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公开(公告)号:ES2066295T3
公开(公告)日:1995-03-01
申请号:ES91113983
申请日:1991-08-21
Applicant: BASF AG
Inventor: KSOLL PETER DR , REUTHER WOLFGANG DR , HOHMANN ANDREAS DR , WITTMER PETER
Abstract: Process for the preparation of carboxylic acid chlorides of the general formula I in which R represents C1- to C30-alkyl, C2- to C30-alkenyl and C2- to C30-alkynyl, from essentially equimolar amounts of a carboxylic acid of the general formula II in which R has the abovementioned meanings, and phosgene COCl2 (III), in the presence of a catalyst adduct of phosgene and N,N-disubstituted formamide or their hydrochlorides of the general formula IV in which R and R independently of one another denote C1- to C3-alkyl or R and R together denote a C4- or C5-alkylene chain which can optionally be interrupted by an oxygen atom or a nitrogen atom having a C1- to C3-alkyl group or CHO, and n is 0, 1 or 2, the reaction being carried out with a static phase of the catalyst adduct.
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公开(公告)号:DK0437764T3
公开(公告)日:1993-08-30
申请号:DK90124486
申请日:1990-12-18
Applicant: BASF AG
Inventor: HOHMANN ANDREAS DR , KSOLL PETER DR , HAHN ERWIN DR , WITTMER PETER , DE CLERQ ARNOLD DR , RIEBELING ULRICH
IPC: B01J13/00 , C07C45/90 , C07C49/88 , C09K23/00 , C07D305/12 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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公开(公告)号:AU6940491A
公开(公告)日:1991-07-25
申请号:AU6940491
申请日:1991-01-17
Applicant: BASF AG
Inventor: KSOLL PETER , HAHN ERWIN , WITTMER PETER , HOHMANN ANDREAS , CLERCQ ARNOLD DE , RIEBELING ULRICH
IPC: C09K23/00 , B01J13/00 , C07C45/90 , C07C49/88 , C07D305/12 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14 , B01F17/00
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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公开(公告)号:NO910199L
公开(公告)日:1991-07-19
申请号:NO910199
申请日:1991-01-17
Applicant: BASF AG
Inventor: KSOLL PETER , HAHN ERWIN , WITTMER PETER , HOHMANN ANDREAS , CLERCQ ARNOLD DE , RIEBELING ULRICH
IPC: B01J13/00 , C07C45/90 , C07C49/88 , C07D305/12 , C07D315/00 , D21H17/06 , C09K23/00 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14 , D21H21/16 , C09K15/06 , C09K15/22
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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公开(公告)号:CA2034355A1
公开(公告)日:1991-07-19
申请号:CA2034355
申请日:1991-01-17
Applicant: KSOLL PETER , HAHN ERWIN , WITTMER PETER , HOHMANN ANDREAS , CLERCQ ARNOLD DE , RIEBELING ULRICH , BASF AG
Inventor: KSOLL PETER , HAHN ERWIN , WITTMER PETER , HOHMANN ANDREAS , DE CLERCQ ARNOLD , RIEBELING ULRICH
IPC: C09K23/00 , B01J13/00 , C07C45/90 , C07C49/88 , C07D305/12 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14 , C11D1/72
Abstract: BASF Aktiengesellschaft Stabilized aqueous alkyldiketene emulsions of the disclosure: Stabilized aqueous Cl4-C22-alkyldiketene emulsions containing, as essential components: (a) from 10 to 60 % w/w of at least one C14-C22-alkyldiketene, (b) from 1 to 10 % w/w of at least one protective colloid and (c) from 0.1 to 20 % w/w of at least one ester of formula I (I) in which R1 and R2 each denote Cl4-C22-alkyl, R1 differing in this case from R2 by at least 4 carbon atoms in the alkyl chain, and/or the same or different C14-C22-alkenyl groups, or at least one ester of the formula R3-O-CO-O-R4 (II),in which R3 and R4 are alkyl or alkenyl radicals of from 2 to 22 carbon atoms or at least one urethane of formula III (III), in which R5, R5 and R7 are the same or different alkyl or alkenyl radicals of from 2 to 22 carbon atoms and one of the substituents R5, R6 and R7 contains at least 12 carbon atoms, and showing a ratio of emulsified components (a):(c) from 200:1 to 1:1 and the use of compounds of formulae I to III as stabilizers for the preparation of alkyldiketene emulsions containing at least 10% w/w and preferably from 16 to 40% w/w of emulsified alkyldiketene.
