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    New ((tetra:hydro-indazolyl)-phenyl)-propionic acid derivatives
    1.
    发明专利
    New ((tetra:hydro-indazolyl)-phenyl)-propionic acid derivatives 未知

    公开(公告)号：DE19613548A1

    公开(公告)日：1997-10-09

    申请号：DE19613548

    申请日：1996-04-04

    Applicant: BASF AG

    Inventor： HEISTRACHER ELISABETH DR ,  HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

    IPC: A01N43/56 ,  C07D231/56 ,  A01N37/00

    Abstract: 3-Chloro-tetrahydroindazolyl-phenylpropionic acid derivatives of formula (I) and their salts are new. R1, R5 = H or 1-6C alkyl; R2 = H or halo; R3 = CN, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy; R4 = halo; R6 = OR7, SR7, NR8R9 or N(R8)OR10; R7 = H, 1-6C alkyl (optionally substituted by halo, CN, 1-6C alkoxy, 1-6C alkylthio, 1-6C alkoxy-carbonyl, 1-6C alkylamino-carbonyl, di-1-6C alkylamino-carbonyl or 1-6C alkoxyimino), 2-6C alkyl (disubstituted by 1-6C alkoxy or 1-6C alkylthio), 3-6C alkenyl, 3-6C haloalkenyl, 3-6C alkynyl, 3-6C cycloalkyl, Ph' or CH2Ph'; Ph' = phenyl (optionally mono-, di- or tri- substituted by CN, NO2, halo, 1-6C alkoxy-carbonyl, 1-6C alkyl, 1-6C alkoxy, 1-6C alkylthio, 1-6C haloalkyl, 1-6C haloalkoxy or 1-6C haloalkylthio; R8-R10 = as R7, 1-6C alkyl-carbonyl or 1-6C haloalkyl-carbonyl; or R8+R9 = 4-6 membered hydrocarbon chain with 1 non-terminal CH2 optionally replaced by O or 1-4C alkylimino.

    2.
    发明专利
    未知

    公开(公告)号：DE19605766A1

    公开(公告)日：1997-08-21

    申请号：DE19605766

    申请日：1996-02-16

    Applicant: BASF AG

    Inventor： ZAGAR CYRILL DR ,  SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

    IPC: A01N57/08 ,  A01N57/24 ,  C07F9/58 ,  C07F9/6558 ,  A01N43/40

    Abstract: The invention concerns substituted 2-phenylpyridines of formula (I) and their salts, in which X = a bond, 1,2-ethinediyl, an optionally substituted methylene-, 1,2-ethanediyl- or 1,3-propylene bridge, optionally substituted methyleneoxymethylene, methylenethiamethylene, ethene-1,2-diyl, optionally substituted oxymethylene, thiamethylene, oxyethylene or thiaethylene bonded to the phenyl ring via the heteroatom; Y = -O-, -S-; -Z = -O-, -S-, -N(R )-; Z = -O2-, -S-, -N(R )-; R , R , R , R = H, C1-C6-alkyl, C1-C6-alkyl halide, hydroxy-C1-C4-alkyl, cyano-C1-C4-alkyl, C1-C4alkoxy-C1-C4alkyl, C1-C4alkoxy halide-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkinyloxy-C1-C4-alkyl, C3-C8-cycloalkoxy-C1-C4-alkyl, amino-C1-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di-(C1-C4-alkyl)amino-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthiohalide-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4alkinylthio-C1-C4-alkyl, C1-C4-alkylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphinylhalide-C1-C4-alkyl, C3-C4-alkenylsulphinyl-C1-C4-alkyl, C3-C4-alkinylsulphinyl-C1-C4-alkyl, C1-C4-alkylsulphonyl-C1-C4-alkyl, C1-C4-alkylsulphonyl halide-C1-C4-alkyl, C3-C4-alkenylsulphonyl-C1-C4-alkyl, C3-C4-alkinylsulphonyl-C1-C4-alkyl, C3-C6-alkenyl, C3-C6-alkenyl halide, cyano-C3-C6-alkenyl, C3-C6-alkinyl, C3-C6-alkinyl halide, cyano-C3-C6-alkinyl, hydroxycarbonyl-C1-C4-alkyl, (C1-C4-alkoxy)-carbonyl-C1-C4-alkyl, (C1-C4-alkylthio)carbonyl-C1-C4-alkyl, amino-carbonyl-C1-C4-alkyl, (C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, di-(C1-C4-alkyl)aminocarbonyl-C1-C4-alkyl, optionally substituted C3-C8-cycloalkyl, C3-C8-cycloalkyl-C1-C4-alkyl, phenyl, phenyl-C1-C4-alkyl, 3- to 7-members heterocyclyl or heterocyclyl-C1-C4-alkyl, wherein all the heterocycles can contain a (thio)carbonyl ring member, or R + R and/or R + R and/or R + R together in each case are an optionally substituted 1,2-ethanediyl-, 1,3-propylene-, tetramethylene-, pentamethylene- or ethyleneoxyethylene chain; or R + R together are optionally substituted 1,2-phenylene; R = CN, halogen, C1-C4-alkyl, C1-C4 alkyl halide, C1-C4 alkoxy or C1-C4 halkoxy halide; R , R are H, halogen; R is halogen, C1-C4 alkyl halide; and n = 0,1. The invention further concerns the use of these substances as herbicides and for desiccating/defoliating plants.

