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    18.
    发明专利
    未知

    公开(公告)号：DE19645313A1

    公开(公告)日：1998-05-07

    申请号：DE19645313

    申请日：1996-11-04

    Applicant: BASF AG

    Inventor： ZAGAR CYRILL DR ,  HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  SCHAEFER PETER DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

    IPC: A01N43/56 ,  A61K31/415 ,  A61K31/4152 ,  A61K31/4155 ,  A61K31/454 ,  A61K31/5377 ,  A61P3/10 ,  C07D231/20 ,  C07D401/10 ,  C07D401/12 ,  C07D403/10 ,  C07D403/12 ,  C07D405/12 ,  C07D231/14 ,  C07D231/16 ,  C07D231/18

    Abstract: The invention relates to substituted 3-benzylpyrazoles of formula (I), their precursors of formulas (IIa), (IIb), (IIc), their byproducts of formula (III) as well as their salts, wherein R stands for H, C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkyl sulfonyl, C1-C4 halogen alkyl sulfonyl; R stands for C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkyl thio, C1-C4 halogen alkyl thio, C1-C4 alkyl sulfinyl, C1-C4 halogen alkyl sulfinyl, C1-C4 alkyl sulfonyl, C1-C4 halogen alkyl sulfonyl; R stands for H, CN, NO2, halogen, C1-C4 alkyl, C1-C4 halogen alkyl; X -X stands for chemical bond, optionally substituted methylene-, ethylene-, ethene-1,2-diyl or oxymethylene or thiamethylene chain linked through the heteroatom to the phenyl ring; R -R stands for H, CN, NO2, halogen -O-Y -R , -O-CO-Y -R , -N(Y -R ) (Y -R ), -N(Y -R )-SO2-Y -R , -N(SO2-Y -R ) (SO2-Y -R ), -N(Y -R )-CO-Y -R , -N(Y -R ) (O-Y -R ), -S-Y -R , -SO-Y -R , -SO2-Y -R , -SO2-O-Y -R , -SO2-N(Y -R ) (Y -R ), -CO-Y -R , -C(=NOR )-Y -R , -C(=NOR )-O-Y -R , -C(=NOR )-CO-O-Y -R , -CO-O-Y -R , -CO-S-Y -R , -CO-N(Y -R ) (Y -R ), -CO-N(Y -R ) (O-Y -R ); R stands C1-C4 alkyl, C1-C4 halogen alkyl. The invention further relates to the use of (I) as herbicide, for the desiccation/defoliation of plants, and of (I), (IIa), (IIb), (IIc) and (III) for lowering the sugar content in blood.

    New 3-pyrimidinyl:benzyl-hydroxylamine derivs.
    19.
    发明专利
    New 3-pyrimidinyl:benzyl-hydroxylamine derivs. 未知

    公开(公告)号：DE19616719A1

    公开(公告)日：1997-10-30

    申请号：DE19616719

    申请日：1996-04-26

    Applicant: BASF AG

    Inventor： MENKE OLAF DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  MENGES MARKUS DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

    IPC: A01N43/54 ,  A01N47/12 ,  A01N47/30 ,  A01N53/00 ,  C07D239/46 ,  C07C239/10 ,  C07C239/16 ,  C07C239/20 ,  C07C265/12 ,  C07C271/06 ,  C07C275/40