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公开(公告)号:FI882785A
公开(公告)日:1988-12-13
申请号:FI882785
申请日:1988-06-10
Applicant: BASF AG
Inventor: FREUDENBERG ENRIQUE , WITTMER PETER , HOHMANN ANDREAS , BECHTOLSHEIMER HANS-HEINRICH
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公开(公告)号:DE59104041D1
公开(公告)日:1995-02-09
申请号:DE59104041
申请日:1991-08-21
Applicant: BASF AG
Inventor: KSOLL PETER DR , REUTHER WOLFGANG DR , HOHMANN ANDREAS DR , WITTMER PETER
Abstract: Process for the preparation of carboxylic acid chlorides of the general formula I in which R represents C1- to C30-alkyl, C2- to C30-alkenyl and C2- to C30-alkynyl, from essentially equimolar amounts of a carboxylic acid of the general formula II in which R has the abovementioned meanings, and phosgene COCl2 (III), in the presence of a catalyst adduct of phosgene and N,N-disubstituted formamide or their hydrochlorides of the general formula IV in which R and R independently of one another denote C1- to C3-alkyl or R and R together denote a C4- or C5-alkylene chain which can optionally be interrupted by an oxygen atom or a nitrogen atom having a C1- to C3-alkyl group or CHO, and n is 0, 1 or 2, the reaction being carried out with a static phase of the catalyst adduct.
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公开(公告)号:FI90527C
公开(公告)日:1994-02-25
申请号:FI882785
申请日:1988-06-10
Applicant: BASF AG
Inventor: FREUDENBERG ENRIQUE , WITTMER PETER , HOHMANN ANDREAS , BECHTOLSHEIMER HANS-HEINRICH
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公开(公告)号:NO173863B
公开(公告)日:1993-11-08
申请号:NO910199
申请日:1991-01-17
Applicant: BASF AG
Inventor: KSOLL PETER , HAHN ERWIN , WITTMER PETER , HOHMANN ANDREAS , CLERCQ ARNOLD DE , RIEBELING ULRICH
IPC: B01J13/00 , C07C45/90 , C07C49/88 , C07D305/12 , C09K23/00 , C07D315/00 , D21H17/06 , D21H17/07 , D21H17/17 , D21H17/46 , D21H21/14 , D21H21/16
Abstract: Stabilised aqueous C14- to C22-alkyldiketene emulsions containing, as essential components, (a) 10 to 60 % by weight of at least one C14- to C22-alkyldiketene, (b) 1 to 10 % by weight of at least one protective colloid and (c) 0.1 to 20 % by weight of at least one ester of the formula in which R , R are C14- to C22-alkyl, in which case R and R must differ in the alkyl group by at least 4 C atoms, and/or denote identical or different C14- to C22-alkenyl groups, an ester of the formula R -O-CO-O-R (II), in which R and R are alkyl or alkenyl radicals having 2 to 22 C atoms or a urethane of the formula in which R , R and R are identical or different alkyl or alkenyl radicals having 2 to 22 C atoms, and the use of the compounds of the formula I to III as stabiliser for the preparation of alkyldiketene emulsions containing at least 10, preferably 16 to 40 % by weight of alkyldiketene in emulsified form.
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公开(公告)号:BR8802859A
公开(公告)日:1989-01-03
申请号:BR8802859
申请日:1988-06-10
Applicant: BASF AG
Inventor: FREUDENBERG ENRIQUE , WITTMER PETER , HOHMANN ANDREAS , BECHTOLSHEIMER HANS-HEINRICH
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