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公开(公告)号:DE59601895D1
公开(公告)日:1999-06-17
申请号:DE59601895
申请日:1996-08-06
Applicant: BASF AG
Inventor: HEIDER MARC , RUEHL THOMAS , HENKELMANN JOCHEM , STUTZ SUSANNE , PREISS THOMAS , RUETTER HEINZ , SCHAEFER MARTIN , HOEHN ARTHUR
IPC: C07D307/33 , B01J31/20 , C07B61/00 , C07D307/32 , C07D307/58 , C07D315/00 , C07F7/08
Abstract: PCT No. PCT/EP96/03472 Sec. 371 Date Feb. 12, 1998 Sec. 102(e) Date Feb. 12, 1998 PCT Filed Aug. 6, 1996 PCT Pub. No. WO97/07111 PCT Pub. Date Feb. 27, 1997A process for the preparation of butyrolactones of the formula I where the substituents R1 and R2 are hydrogen, alkyl or hydroxyalkyl groups, or aryl and trialkylsilyl groups, if appropriate carrying inert: substituents, is described in which an alkyne of the formula IIR1-C 3BOND C-R2IIwhere the substituents have the meanings indicated above, is reacted under reducing conditions at elevated pressure and elevated temperature with carbon monoxide CO and hydrogen in the presence of a transition metal catalyst or with carbon monoxide and water in the presence of a transition metal catalyst.
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公开(公告)号:CA2237060A1
公开(公告)日:1997-06-26
申请号:CA2237060
申请日:1996-12-11
Applicant: BASF AG
Inventor: KRATZ DETLEF , FISCHER ROLF , SCHAEFER MARTIN , PINKOS ROLF , HOEHN ARTHUR
IPC: C07C29/10 , C07C29/132 , C07C31/20
Abstract: The proposed production of 1,6-hexane diol involves the following steps: a) epoxybutadiene is reacted in the presence of a metathesis catalyst, ethene being broken down to bisepoxihexatrienes of formulae (Ia) and (Ib); and b) these bisepoxihexatrienes are then hydrated with hydrogen to form 1,6-hexane diol.
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公开(公告)号:AT278467T
公开(公告)日:2004-10-15
申请号:AT02704673
申请日:2002-01-26
Applicant: BASF AG
Inventor: SLANY MICHAEL , SCHAEFER MARTIN , ROEPER MICHAEL
IPC: B01J31/22 , B01J31/24 , C07B61/00 , C07C67/38 , C07C69/24 , C07C69/34 , C07C253/30 , C07C255/19 , C07F9/50 , C07F9/6568
Abstract: A compound of formula (I) suitable as a catalyst or for the preparation of a catalyst system: L 1 -X-L 2 (I) is provided, in which X is a lower alkylene group, an arylene group or an alkarylene group; L 1 is in which Y 1 is oxygen, sulfur or N-R 17 , R 11 , R 12 , R 13 , R 14 , R 15 , R 16 and R 17 independently of one another being hydrogen, alkyl or aryl; and L 2 is in which Y 2 is oxygen, sulfur or N-R 27 , R 21 , R 22 , R 23 , R 24 , R 25 , R 26 and R 27 independently of one another being hydrogen, alkyl or aryl, it being possible for L 1 and L 2 to be identical or different.
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公开(公告)号:DE10210730A1
公开(公告)日:2003-09-25
申请号:DE10210730
申请日:2002-03-12
Applicant: BASF AG
Inventor: SLANY MICHAEL , SCHAEFER MARTIN , KARL JOERN , ROEPER MICHAEL
Abstract: A process for the production of formic acid formates comprises reaction of methyl formate with water and a basic compound having a pKa value of the corresponding dissociation step of a least 3 (measured at 25 degreesC in aqueous solution), separation of the formed methanol and optionally addition of formic acid to the desired acid content.
