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11.
公开(公告)号:EA012040B1
公开(公告)日:2009-06-30
申请号:EA200701821
申请日:2006-03-08
Applicant: BASF AG
Inventor: AMRHEIN PATRICK , KLEIST GUNNAR , HAENTZSCHEL DIRK , HABICHT JOERG , SCHOPKE HOLGER
Abstract: Настоящееизобретениеотноситсяк водныминсектициднымпрепаратамв видеводнойдисперсиивысокодисперсныхполимерныхчастиц, которыесодержатпоменьшеймереодноинсектицидноеорганическоедействующеевещество, имеющеерастворимостьв воденеболеечем 5 г/лпри 25°C и 1013 мбар, икоторыеимеютсреднийразмер, определенныйприпомощидинамическогорассеиваниясвета, неболеечем 300 нм, гдеполимерныечастицы, которыесодержатпоменьшеймереодноинсектицидноедействующеевещество, имеюткатионныйповерхностныйзаряди гдеводнаядисперсияполимерныхчастиц, включающихдействующеевещество, получаетсяпутемрадикальнойэмульсионнойполимеризациив воднойфаземономернойкомпозицииэтиленненасыщенныхмономеров M, вкоторойэтиленненасыщенныемономеры M содержатпоменьшеймереодноинсектицидноедействующеевеществов растворенномвиде. Изобретениетакжеотноситсяк применениютакихводныхинсектицидныхкомпозицийдлязащитылигноцеллюлозныхматериалов, вчастностидревесных, отнападениявредныхнасекомых.
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公开(公告)号:AP2006003655A0
公开(公告)日:2006-06-30
申请号:AP2006003655
申请日:2004-12-21
Applicant: BASF AG
Inventor: THOMAS JOHN H , SCHOPKE HOLGER , BURGER JOACHIM
IPC: A01N25/10 , A01N53/00 , D06M15/19 , D06M15/263 , D06M15/273 , D06M15/29 , D06M15/564 , D06M15/568
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公开(公告)号:AU746031B2
公开(公告)日:2002-04-11
申请号:AU3990497
申请日:1997-10-02
Applicant: BASF AG
Inventor: KRONER HUBERTUS , KLANIG WOLFGANG , MORRISON BRADLEY RONALD , KLOSTERMANN RAINER , SCHOPKE HOLGER , KASTENHUBER WALTER
IPC: B01J19/18 , C08F2/00 , C08F2/22 , C08F12/08 , C08F14/06 , C08F14/08 , C08F18/08 , C08F20/00 , C08F36/06 , C08F20/06 , C08F20/10 , C08F20/56 , C08F20/44
Abstract: In a process for the preparation of homo or copolymers of at least one polymerisable monomer consisting of styrene, butadiene, vinyl chloride, vinyl acetate, vinylidene chloride, alkyl(meth)acrylate, meth(acrylic)acid, (meth)acrylonitrile or (meth)acrylamide by an emulsion polymerisation technique, reaction is carried out at at least 40 degrees C in the presence of a dispersing agent and a radical initiator such that at least 85 wt.% of the polymer is prepared by (a) mixing water, inert solvent and optionally dispersing agent and optionally a portion of the monomer, (b) adding initiator and (c) adding the rest of the monomer, optionally in the form of an emulsion with further water and optionally further dispersing agent or processing aids. Steps (a) and (b) or (b) and (c) may be carried out together at 40-120 degrees C and the resulting dispersion from each step or all the steps is recirculated around a flow loop external to the reaction vessel containing a low shear pump and a heat exchanger exhibiting a laminar flow profile. An apparatus for carrying out the reaction is also claimed and comprises means for storing and feeding reactants and processing aids, a reactor vessel with a heating/cooling mantle and means for draining, an external flow loop with a low shear pump and heat exchanger exhibiting a laminar flow profile and necessary connecting pipes.
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公开(公告)号:AU6394801A
公开(公告)日:2001-12-17
申请号:AU6394801
申请日:2001-06-02
Applicant: BASF AG
Inventor: BOECKH DIETER , NORENBERG RALF , DETERING JURGEN , BERTLEFF WERNER , SCHOPKE HOLGER , LEYRER REINHOLD J , HUFF JURGEN
IPC: C11D1/38 , C11D1/86 , C11D3/00 , C11D3/02 , C11D3/37 , C11D11/00 , D06M15/263 , D06M23/08 , C11D17/00 , C11D17/06 , C11D1/02 , C11D1/66 , C11D3/04
Abstract: Use of cationically modified, particulate, hydrophobic polymers, the surface of which has been cationically modified by coating with polyvalent metal ions and/or cationic surfactants, the particle size of which is 10 nm to 100 mum, as additive to rinse compositions, care compositions, detergents and cleaners, and also rinse compositions, care compositions, detergents and cleaners which comprise the cationically modified, particulate, hydrophobic polymers.
