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    1.
    发明专利
    未知

    公开(公告)号：DE59310185D1

    公开(公告)日：2001-08-02

    申请号：DE59310185

    申请日：1993-04-20

    Applicant: BASF AG

    Inventor： KLINTZ RALF DR ,  HEISTRACHER ELISABETH DR ,  SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  PLATH PETER DR ,  KARDORFF UWE DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

    IPC: C07D317/30 ,  A01N37/30 ,  A01N37/32 ,  A01N37/34 ,  A01N37/46 ,  A01N43/08 ,  A01N43/12 ,  A01N43/16 ,  A01N43/18 ,  A01N43/28 ,  A01N43/32 ,  A01N43/38 ,  A01N43/40 ,  A01N43/74 ,  A01N43/78 ,  C07C233/57 ,  C07C233/60 ,  C07C233/61 ,  C07C233/62 ,  C07C233/63 ,  C07C237/42 ,  C07C251/48 ,  C07C251/60 ,  C07C255/13 ,  C07C255/24 ,  C07C255/42 ,  C07C255/46 ,  C07C255/58 ,  C07C271/62 ,  C07D209/48 ,  C07D295/185 ,  C07D307/12 ,  C07D307/90 ,  C07D309/06 ,  C07D335/02 ,  C07D339/06 ,  C07D339/08 ,  C07D401/10 ,  C07D413/06 ,  C07D413/10 ,  C07D417/06 ,  C07D417/10

    Abstract: Substd. cyclohexene-1,2-dicarboxylic acid derivs. of formula (I), and their salts are new. Where T = CONR1R2 or CN; R1, R2 = H; R, 3-6C alkenyl, or 3-6C alkynyl, all opt. substd. by 1-3 halo, CN, NH2, SH, OH, OR, RSO, RSO2, RCO, COOH, ROCO, RNH, (R)2N, RNHCO, (R)2NCO, (RO)(HO)PO, (RO)2PO, or Ar); or Ar' when R1 is H or R, R2 may also be OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-7C cycloalkoxy 5-7 cycloalkenyloxy, 1-6C haloalkoxy, 3-6C halo alkenyloxy, 3-7C cycloalkyl-1-6C alkoxy, RCOO, 1-6C cyanoalkoxy, etc.; NR1R2 = a 3-8 membered non-aromatic heterocycle contg. 1-3N atoms and/or one O or S atom and opt. 1-2 CO gps., the ring being opt. substd. by 1-3R; Ar = phenyl or a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1O or 1S) both opt. substd. on every substitutable atom by OH, halo, CN, NO2, CF3, R or RO; Ar' as Ar except that the heterocycle contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S, and only C-atoms may be substd. R = 1-6C alkyl; R3 = H or R; R4 = H or halo; R5 = H, halo, NO2, CN or CF3; R6 = a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1-2O and 1-2S, and in which 1-2 CH2 gps. are opt. replaced by CO), opt. C-substd. by R, 2-6C alkenyl, 2-6C alkynyl, RO, RS, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-6C alkenylthio, 