventor： OHLBACH FRANK ,  MELDER JOHANN-PETER ,  ROS KARL-HEINZ ,  RUDLOFF MARTIN ,  LIEBE JOERG

IPC: C07B61/00 ,  C07D207/26 ,  C07D207/267

Abstract: N-Methyl-2-pyrrolidone (NMP) is prepared by preparing a mixture comprising monomethylamine, dimethylamine and trimethylamine and ammonia in a first process step by reacting ammonia with methanol at elevated temperature in the presence of a catalyst, separating 10 off the ammonia, reacting the mixture comprising the methylamines with gamma-butyrolactone (gamma-BL), in a molar ratio of monomethylamine to gamma-BL of at least 1 in a second process step at elevated temperature and superatmospheric pressure, separating NMP and unreacted methylamines from the reaction product and returning unreacted methylamines to the first process step for reaction with methanol and ammonia.

公开(公告)号：DE502004003979D1

公开(公告)日：2007-07-12

申请号：DE502004003979

申请日：2004-07-03

Applicant: BASF AG

Inventor： VICARI MAXIMILIAN ,  RUDLOFF MARTIN ,  KRAMER ANDREAS ,  DREWS RONALD

IPC: C07C29/42 ,  C07C33/042

Abstract: In the production of propargyl alcohol (I) by conversion of an aqueous formaldehyde solution containing acetylene in presence of a catalyst containing copper acetylide at 1-15 (preferably 3-7) bars and 70-120[deg]C without formation of a coherent gas phase, the aqueous formaldehyde solution contains an organic solvent for acetylene and the catalyst is arranged in a fluidized bed.

公开(公告)号：DE50207212D1

公开(公告)日：2006-07-27

申请号：DE50207212

申请日：2002-08-30

Applicant: BASF AG

Inventor： RUDLOFF MARTIN ,  STOPS PETER ,  HENKES ERHARD ,  SCHMIDTKE HELMUT ,  FISCHER ROLF-HARTMUTH ,  JULIUS MANFRED ,  LEBKUECHER ROLF ,  ROSS KARL-HEINZ

IPC: C07D207/26 ,  C07D201/08 ,  C07D207/267

Abstract: A process for continuously preparing 2-pyrrolidone by reacting gamma-butyrolactone with ammonia in the liquid phase in the presence of water, wherein the reaction is carried out at a temperature of from 275 to 300° C. and an absolute pressure of from 140 to 180 bar.