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公开(公告)号：DE59600231D1
公开(公告)日：1998-07-09
申请号：DE59600231
申请日：1996-02-06
Applicant: BASF AG
Inventor： SCHLARB BERNHARD DR , SCHUPP EBERHARD DR , RAU MARIA GYOPAR DR , SCHULTZ GUENTHER DR , WIESE HARM DR
IPC: C08F2/22 , C08F2/30 , C08F220/06 , C08F220/12 , C08F222/02 , C09D109/00 , C09D123/00 , C09D125/02 , C09D127/00 , C09D131/02 , C09D133/06 , C09D133/18 , C09D157/00 , C09J157/00 , D06M15/00
Abstract: Aq. polymer dispersions, obtd. by radical polymerisation of monomers in aq. emulsion in presence of a polymeric protective colloid (A) with an average mol. wt. (Mw) of >20,000. Colloid (A) is a copolymer of 5-50 wt. % unsatd. monomer(s) with acid or acid anhydride gp(s). (monomers I), 0.1-80 wt.% (meth)acrylate ester(s) of at least 10C aliphatic alcohols (monomers II), 0-94.9 wt.% "principal monomers", comprising 1-9C alkyl (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, unsatd. nitriles, vinyl halides and/or 2-8C aliphatic hydrocarbons with 1 or 2 double bonds (monomers III) and 0-60 wt.% other monomers (IV). Also claimed is the above process for the prodn. of aq. polymer dispersions.
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公开(公告)号：AT166885T
公开(公告)日：1998-06-15
申请号：AT96101647
申请日：1996-02-06
Applicant: BASF AG
Inventor： SCHLARB BERNHARD DR , SCHUPP EBERHARD DR , RAU MARIA GYOPAR DR , SCHULTZ GUENTHER DR , WIESE HARM DR
IPC: C08F2/22 , C08F2/30 , C08F220/06 , C08F220/12 , C08F222/02 , C09D109/00 , C09D123/00 , C09D125/02 , C09D127/00 , C09D131/02 , C09D133/06 , C09D133/18 , C09D157/00 , C09J157/00 , D06M15/00
Abstract: Aq. polymer dispersions, obtd. by radical polymerisation of monomers in aq. emulsion in presence of a polymeric protective colloid (A) with an average mol. wt. (Mw) of >20,000. Colloid (A) is a copolymer of 5-50 wt. % unsatd. monomer(s) with acid or acid anhydride gp(s). (monomers I), 0.1-80 wt.% (meth)acrylate ester(s) of at least 10C aliphatic alcohols (monomers II), 0-94.9 wt.% "principal monomers", comprising 1-9C alkyl (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, unsatd. nitriles, vinyl halides and/or 2-8C aliphatic hydrocarbons with 1 or 2 double bonds (monomers III) and 0-60 wt.% other monomers (IV). Also claimed is the above process for the prodn. of aq. polymer dispersions.
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公开(公告)号：DE19810053A1
公开(公告)日：1999-04-29
申请号：DE19810053
申请日：1998-03-09
Applicant: BASF AG
Inventor： SCHWARTZ MANFRED DR , BECHERT BERTOLD , WIESE HARM DR , HUEMMER WOLFGANG DR
Abstract: A process for the neutralisation or slight basification of aqueous dispersions of film forming copolymers containing carboxylic groups with an alkali metal hydroxide is claimed. The aqueous copolymer dispersion is strongly mixed with a dilute, aqueous alkali metal hydroxide solution under static pH control such that during the addition the pH does not exceed 7.9 and the final pH is 7.0-7.9. An Independent claim is included for a coating composition for mineral based molded articles prepared using the neutralized polymer dispersion.
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Patent Agency Ranking
公开(公告)号：CZ44696A3
公开(公告)日：1996-09-11
申请号：CZ44696
申请日：1996-02-15
Applicant: BASF AG
Inventor： SCHLARB BERNHARD DR , SCHUPP EBERHARD DR , RAU MARIA GYOPAR DR , SCHULZ GUNTHER DR , WIESE HARM DR
IPC: C08F2/22 , C08F2/30 , C08F220/06 , C08F220/12 , C08F222/02 , C09D109/00 , C09D123/00 , C09D125/02 , C09D127/00 , C09D131/02 , C09D133/06 , C09D133/18 , C09D157/00 , C09J157/00 , D06M15/00
Abstract: Aq. polymer dispersions, obtd. by radical polymerisation of monomers in aq. emulsion in presence of a polymeric protective colloid (A) with an average mol. wt. (Mw) of >20,000. Colloid (A) is a copolymer of 5-50 wt. % unsatd. monomer(s) with acid or acid anhydride gp(s). (monomers I), 0.1-80 wt.% (meth)acrylate ester(s) of at least 10C aliphatic alcohols (monomers II), 0-94.9 wt.% "principal monomers", comprising 1-9C alkyl (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, unsatd. nitriles, vinyl halides and/or 2-8C aliphatic hydrocarbons with 1 or 2 double bonds (monomers III) and 0-60 wt.% other monomers (IV). Also claimed is the above process for the prodn. of aq. polymer dispersions.