3-6C alkynylthio, ROCO, NO2, NH2, halo, 1-4C alkylamino, di(1-4C)alkylamino, CN, 1-6C cyanoalkyl, 1-6C haloalkyl or 1-6C haloalkyloxy; ACN, ACOB, OR9, C(O)R10, C(S)R10, C(NR16)R10, A = straight chain 2-4C alkenylene or 2-4C alkynylene, both opt. substd. by 1-2 halo, CN, R, 1-6C haloalkyl, OH, RO, RCOO, ROCO or RCO; B = H, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, OR17, SR17, phenyl (opt. substd. by 1-3R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO), 1-6C alkoxy-1-6C alkyl, di(1-6C alkoxy)-1-6C alkyl, 1-6C alkylthio-1-6C alkyl or NR18R19; R17 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, 1-6C cyanoalkyl, 3-6C haloalkenyl, ROCO, 1-6C alkoxy(1-6C)alkyl, 1-6C alkoxycarbonyl (1-6C) alkyl, 1-6C alkoxyimino(1-6C)alkyl, or phenyl (opt. substd. by 1-3 R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO); R18, R19 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, RCO, ROCO, 1-6C alkoxy (1-6C)alkyl, or phenyl (opt. substd. by 1-3R, 3-6C alkenyl, halo, CN, NO2, RO or ROCO); R9 = 1-6C cyanoalkyl RQ, 1-6C haloalkyl, 3-6C haloalkenyl, 3-6C alkynyl, 3-6C haloalkynyl, 1-6 alkoxycarbonyl-2-6C alkyl, ROQOCOQ, 1-6C alkoxyimino (1-6C)alkyl, or phenyl, phenyl-Q, 3-8 membered heterocyclyl or heterocyclyl-Q (where the heterocycles contain 1-4 heteroatoms, etc.; R10 = H, CN, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, ROCO, ROCOQ, or phenyl (opt. substd. by 1-3 halo, CN, NO2, R, 3-6C alkenyl, 1-6C haloalkyl, RO or ROCO); R16 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-7C cycloalkyl, 1-6C haloalkyl, phenyl (opt. substd. by 1-3R, halo, CN, 2-6C alkenyl, NO2, 1-6C haloalkyl, 1-6C alkoxy, or ROCO), ROQ, OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 5-7C cycloalkoxy, 5-7C cycloalkenyloxy, etc.; R5+R6 = an opt. unsatd. 3-5 membered carbon chain which opt. contains 1-2O, S, N, CO or 1-6C alkoximino gps. and which is opt. substd. by 1-2 CN, NO2, NH2, halo, R, 1-6C haloalkyl, 2-6C alkenyl, 2-6C alkynyl, 1-6C cyanoalkyl, RCOQ, phenyl-Q or 3-8 membered heterocyclyl-1-6C alkyl, where the heterocycle is opt. unsatd. and contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S; provided that when T is CONR1R2 then R9 is not 3-6C alkynyl and R16 is not 1-6C alkoxy, and when T is CN then R9 is not 1-6C haloalkoxy.