    4.
    发明专利
    未知

    公开(公告)号：DE19528943A1

    公开(公告)日：1997-02-13

    申请号：DE19528943

    申请日：1995-08-07

    Applicant: BASF AG

    Inventor： SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  MENKE OLAF DR ,  ZAGAR CYRILL DR ,  RACK MICHAEL DR ,  GOETZ NORBERT DR ,  HARREUS ALBRECHT DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR ,  MISLITZ ULF DR

    IPC: A01N43/40 ,  C07D213/61 ,  C07D405/12 ,  C07D409/12 ,  A01N43/34

    Abstract: Substituted 2-phenylpyridines have the formula (I), in which n equals 0, 1; R stands for halogen, C1-C6 alkyl halide; R , R stand for H, halogen; R stand for CN, halogen; X, Y stand for -O-, -S-; R , R stand for H, C1-C4 alkyl or form together an 1,2-ethylene, 1,3-propylene, 1,4-tetramethylene or 1,5-pentamethylene chain; R stands for C1-C6 alkyl halide, C3-C6 alkenyl halide, C2-C6-alkenyloxy-C1-C4-alkyl, C2-C6-alkenyloxy-C1-C4-alkoxy-C1-C4-alkyl, C3-C6-alkenyl, C3-C6-alkenyloxy-C1-C4-alkoxy-C1-C4-alkyl, C3-C6-alkenyl, C3-C6-alkadienyl, C3-C6-alkinyl, C3-C6-cycloalkyl, C5-C6-cycloalkenyl, 3-oxetanyl, 3-thietanyl, phenyl, phenyl-C1-C4-alkyl or 5/6-membered heteroaryl with 1 to 3 heteroatoms selected from the group that consists of 2 oxygen atoms, two sulphur atoms and 3 nitrogen atoms, whereas each phenyl ring and heteroaromatic compound may be unsubstituted or bear 1 to 3 substituents halogen, NO2, CN, C1-C4-alkyl, C1-C4-alkoxy or C1-C4-alkoxycarbonyl; or R and R form together an 1,2-ethylene or 1,3-propylene chain that may bear one or two C1-C4 alkyl substituents. These compounds are useful as herbicides, as plant siccative/defoliating agents.

    5.
    发明专利
    未知

    公开(公告)号：DE19500760A1

    公开(公告)日：1996-07-18

    申请号：DE19500760

    申请日：1995-01-13

    Applicant: BASF AG

    Inventor： SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  KLINTZ RALF DR ,  KOENIG HARTMANN DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR

    IPC: C07D213/24 ,  A01N43/40 ,  C07D213/61 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D213/28

    Abstract: The invention concerns substituted 2-phenylpyridines of formula (I), in which: n = 0, 1; R , R and R represent H, OH, SH, NO2, NH2, CN, COOH, CONH2, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, alkyl amino, dialkyl amino, alkyl thio, alkyl thio halide, alkoxy carbonyl, amino carbonyl, alkylamino carbonyl, dialkylamino carbonyl; R represents H, OH, SH, NO2, NH2, CN, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, alkylthio halide, alkyl sulphinyl, alkyl sulphinyl halide, alkylsulphonyl, alkylsulphonyl halide; R represents H, CN or halogen; R , R represent H or halogen; X represents -CH2- or -CO-; R , R , R , R represent H, NO2, CN, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide; R represents H, OH, NO2, NH2, NHOH, CN, CHO, COOH, COCL, CONH2, 1-pyrrolidinyl carbonyl, 1-piperidinyl carbonyl, 4-morpholinyl carbonyl, 2-hydroxy carbonyl-pyrrolidine-1-yl-carbonyl, halogen or various organic groups; R represents H, NO2, NH2, NHOH, alkylsulphonyl amino, dialkylsulphonyl amino, alkylsulphonyl amino halide, alkoxy carbonyl-alkyl halide, alkoxycarbonyl-alkenyl halide. The invention also concerns salts of these compounds. Excluded are variants of formula (I) in which R , R , R and R all represent hydrogen or R and R or R and R represent fluorine. The said compounds can be used as herbicides and for drying out and defoliating plants.