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公开(公告)号：DE4429239A1
公开(公告)日：1996-02-22
申请号：DE4429239
申请日：1994-08-18
Applicant: BASF AG
Inventor： FRIEDRICH THOMAS DR , HORN DIETER DR , KLINGLER JUERGEN DR , WIESE HARM DR
Abstract: The spectroscopy method involves feeding light from a stimulation light source (1) via a first optical fibre (2) to a fibre coupler (3) and from there via a second optical fibre (4) to a specimen (6). Fluorescent light emitted from particles in the specimen are fed via the second optical fibre back to the coupler and from there via a third optical fibre (8) to a detector (10). Alternatively, the light from the source can be fed to the specimen via a first optical fibre and fluorescent light from particles in the specimen passed via a second fibre to a detector, whereby the ends of the fibres facing the specimen are oriented w.r.t. each other so that emitted stimulation light passes to a specimen region from which fluorescent light will be detected.
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公开(公告)号：DE59906330D1
公开(公告)日：2003-08-28
申请号：DE59906330
申请日：1999-05-21
Applicant: BASF AG
Inventor： SCHLARB BERNHARD DR , WIESE HARM DR , WILDBURG GERALD DR , RAU MARIA GYOPAR DR
IPC: C08L25/04 , C08F2/22 , C08F2/24 , C08F2/44 , C08F220/18 , C08F230/02 , C08L31/02 , C08L33/08 , C09D5/08 , C09D157/00
Abstract: Protective colloid includes 2-40 wt.% ethylenically unsaturated monomer with at least one phosphate or phosphonate group. Aqueous polymer dispersion is prepared by emulsion polymerisation of (A) comprising 50-100 wt.% 1-18 C alkyl (meth)acrylate, vinyl ester and/or vinyl aromatic monomers in the presence of a protective colloid (B) comprising: (1) 2-40 wt.% ethylenically unsaturated monomer with at least one phosphate or phosphonate group; (2) 0-98 wt.% 1-18 C alkyl (meth)acrylate, vinyl ester or vinyl aromatic monomers; and (3) 0-50 wt.% other monomers.
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公开(公告)号：DE19727060A1
公开(公告)日：1999-01-07
申请号：DE19727060
申请日：1997-06-25
Applicant: BASF AG
Inventor： GERST MATTHIAS DR , SCHULER BERNHARD DR , DAMES BURKHARDT DR , URBAN DIETER DR , WIESE HARM DR , MORRISON BRADLEY RONALD DR
IPC: C08F2/22 , C08F4/40 , C08F110/06 , C08F257/02 , C08F291/00 , C09K3/10 , C09D157/00 , D06M15/21 , C08J3/03 , C09J9/00 , C14C9/00
Abstract: Preparation of aqueous polymer dispersions of wt. average particle diameter above 400 nm comprises radically polymerising ethylenically unsaturated monomers in the presence of a surface active agent (emulsifier) and 0.001-1 wt.% seed polymer of monomodal particle size where, when 1% monomer conversion has been achieved, a redox initiator system is added, comprising an organic or inorganic (hydro)peroxide(s) and ascorbic acid, and polymerisation is undertaken in the presence of this system or another initiator system. Also claimed are the obtained aqueous dispersions comprising at least 60 wt.% polymer particles of dmax above 800 nm and half width h1/2 below 1/2 dmax, with the remainder being of diameter d below dmax.
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公开(公告)号：DE19505039A1
公开(公告)日：1996-08-22
申请号：DE19505039
申请日：1995-02-15
Applicant: BASF AG
Inventor： SCHLARB BERNHARD DR , SCHUPP EBERHARD DR , RAU MARIA GYOPAR DR , SCHULZ GUENTHER DR , WIESE HARM DR
IPC: C08F2/22 , C08F2/30 , C08F220/06 , C08F220/12 , C08F222/02 , C09D109/00 , C09D123/00 , C09D125/02 , C09D127/00 , C09D131/02 , C09D133/06 , C09D133/18 , C09D157/00 , C09J157/00 , D06M15/00 , C09D127/02 , C09D123/02 , D06M15/263 , D06M15/327 , D06M15/227
Abstract: Aq. polymer dispersions, obtd. by radical polymerisation of monomers in aq. emulsion in presence of a polymeric protective colloid (A) with an average mol. wt. (Mw) of >20,000. Colloid (A) is a copolymer of 5-50 wt. % unsatd. monomer(s) with acid or acid anhydride gp(s). (monomers I), 0.1-80 wt.% (meth)acrylate ester(s) of at least 10C aliphatic alcohols (monomers II), 0-94.9 wt.% "principal monomers", comprising 1-9C alkyl (meth)acrylates, vinyl esters of 1-20C carboxylic acids, up to 20C vinylaromatics, unsatd. nitriles, vinyl halides and/or 2-8C aliphatic hydrocarbons with 1 or 2 double bonds (monomers III) and 0-60 wt.% other monomers (IV). Also claimed is the above process for the prodn. of aq. polymer dispersions.
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