    New (tetra:hydro)phthalimido-cinnamic acid derivatives
    3.
    发明专利
    New (tetra:hydro)phthalimido-cinnamic acid derivatives 未知

    公开(公告)号：DE19610701A1

    公开(公告)日：1997-09-25

    申请号：DE19610701

    申请日：1996-03-19

    Applicant: BASF AG

    Inventor： HEISTRACHER ELISABETH DR ,  HAMPRECHT GERHARD DR ,  MENGES MARKUS DR ,  MENKE OLAF DR ,  SCHAEFER PETER DR ,  ZAGAR CYRILL DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR ,  WALTER HELMUT DR

    IPC: A01N37/46 ,  C07D209/48 ,  A01N43/38 ,  C07C205/07 ,  C07C211/46

    Abstract: Tetrahydrophthalimido-cinnamic acid derivatives of formula (I) and their salts are new. R1 = H or 1-6C alkyl; R2 = CN, halo, 1-6C alkyl, 1-6C haloalkyl, 1-6C alkoxy or 1-6C haloalkoxy; R3 = NO2, CN or halo; R4 = OR5, SR5, NR6R7 or NR6OR7; R5 = H, 1-6C alkyl (optionally substituted by halo, cyano, 1-6C alkoxy, 1-6C alkylthio,(1-6C alkyl)carbonyl, (1-6C alkyl)aminocarbonyl, di(1-6C alkyl)aminocarbonyl or 1-6C alkyloxyimino), 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, di(1-6C alkoxy)-2-6C alkyl, di(1-6C alkylthio)-2-6C alkyl, 3-6C haloalkenyl, or phenyl or benzyl (both optionally ring-substituted by 1-3 of CN, NO2, halo, 1-6C alkyl, 1-6C haloalkyl, 1-6C alkoxy, 1-6C haloalkoxy, 1-6C alkylthio, 1-6C haloalkylthio and (1-6C alkyl)carbonyl); R6-R8 = (1-6C alkyl)carbonyl, (1-6C haloalkyl)carbonyl or as for R5; or R6+R7 = 4-6-membered hydrocarbon chain, optionally with a non-terminal CH2 replaced by O or 1-4C alkylimino. Also claimed are (1) the preparation of substituted anilines (amino-cinnamic acid derivatives) of formula (X) by reduction of the corresponding nitro compound of formula (XI); and (2) the preparation of the nitro compounds (XI) (a) from 4-chloro-5-nitro-2-R2-aniline by the Meerwein reaction, using an alkyne of formula H-C?=C-COR4 (III), or (b) from 4-chloro-5-nitro-2-R2-benzaldehyde by reaction with an ylide of formula (Ar)3P=CX-COR4 (V), or an acidic CH compound of formula CH2Y-COR4 (VI). X = F, Cl or Br; Y = NO2 or CN; Ar = optionally substituted aromatic residue.

    5.
    发明专利
    未知

    公开(公告)号：DE19500758A1

    公开(公告)日：1996-07-18

    申请号：DE19500758

    申请日：1995-01-13

    Applicant: BASF AG

    Inventor： SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  HEISTRACHER ELISABETH DR ,  KLINTZ RALF DR ,  KOENIG HARTMANN DR ,  HARREUS ALBRECHT DR ,  GOETZ NORBERT DR ,  WALTER HELMUT DR ,  WESTPHALEN KARL-OTTO DR ,  MISLITZ ULF DR

    IPC: C07D213/24 ,  A01N43/40 ,  C07D213/61 ,  C07D405/10 ,  C07D405/12 ,  C07D401/12 ,  A01N43/34

    Abstract: The invention concerns substituted 2-phenylpyridines of formula (I), in which: n = 0, 1; R , R and R represent H, OH, SH, NO2, NH2, CN, COOH, CONH2, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, alkyl amino, dialkyl amino, alkyl thio, alkyl thio halide, alkoxy carbonyl, amino carbonyl, alkylamino carbonyl, dialkylamino carbonyl; R represents H, OH, SH, NO2, NH2, CN, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, alkylthio, alkyl thio halide, alkyl sulphinyl, alkyl sulphinyl halide, alkylsulphonyl, alkyl halide sulphonyl; R represents H, CN or halogen; R , R represent H or halogen; R represents H, OH, NO2, CN, CF3-SO2-O-, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide; X represents -CO-, -O-C(R , R )-CO-, -S-(R , R )-CO-, -CH2-CH(R )-CO-, -CH=C(R )-CO-; R , R represent H or alkyl; R represents H, halogen or alkyl; Z represents optionally substituted tetrahydrofurane-3-yl or -C(R , COR )-CH2-COR ; R represents H or alkyl; R and R represent OH, NH2, pyrrolidinyl, piperidinyl, morpholinyl, alkoxy, alkenyloxy, alkinyloxy, alkoxyalkoxy, cycloalkyloxy, alkylamino, dialkylamino, cycloalkylamino, dicycloalkylamino, alkenylamino, alkinylamino, or alternatively together represent -N(R )-N(R )-, -N(R )-; R , R represent H or alkyl; R represents H, alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy. The invention also concerns salts of these compounds and the use of the compounds and salts as herbicides and for drying out and defoliating plants.