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公开(公告)号:CA2410442A1
公开(公告)日:2001-12-13
申请号:CA2410442
申请日:2001-06-02
Applicant: BASF AG
Inventor: MOHR BERNHARD , HUFF JURGEN , SCHOPKE HOLGER , HILDEBRANDT SOREN , BOECKH DIETER , LEYRER REINHOLD J , NORENBERG RALF
IPC: D06L1/12 , C08J3/205 , C11D3/37 , C11D17/06 , D06M15/267 , D06M15/285 , D06M15/356
Abstract: The invention relates to the use of cationically-modified, particle-shaped, hydrophobic polymers as addition agents in rinsing, care, detergent, and cleaning products. The surface of said polymers is cationically modified by means of a coating of cationic polymers and the particle size of said polyme rs ranges from 10 nm to 100 .mu.m.
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公开(公告)号:AU3990497A
公开(公告)日:1998-04-09
申请号:AU3990497
申请日:1997-10-02
Applicant: BASF AG
Inventor: KRONER HUBERTUS , KLANIG WOLFGANG , MORRISON BRADLEY RONALD , KLOSTERMANN RAINER , SCHOPKE HOLGER , KASTENHUBER WALTER
IPC: B01J19/18 , C08F2/00 , C08F2/22 , C08F12/08 , C08F14/06 , C08F14/08 , C08F18/08 , C08F20/00 , C08F36/06 , C08F20/06 , C08F20/10 , C08F20/56 , C08F20/44
Abstract: In a process for the preparation of homo or copolymers of at least one polymerisable monomer consisting of styrene, butadiene, vinyl chloride, vinyl acetate, vinylidene chloride, alkyl(meth)acrylate, meth(acrylic)acid, (meth)acrylonitrile or (meth)acrylamide by an emulsion polymerisation technique, reaction is carried out at at least 40 degrees C in the presence of a dispersing agent and a radical initiator such that at least 85 wt.% of the polymer is prepared by (a) mixing water, inert solvent and optionally dispersing agent and optionally a portion of the monomer, (b) adding initiator and (c) adding the rest of the monomer, optionally in the form of an emulsion with further water and optionally further dispersing agent or processing aids. Steps (a) and (b) or (b) and (c) may be carried out together at 40-120 degrees C and the resulting dispersion from each step or all the steps is recirculated around a flow loop external to the reaction vessel containing a low shear pump and a heat exchanger exhibiting a laminar flow profile. An apparatus for carrying out the reaction is also claimed and comprises means for storing and feeding reactants and processing aids, a reactor vessel with a heating/cooling mantle and means for draining, an external flow loop with a low shear pump and heat exchanger exhibiting a laminar flow profile and necessary connecting pipes.
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公开(公告)号:ID17248A
公开(公告)日:1997-12-11
申请号:ID973346
申请日:1997-10-02
Applicant: BASF AG
Inventor: KRONER HUBERTUS , KLANIG WOLFGANG , MORRISON BRADLEY RONALD , SCHOPKE HOLGER , KASTENHUBER WLATER
IPC: B01J19/18 , C08F2/00 , C08F2/22 , C08F12/08 , C08F14/06 , C08F14/08 , C08F18/08 , C08F20/00 , C08F36/06
Abstract: In a process for the preparation of homo or copolymers of at least one polymerisable monomer consisting of styrene, butadiene, vinyl chloride, vinyl acetate, vinylidene chloride, alkyl(meth)acrylate, meth(acrylic)acid, (meth)acrylonitrile or (meth)acrylamide by an emulsion polymerisation technique, reaction is carried out at at least 40 degrees C in the presence of a dispersing agent and a radical initiator such that at least 85 wt.% of the polymer is prepared by (a) mixing water, inert solvent and optionally dispersing agent and optionally a portion of the monomer, (b) adding initiator and (c) adding the rest of the monomer, optionally in the form of an emulsion with further water and optionally further dispersing agent or processing aids. Steps (a) and (b) or (b) and (c) may be carried out together at 40-120 degrees C and the resulting dispersion from each step or all the steps is recirculated around a flow loop external to the reaction vessel containing a low shear pump and a heat exchanger exhibiting a laminar flow profile. An apparatus for carrying out the reaction is also claimed and comprises means for storing and feeding reactants and processing aids, a reactor vessel with a heating/cooling mantle and means for draining, an external flow loop with a low shear pump and heat exchanger exhibiting a laminar flow profile and necessary connecting pipes.