    7.
    发明专利
    未知

    公开(公告)号：DE4236880A1

    公开(公告)日：1994-05-05

    申请号：DE4236880

    申请日：1992-10-31

    Applicant: BASF AG

    Inventor： KLINTZ RALF DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  SCHAEFER PETER DR ,  KARDORFF UWE DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR

    IPC: A01N37/46 ,  A01N43/40 ,  C07C233/07 ,  C07C233/34 ,  C07C233/54 ,  C07C323/60 ,  C07C327/38 ,  C07D211/84 ,  C07D211/86 ,  C07D211/88 ,  C07D211/90 ,  C07D211/96 ,  C07D221/04 ,  C07D221/20 ,  C07D401/10 ,  C07D413/10 ,  C07D417/10 ,  C07D521/00

    Abstract: Substituted N-phenylglutarimides (I), wherein X , X = O, S; R = halogen, NO2, CN, CF3; R = H, halogen; R , R , R = H, halogen, CN, alkyl, cycloalkyl, alkenyl, alkinyl, alkyl halide, alkoxy, alkoxy halide, alkyl thio, alkyl thio halide, cyanoalkyl, alkoxy carbonyl, possibly substituted phenyl or benzyl, or 2 substituents of a C atom of the glutarimide ring are linked via a possibly substituted chain, or 2 substituents of adjacent C atoms of the glutarimide ring are linked via a possibly substituted chain; A = CHR -CHR -CO-B or CR =CR -CO-B; R = H, C1-C6-alkyl or C1-C6-alkyl halide; R = halogen, alkyl halide, OH, alkoxy or alkyl carbonyl alkoxy; R = H, halogen, CN, alkyl, alkyl halide, OH, alkoxy, alkyl carbonyl, alkoxy carbonyl or alkyl carbonyloxy; B = H, alkyl, alkenyl, alkinyl, alkyl halide, cycloalkyl, alkoxy alkyl, dialkoxy alkyl, alkyl thioalkyl, OR , SR , NR , R ; R = H, alkyl, alkenyl, alkinyl, cycloalkyl, alkyl halide, cyanoalkyl, alkenyl halide, alkoxy carbonyl alkyl, alkoxyalkyl, alkyl thioalkyl, alkylimino, alkylimino alkyl, possibly substituted phenyl or benzyl; R , R = H, alkyl, alkenyl, alkinyl, cycloalkyl, alkyl halide, alkyl carbonyl, alkoxy carbonyl, alkoxy alkyl, possibly substituted phenyl, or R und R together with the common N atom = saturated or unsaturated 4- to 7- membered heterocycle with 1-2 other heteroatoms, as well as salts of (I) that are tolerable to plants; their preparation and use as herbicides and desiccants/defoliants, as well as preproducts for preparing the N-phenylglutarimides (I).

    8.
    发明专利
    未知

    公开(公告)号：DE59310185D1

    公开(公告)日：2001-08-02

    申请号：DE59310185

    申请日：1993-04-20

    Applicant: BASF AG

    Inventor： KLINTZ RALF DR ,  HEISTRACHER ELISABETH DR ,  SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  PLATH PETER DR ,  KARDORFF UWE DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

    IPC: C07D317/30 ,  A01N37/30 ,  A01N37/32 ,  A01N37/34 ,  A01N37/46 ,  A01N43/08 ,  A01N43/12 ,  A01N43/16 ,  A01N43/18 ,  A01N43/28 ,  A01N43/32 ,  A01N43/38 ,  A01N43/40 ,  A01N43/74 ,  A01N43/78 ,  C07C233/57 ,  C07C233/60 ,  C07C233/61 ,  C07C233/62 ,  C07C233/63 ,  C07C237/42 ,  C07C251/48 ,  C07C251/60 ,  C07C255/13 ,  C07C255/24 ,  C07C255/42 ,  C07C255/46 ,  C07C255/58 ,  C07C271/62 ,  C07D209/48 ,  C07D295/185 ,  C07D307/12 ,  C07D307/90 ,  C07D309/06 ,  C07D335/02 ,  C07D339/06 ,  C07D339/08 ,  C07D401/10 ,  C07D413/06 ,  C07D413/10 ,  C07D417/06 ,  C07D417/10