    Abstract: N- or O-(3-(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)benzyl)-hydroxylamine derivs. of formula (I) and salts of (I; R , R and/or R = H) are new. X = -N(R )-O-, with R bonded to O or N; Y = O or S ; R = halo, CN, NO2 or CF3; R = H or halo; R = H, NH2 or Me; R = H, halo, alkyl, haloalkyl, alkylthio, alkylsulphinyl or alkylsulphonyl; R = H, halo or alkyl; R = H, alkyl, haloalkyl, 3-6C cycloalkyl or 2-6C alkenyl; R = (i) H; (ii) alkyl, cycloalkyl, haloalkyl, alkenyl, alkynyl, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl, alkoxycarbonyl, (2-6C)alkenyloxycarbonyl, (2-6C)alkynyloxycarbonyl, alkylthiocarbonyl, alkylsulphonyl or alkylcarbamoyl (all opt. substd. by 1-3 of NO2, CN, cycloalkyl, OH, alkoxy, cycloalkoxy, alkenyloxy, alkynyloxy, alkoxyalkoxy, alkylthio, alkylcarbonyl, alkylcarbonyloxy, alkylsulphinyl, alkylsulphonyl, 1-6C alkylideneaminoxy, alkylcarbamoyl, Ar, OAr, SO2Ar, Het, OHet, COZ R , OCOZ R and NR R ); or (iii) cycloa lkylcarbonyl, benzoyl, phenylsulphonyl or phenylcarbamoyl (all opt. substd. by 1-3 of halo, NO2, CN, alkyl, alkoxy and haloalkyl); R = H ; or alkyl, cycloalkyl, haloalkyl, alkenyl or alkynyl (all opt. substd. by 1-3 of NO2, CN, halo, cycloalkyl, OH, alkoxy, cycloalkoxy, alkenyloxy, alkynyloxy, alkoxyalkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, 1-6C alkylideneaminoxy, Ar, OAr, SO2Ar, Het, OHet, COZ R , OCOZ R and NR R ); Z = a bond, O, S or NR ; Z = a bond, O, S or NR ; Ar = phenyl (opt. substd. by 1-3 of halo, NO2, CN, alkyl, haloalkyl and alkoxy); Het = 3-7 membered satd., partially or completely unsatd. or aromatic heterocycle contg. 1-3 heteroatoms selected from 2 O, 2 S and 3 N (opt. substd. by 1-3 of halo, NO2, CN, alkyl, alkoxy, haloalkyl and alkylcarbonyl); R , R = H, alkyl, haloalkyl, cycloalkyl, alkenyl, alkynyl, alkoxyalkyl or alkoxycarbonylalkyl, or phenyl or phenylalkyl (both opt. ring-substd. by 1-3 of NO2, CN, halo, alkyl, haloalkyl, alkoxy or alkylcarbonyl); or Z + R and/or Z + R may complete an N-bonded heterocycle as defined for Het (except that the optional substituents do not include alkylcarbonyl); R , R = H, OH, alkyl, cycloalkyl or alkoxy; unless specified otherwise, alkyl moieties have 1-6C, alkenyl or alkynyl moieties 3-6C and cycloalkyl moieties 3-8C.

    20.
    发明专利
    未知

    公开(公告)号：DE19532048A1

    公开(公告)日：1997-03-06

    申请号：DE19532048

    申请日：1995-08-31

    Applicant: BASF AG

    Inventor： HEISTRACHER ELISABETH DR ,  HAMPRECHT GERHARD DR ,  MENKE OLAF DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

    IPC: C07D277/64 ,  A01N43/78 ,  C07D277/68 ,  C07D277/76 ,  C07D417/04 ,  A01N43/54

    Abstract: The invention concerns substituted benzothiazols of general formula (I) and their salts. In the formula: X , X = O or S; R = H, NH2, C1-C6 alkyl or C1-C6 alkyl halide; R = H, halogen, C1-C6 alkyl, C1-C6 alkyl halide, C1-C6 alkythio, C1-C6 alkylsulphinyl or C1-C6 alkylsulphonyl; R = H, halogen or C1-C6 alkyl; R = H or halogen; R = CN, halogen, C1-C6 alkyl, C1-C6 alkyl halide, C1-C6 alkoxy or C1-C6 alkoxy halide; Y = a chemical bond, -O-, -S-, -SO- or -SO2-; R = hydrogen, CN, halogen, C3-C6 cycloalkyl, C1-C6 alkyl halide, C3-C6 alkenyl, C3-C6 alkyl halide, C3-C6 alkinyl or C1-C6 alkyl, wherein the said cycloalkyl, alkyl, alkenyl and alkinyl groups can be substituted by CN, C1-C6 alkoxy, C1-C6 alkylthio, C1-C6 alkoxycarbonyl, C1-C6 alkylaminocarbonyl, di(C1-C6 alkyl)aminocarbonyl, C1-C6 alkylcarbonyloxy, C1-C6 alkoxy halide, C1-C6 alkylthio halide or C3-C6 cycloalkyl, provided that R can mean cyano only when Y stands for a chemical bond, oxygen or sulphur, and R can mean halogen only when Y stands for a chemical bond. The invention further concerns the use of these substances as herbicides and for the desiccation and abscission of plants.

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