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公开(公告)号:DE10228293A1
公开(公告)日:2003-02-13
申请号:DE10228293
申请日:2002-06-25
Applicant: BASF AG
Inventor: SLANY MICHAEL , SCHAEFER MARTIN , ROEPER MICHAEL
Abstract: Preparation of dialkyl ketones (I) by reductive carbonylation of alpha -olefins with carbon monoxide (CO) and hydrogen (H2) is carried out in the presence of a catalyst system containing: (a) palladium (Pd) or a Pd compound; (b) a phosphine; (c) a protonic acid with a pKa value \- 4.5, measured in aqueous solution at 25 deg C; and (d) a solubilizable carboxamide.
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公开(公告)号:DE10048874A1
公开(公告)日:2002-04-11
申请号:DE10048874
申请日:2000-09-29
Applicant: BASF AG
Inventor: SCHAEFER MARTIN , SLANY MICHAEL , ZELLER EDGAR , ROEPER MICHAEL , SCHULZ MICHAEL , GRIMM GUENTHER
IPC: B01J31/24 , B01J31/16 , B01J31/28 , B01J35/00 , C07B61/00 , C07C51/14 , C07C53/122 , C07C67/38 , B01J31/02 , C07C45/50
Abstract: The invention relates to a catalyst system for carbonylating olefinically or acetylenically unsaturated compounds with carbon monoxide and a nucleophile compound, containing (a) palladium; (b) a phosphine and (c) a polymer containing nitrogen which is soluble in the reaction mixture, with the exception of polyvinyl polymers with aromatic radicals containing nitrogen on the polymer chain. The invention also relates to a method for carbonylation in the presence of one such catalyst system.
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公开(公告)号:DE59607693D1
公开(公告)日:2001-10-18
申请号:DE59607693
申请日:1996-12-11
Applicant: BASF AG
Inventor: FISCHER ROLF , KRATZ DETLEF , PINKOS ROLF , SCHAEFER MARTIN , HOEHN ARTHUR
IPC: C07D303/04 , B01J31/24 , C07B61/00 , C07C29/132 , C07C29/17 , C07C31/20 , C07D303/22
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公开(公告)号:DE19936979A1
公开(公告)日:2001-02-08
申请号:DE19936979
申请日:1999-08-05
Applicant: BASF AG
Inventor: SCHAEFER MARTIN , SCHULZ MICHAEL
IPC: B01J23/46 , B01J31/02 , B01J31/04 , B01J31/12 , B01J31/20 , B01J31/22 , C07B61/00 , C07C51/14 , C07C53/122 , C07B41/08
Abstract: The invention relates to a method of producing carboxylic acids on the basis of olefins and carbon monoxide in the presence of water. The inventive method is characterized by using as a halide-free catalyst system a mixture from a) rhodium or a rhodium compound, b) at least one nitrogenous heterocyclic compound, c) at least one alkaline or alkaline earth salt of an aliphatic C2-C20 carboxylic acid, and d) at least one glycol ether of general formula (I), in which R and R independently represent C1-C20 alkyl, R CO, with R being hydrogen, C1-C20 alkyl or R and R together represent a C1-C20 alkylene chain and n is 1 to 30.
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公开(公告)号:DE19919174A1
公开(公告)日:2000-11-09
申请号:DE19919174
申请日:1999-04-28
Applicant: BASF AG
Inventor: SLANY MICHAEL , SCHULZ MICHAEL , SCHAEFER MARTIN , ZELLER EDGAR , EBEL KLAUS
IPC: C07D263/08 , C07D233/76 , C07D263/44
Abstract: Preparation of hydantoins or aminoacid cyclic anhydrides (I) involves reacting an aldehyde (II) with carbon monoxide and a u or carbamate compound (III) in presence of a transition metal catalyst. Preparation of hydantoins or aminoacid cyclic anhydrides of formula (I) involves reacting an aldehyde RCHO (II) with carbon monoxide and a urea or carbamate compound of formula R3-NH-C(O)-R2 (III) in presence of a transition metal catalyst. X = O or NH; R = alkyl or aryl (both optionally substituted); R3 = H or as defined for R; R2 = group which reacts with the COOH group formed in the reaction under ring-closure to form (I).
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公开(公告)号:ZA200404518B
公开(公告)日:2005-06-08
申请号:ZA200404518
申请日:2004-06-08
Applicant: BASF AG
Inventor: SLANY MICHAEL , SCHAEFER MARTIN , MICHAEL KARL ROEPER
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