    Abstract: Substd. cyclohexene-1,2-dicarboxylic acid derivs. of formula (I), and their salts are new. Where T = CONR1R2 or CN; R1, R2 = H; R, 3-6C alkenyl, or 3-6C alkynyl, all opt. substd. by 1-3 halo, CN, NH2, SH, OH, OR, RSO, RSO2, RCO, COOH, ROCO, RNH, (R)2N, RNHCO, (R)2NCO, (RO)(HO)PO, (RO)2PO, or Ar); or Ar' when R1 is H or R, R2 may also be OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-7C cycloalkoxy 5-7 cycloalkenyloxy, 1-6C haloalkoxy, 3-6C halo alkenyloxy, 3-7C cycloalkyl-1-6C alkoxy, RCOO, 1-6C cyanoalkoxy, etc.; NR1R2 = a 3-8 membered non-aromatic heterocycle contg. 1-3N atoms and/or one O or S atom and opt. 1-2 CO gps., the ring being opt. substd. by 1-3R; Ar = phenyl or a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1O or 1S) both opt. substd. on every substitutable atom by OH, halo, CN, NO2, CF3, R or RO; Ar' as Ar except that the heterocycle contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S, and only C-atoms may be substd. R = 1-6C alkyl; R3 = H or R; R4 = H or halo; R5 = H, halo, NO2, CN or CF3; R6 = a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1-2O and 1-2S, and in which 1-2 CH2 gps. are opt. replaced by CO), opt. C-substd. by R, 2-6C alkenyl, 2-6C alkynyl, RO, RS, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-6C alkenylthio, 3-6C alkynylthio, ROCO, NO2, NH2, halo, 1-4C alkylamino, di(1-4C)alkylamino, CN, 1-6C cyanoalkyl, 1-6C haloalkyl or 1-6C haloalkyloxy; ACN, ACOB, OR9, C(O)R10, C(S)R10, C(NR16)R10, A = straight chain 2-4C alkenylene or 2-4C alkynylene, both opt. substd. by 1-2 halo, CN, R, 1-6C haloalkyl, OH, RO, RCOO, ROCO or RCO; B = H, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, OR17, SR17, phenyl (opt. substd. by 1-3R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO), 1-6C alkoxy-1-6C alkyl, di(1-6C alkoxy)-1-6C alkyl, 1-6C alkylthio-1-6C alkyl or NR18R19; R17 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, 1-6C cyanoalkyl, 3-6C haloalkenyl, ROCO, 1-6C alkoxy(1-6C)alkyl, 1-6C alkoxycarbonyl (1-6C) alkyl, 1-6C alkoxyimino(1-6C)alkyl, or phenyl (opt. substd. by 1-3 R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO); R18, R19 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, RCO, ROCO, 1-6C alkoxy (1-6C)alkyl, or phenyl (opt. substd. by 1-3R, 3-6C alkenyl, halo, CN, NO2, RO or ROCO); R9 = 1-6C cyanoalkyl RQ, 1-6C haloalkyl, 3-6C haloalkenyl, 3-6C alkynyl, 3-6C haloalkynyl, 1-6 alkoxycarbonyl-2-6C alkyl, ROQOCOQ, 1-6C alkoxyimino (1-6C)alkyl, or phenyl, phenyl-Q, 3-8 membered heterocyclyl or heterocyclyl-Q (where the heterocycles contain 1-4 heteroatoms, etc.; R10 = H, CN, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, ROCO, ROCOQ, or phenyl (opt. substd. by 1-3 halo, CN, NO2, R, 3-6C alkenyl, 1-6C haloalkyl, RO or ROCO); R16 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-7C cycloalkyl, 1-6C haloalkyl, phenyl (opt. substd. by 1-3R, halo, CN, 2-6C alkenyl, NO2, 1-6C haloalkyl, 1-6C alkoxy, or ROCO), ROQ, OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 5-7C cycloalkoxy, 5-7C cycloalkenyloxy, etc.; R5+R6 = an opt. unsatd. 3-5 membered carbon chain which opt. contains 1-2O, S, N, CO or 1-6C alkoximino gps. and which is opt. substd. by 1-2 CN, NO2, NH2, halo, R, 1-6C haloalkyl, 2-6C alkenyl, 2-6C alkynyl, 1-6C cyanoalkyl, RCOQ, phenyl-Q or 3-8 membered heterocyclyl-1-6C alkyl, where the heterocycle is opt. unsatd. and contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S; provided that when T is CONR1R2 then R9 is not 3-6C alkynyl and R16 is not 1-6C alkoxy, and when T is CN then R9 is not 1-6C haloalkoxy.

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