    7.
    发明专利
    未知

    公开(公告)号：DE4429006A1

    公开(公告)日：1996-02-22

    申请号：DE4429006

    申请日：1994-08-16

    Applicant: BASF AG

    Inventor： HEISTRACHER ELISABETH DR ,  BUSSCHE-HUENNEFELD CHRISTOPH D ,  HAMPRECHT GERHARD DR ,  KLINTZ RALF DR ,  SCHAEFER PETER DR ,  WESTPHALEN KARL-OTTO DR ,  GERBER MATTHIAS DR ,  WALTER HELMUT DR

    IPC: A01N43/653 ,  C07D249/12 ,  C07D403/12 ,  C07D413/12 ,  A01N43/647

    Abstract: Substituted triazolinones of formula (I) are disclosed, in which R , R represent C1-C6 alkyl or C1-C6 alkyl halide; R represents H or a halogen; R represents CN, a halogen, C1-C6 alkyl, C1-C6 alkyl halide, C1-C6 alkoxy or C1-C6 alkoxyl halide; R represents NO2, CN or hydrogen; R represents -OR , -SR , -N(R )-R or -N(R )-OR ; R represents H, C1-C6 alkyl, C3-C6 alkenyl, C3-C6 alkinyl, C3-C6 cycloalkyl, C1-C6 alkyl halide, cyano-C1-C6 alkyl, C1-C6 alkoxy-C1-C6-alkyl, C1-C6 alkylthio-C1-C6-alkyl, C1-C6 alkoxycarbonyl-C1-C6-alkyl, C1-C6-alkylaminocarbonyl-C1-C6-alkyl, Di-(C1-C6-alkyl)-aminocarbonyl-C1-C6 alkyl, C1-C6 alkyloxyamino-C1-C6 alkyl, Di-(C1-C6-alkoxy)-C2-C6-alkyl, Di-(C1-C6-alkylthio)-C2-C6 alkyl, C3-C6 alkenyl halide, (as required) substituted phenyl or benzyl; R , R , R represent C1-C6 alkylcarbonyl, C1-C6 alkylcarbonyl halide or one of the possible R groups; R + R represent a halide 4 to 6-membered C chain in which one methylene unit can be replaced by oxygen or C1-C4 alkylamino. Also disclosed are the salts of compounds of formula (I). Use as herbicides, for desiccation and defoliation of plants.

    9.
    发明专利
    未知

    公开(公告)号：ES2066890T3

    公开(公告)日：1995-03-16

    申请号：ES90103619

    申请日：1990-02-24

    Applicant: BASF AG

    Inventor： SAUPE THOMAS DR ,  SCHAEFER PETER DR ,  MEYER NORBERT DR ,  WUERZER THOMAS DR ,  WESTPHALEN KARL-OTTO DR

    IPC: A01N25/32 ,  A01N43/90 ,  C07D471/04

    Abstract: Substituted 1,8-naphthyridines of the general formula I in which the substituents have the following meaning: R denotes amino, substituted NR R , in which R denotes C1-C12-alkyl, C3-C6-alkenyl, C3-C8-cycloalkyl, substituted or unsubstituted phenyl or phenyl-(C1-C3)-alkyl or a group in which A represents C1-C8-alkyl, substituted or unsubstituted phenyl, amino, alkyl- or dialkylamino each having 1 to 6 C atoms per alkyl radical, phenylamino, morpholino or piperidyl, and R denotes hydrogen, C1-C12-alkyl, C3-C8-cycloalkyl or R and R are linked together to form a saturated or unsaturated 5- or 6-membered heterocycle, which may contain a further heteroatom such as oxygen or nitrogen; or denote hydroxyl, mercapto, halogen or XR , in which X denotes oxygen or sulphur and R represents C1-C12-alkyl, C1-C4-alkoxycarbonyl-(C1-C4)-alkyl, C5-C8-cycloalkyl, substituted or unsubstituted phenyl or phenyl-(C1-C3)-alkyl, R denotes hydrogen, C1-C12-alkyl, C3-C8-cycloalkyl, substituted or unsubstituted R denotes phenyl [sic] or phenyl-(C1-C3-)-alkyl, hydroxyl, halogen, mercapto, C1-C4-alkoxy, C1-C4-alkylthio, amino, mono- or dialkylamino having 1 to 6 C atoms per alkyl radical, substituted or unsubstituted phenoxy or phenylthio, halogen-(C1-C3)-alkyl, C1-C4-alkoxy(C1-C3)-alkyl, C1-C4-alkylthio-(C1-C3)-alkyl, amino-(C1-C3)-alkyl, C1-C4-acyloxy, substituted or unsubstituted hydrazino, cyano and thiocyanato, R denotes hydrogen, C1-C12-alkyl, C3-C8-cycloalkyl, substituted or unsubstituted phenyl or phenyl-(C1-C3)-alkyl, halogen, halogen-(C1-C3)-alkyl, C1-C4-alkoxy-(C1-C3)-alkyl, C1-C4-alkylthio- (C1-C3)-alkyl, amino-(C1-C3)-alkyl, carboxyl, C1-C4-alkoxycarbonyl, non-phytotoxic salts thereof and processes for their preparation and their use as antidotes.

