公开(公告)号：DE502005000420D1

公开(公告)日：2007-04-12

申请号：DE502005000420

申请日：2005-08-17

Applicant: DEGUSSA

Inventor： KORTH KARSTEN DR ,  ALBERT PHILIPP DR ,  WOLF DORIT DR ,  SEEBALD STEFFEN DR ,  PIETER REIMUND DR ,  ALIG ALFRED

IPC: C07F7/18

Abstract: Preparation of mercaptoorganyl(alkoxysilanes) involves hydrogenation of bis(alkoxysilylorganyl)polysulfides with hydrogen and a transition metal catalyst in a solvent without the addition of alcohols, hydrogen sulfide or water.

公开(公告)号：BR9902644A

公开(公告)日：2000-05-16

申请号：BR9902644

申请日：1999-06-09

Applicant: DEGUSSA

Inventor： BATZ-SHON CHRISTOPH ,  KARCH RALF DR ,  SEEBALD STEFFEN DR ,  PRINZ MATTHIAS

IPC: B01J31/22 ,  C07B61/00 ,  C07F7/08 ,  C07F7/12 ,  C07F7/14 ,  C07F7/18

Abstract: Preparation of 3-functionalized propylsilanes (I) comprises addition of allyl compounds (II) to silanes (III) at 0-200 degrees C and 800 mbar to 6 bar in the presence of a platinum catalyst that has ligand(s) containing sulfur. Preparation of 3-functionalized propylsilanes (I) comprises addition of allyl compounds of formula (II) to silanes of formula (III) at 0-200 degrees C and 800 mbar to 6 bar in the presence of a platinum (Pt) catalyst (IV) that has ligand(s) containing sulfur: X = chlorine (Cl), bromine (Br), iodine (I), fluorine (F), cyano (CN), thiocyanato (SCN), mercapto (SH), organylthio (SR), hydroxyl (OH), amino (NRR ) or organyloxy (OR); R, R = 1-6 carbon (C) alkyl or 3-7 C aryl; R , R , R = hydrogen (H), halogen, 1- C (halo)alkyl, 3-6 C allyl, 1-4 C alkoxy, phenyl, aryl or aralkyl. An Independent claim is also included for the use of (IV) in this addition reaction.