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公开(公告)号:EA012571B1
公开(公告)日:2009-10-30
申请号:EA200601954
申请日:2005-04-25
Applicant: BASF AG
Inventor: GOTTSCHE REINER , KLEIST GUNNAR , HABICHT JOERG , SCHOPKE HOLGER , AMRHEIN PATRICK
IPC: A01N25/04 , A01N43/36 , A01N43/653 , A01N47/12 , B27K3/15
Abstract: Изобретениеотноситсяк воднымфунгициднымкомопзициями ихприменениюдляборьбыс вредоноснымимикроорганизмамии, вособенностидлязащитысодержащихцеллюлозуматериалов, особеннодревесины, отпоражениямикроорганизмами, вчастности, такимипатогеннымигрибами, которыемогутразрушитьдревесину, соответственноцеллюлозу. Композициясодержит: а) поменьшеймереоднофунгицидноеорганическоедействующеевеществос водорастворимостьюнеболее, чем 5 г/лпри 25°С/1013 мбари b) тонкодисперсныйполимеризатсосреднейвеличинойчастиц, определеннойдинамическимсветорассеянием, неболее, чем 300 нм, гдеполимерныечастицысодержатдействующеевещество. Полимеризатобразованизэтиленненасыщенныхмономеров N, включающихот 70 до 99,5 вес.%, впересчетенаобщееколичествомономеров N, поменьшеймереодногонейтральногомоноэтиленненасыщенногомономера M1 сводорастворимостьюнеболее, чем 30 г/лпри 25°Си от 0,5 до 30 вес.%, впересчетенаобщееколичествомономеров N, одногоилинесколькихотличныхотмономеров M1, этиленненасыщенныхмономеровМ2. ЭтиленненасыщенныемономерыМ2 выбраныизгруппы, включающеймоноэтиленненасыщенныемономерыМ2а, которыеимеютпоменьшеймереоднукислотнуюгруппуилипоменьшеймереоднуанионнуюгруппу; моноэтиленненасыщенныенейтральныемономерыМ2b, которыеимеютводорастворимостьпоменьшеймере 50 г/лпри 25°С, имоноэтиленненасыщенныемономерыМ2с, которыеимеютпоменьшеймереоднукатионнуюгруппуи/илипоменьшеймереоднупротонируемуюв воднойсредегруппу.
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19.
公开(公告)号:AU2006222169A1
公开(公告)日:2006-09-14
申请号:AU2006222169
申请日:2006-03-08
Applicant: BASF AG
Inventor: HABICHT JOERG , SCHOPKE HOLGER , HAENTZSCHEL DIRK , AMRHEIN PATRICK , KLEIST GUNNAR
Abstract: The present invention relates to aqueous insecticidal preparations in the form of an aqueous dispersion of finely divided polymer particles which comprise at least one insecticidal organic active ingredient with a solubility in water of not more than 5 g/l at 25° C. at 1013 mbar and which have a mean particle size, determined by dynamic light scattering, of not more than 300 nm, where the polymer particles which comprise the at least one insecticidal active ingredient of a cationic surface charge and where the aqueous dispersion of the active-ingredient-comprising polymer particles is obtainable by subjecting a monomer composition of ethylenically unsaturated monomers M, in which the ethylenically unsaturated monomers M comprise the at least one insecticidal active ingredient in dissolved form, to radical aqueous emulsion polymerization. The invention also related to the use of such aqueous insecticide compositions for protecting lignocellulosic materials, in particular timber, against attack by harmful insects.
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公开(公告)号:CA2562347A1
公开(公告)日:2005-11-03
申请号:CA2562347
申请日:2005-04-25
Applicant: BASF AG
Inventor: AMRHEIN PATRICK , SCHOPKE HOLGER , HABICHT JOERG , KLEIST GUNNAR , GOETTSCHE REIMER
IPC: A01N25/04 , A01N43/36 , A01N43/653 , A01N47/12 , B27K3/15
Abstract: The invention relates to aqueous, fungicidal compositions and the use thereo f in combating harmful micro organisms and particularly for protecting cellulo se- containing materials, especially wood, from being attacked by micro organism s, particularly noxious fungi which can damage wood or cellulose. The inventive active substance compositions contain: a) at least one fungicidal organic active substance having a degree of solubility in water of no more than 5 g/ I at 25 ~C/1013 mbar and b) a fine-particled polymer having an average particl e size (determined by dynamic light scattering) of no more than 300 nm, wherei n the polymer particles contain the active substance, wherein the polymer is constructed from ethylenically unsaturated monomers M, comprising: - at leas t 60 wt.- %, in relation to the total amount of monomers M, of at least one neutral monoethylenically unsaturated monomer Ml having a degree of solubili ty in water of no more than 30 g/I at 25 ~C and up 40 wt.- %, in relation to th e total amount of monomers M, of one or several ethylenically unsaturated Monomers M2 different from monomers MI.
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