    New cyclohexene-1,2-di:carboxylic acid derivs.
    10.
    发明专利
    New cyclohexene-1,2-di:carboxylic acid derivs. 未知

    公开(公告)号：DE4238001A1

    公开(公告)日：1994-07-21

    申请号：DE4238001

    申请日：1992-11-11

    Applicant: BASF AG

    Inventor： KLINTZ RALF DR ,  HEISTRACHER ELISABETH DR ,  SCHAEFER PETER DR ,  HAMPRECHT GERHARD DR ,  PLATH PETER DR ,  KARDORFF UWE DR ,  GERBER MATTHIAS DR ,  WESTPHALEN KARL-OTTO DR ,  WALTER HELMUT DR

    IPC: A01N37/30 ,  A01N37/32 ,  A01N37/34 ,  A01N37/46 ,  A01N43/12 ,  A01N43/16 ,  A01N43/40 ,  A01N43/74 ,  C07C233/61 ,  C07C233/63 ,  C07C255/13 ,  C07C255/46 ,  C07D209/48 ,  C07D295/185 ,  C07D307/12 ,  C07D307/90 ,  C07D309/06 ,  C07D339/08 ,  C07D401/10 ,  C07D413/10 ,  C07D417/10 ,  C07C233/57 ,  A01N37/22 ,  A01N43/28 ,  C07D265/30 ,  C07D295/192 ,  C07D315/00 ,  C07D339/06

    Abstract: Substd. cyclohexene-1,2-dicarboxylic acid derivs. of formula (I), and their salts are new. Where T = CONR1R2 or CN; R1, R2 = H; R, 3-6C alkenyl, or 3-6C alkynyl, all opt. substd. by 1-3 halo, CN, NH2, SH, OH, OR, RSO, RSO2, RCO, COOH, ROCO, RNH, (R)2N, RNHCO, (R)2NCO, (RO)(HO)PO, (RO)2PO, or Ar); or Ar' when R1 is H or R, R2 may also be OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-7C cycloalkoxy 5-7 cycloalkenyloxy, 1-6C haloalkoxy, 3-6C halo alkenyloxy, 3-7C cycloalkyl-1-6C alkoxy, RCOO, 1-6C cyanoalkoxy, etc.; NR1R2 = a 3-8 membered non-aromatic heterocycle contg. 1-3N atoms and/or one O or S atom and opt. 1-2 CO gps., the ring being opt. substd. by 1-3R; Ar = phenyl or a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1O or 1S) both opt. substd. on every substitutable atom by OH, halo, CN, NO2, CF3, R or RO; Ar' as Ar except that the heterocycle contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S, and only C-atoms may be substd. R = 1-6C alkyl; R3 = H or R; R4 = H or halo; R5 = H, halo, NO2, CN or CF3; R6 = a 3-8 membered heterocycle (contg. 1-4 heteroatoms selected from 1-4N, 1-2O and 1-2S, and in which 1-2 CH2 gps. are opt. replaced by CO), opt. C-substd. by R, 2-6C alkenyl, 2-6C alkynyl, RO, RS, 3-6C alkenyloxy, 3-6C alkynyloxy, 3-6C alkenylthio, 3-6C alkynylthio, ROCO, NO2, NH2, halo, 1-4C alkylamino, di(1-4C)alkylamino, CN, 1-6C cyanoalkyl, 1-6C haloalkyl or 1-6C haloalkyloxy; ACN, ACOB, OR9, C(O)R10, C(S)R10, C(NR16)R10, A = straight chain 2-4C alkenylene or 2-4C alkynylene, both opt. substd. by 1-2 halo, CN, R, 1-6C haloalkyl, OH, RO, RCOO, ROCO or RCO; B = H, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, OR17, SR17, phenyl (opt. substd. by 1-3R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO), 1-6C alkoxy-1-6C alkyl, di(1-6C alkoxy)-1-6C alkyl, 1-6C alkylthio-1-6C alkyl or NR18R19; R17 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, 1-6C cyanoalkyl, 3-6C haloalkenyl, ROCO, 1-6C alkoxy(1-6C)alkyl, 1-6C alkoxycarbonyl (1-6C) alkyl, 1-6C alkoxyimino(1-6C)alkyl, or phenyl (opt. substd. by 1-3 R, 2-6C alkenyl, halo, CN, NO2, 1-6C haloalkyl, RO or ROCO); R18, R19 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-6C cycloalkyl, 1-6C haloalkyl, RCO, ROCO, 1-6C alkoxy (1-6C)alkyl, or phenyl (opt. substd. by 1-3R, 3-6C alkenyl, halo, CN, NO2, RO or ROCO); R9 = 1-6C cyanoalkyl RQ, 1-6C haloalkyl, 3-6C haloalkenyl, 3-6C alkynyl, 3-6C haloalkynyl, 1-6 alkoxycarbonyl-2-6C alkyl, ROQOCOQ, 1-6C alkoxyimino (1-6C)alkyl, or phenyl, phenyl-Q, 3-8 membered heterocyclyl or heterocyclyl-Q (where the heterocycles contain 1-4 heteroatoms, etc.; R10 = H, CN, R, 3-6C alkenyl, 3-6C alkynyl, 1-6C haloalkyl, 3-7C cycloalkyl, ROCO, ROCOQ, or phenyl (opt. substd. by 1-3 halo, CN, NO2, R, 3-6C alkenyl, 1-6C haloalkyl, RO or ROCO); R16 = H, R, 3-6C alkenyl, 3-6C alkynyl, 3-7C cycloalkyl, 1-6C haloalkyl, phenyl (opt. substd. by 1-3R, halo, CN, 2-6C alkenyl, NO2, 1-6C haloalkyl, 1-6C alkoxy, or ROCO), ROQ, OH, RO, 3-6C alkenyloxy, 3-6C alkynyloxy, 5-7C cycloalkoxy, 5-7C cycloalkenyloxy, etc.; R5+R6 = an opt. unsatd. 3-5 membered carbon chain which opt. contains 1-2O, S, N, CO or 1-6C alkoximino gps. and which is opt. substd. by 1-2 CN, NO2, NH2, halo, R, 1-6C haloalkyl, 2-6C alkenyl, 2-6C alkynyl, 1-6C cyanoalkyl, RCOQ, phenyl-Q or 3-8 membered heterocyclyl-1-6C alkyl, where the heterocycle is opt. unsatd. and contains 1-4 heteroatoms selected from 1-4N, 1-20 and 1-2S; provided that when T is CONR1R2 then R9 is not 3-6C alkynyl and R16 is not 1-6C alkoxy, and when T is CN then R9 is not 1-6C haloalkoxy.

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