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公开(公告)号:NO892472A
公开(公告)日:1989-05-26
申请号:NO892472
申请日:1989-06-14
Applicant: HOECHST AG
Inventor: MEIJERE ARMIN DE , DUEBAL HANS-ROLF , ESCHER CLAUS , HEMMERLING WOLFGANG , MUELLER INGRID , OHLENDORF DIETER , WINGEN RAINER
IPC: C07D20060101 , C07D239/26 , C07D239/34 , C07D239/38
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公开(公告)号:NO885236D0
公开(公告)日:1988-11-24
申请号:NO885236
申请日:1988-11-24
Applicant: HOECHST AG
Inventor: MEIJERE ARMIN DE , DUEBAL HANS-ROLF , ESCHER CLAUS , HEMMERLING WOLFGANGA , MUELLER INGRID , OHLENDORF DIETER , WINGEN RAINER
IPC: C07D20060101 , C07D213/30 , C07D237/08 , C07D237/10 , C07D237/14 , C07D239/26 , C07D239/32 , C07D239/34 , C07D239/38 , C07D241/12 , C07D285/12 , C07D303/48 , C07D317/10 , C07D405/12 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/13 , G02F1/137 , G02F1/141 , C07D239/00
Abstract: The liquid crystalline cyclopropylalkyl or -alkenyl heterocycles have the formula in which the symbols A , A , A are aromatic or heteroaromatic molecular building blocks, such as 1,4-phenylene or pyrimidin-2,5-diyl which are linked via a single bond (if k,m are zero) or via functional groups M , M , such as CO-O or CH2-O; j, k, l, m, n are zero or 1 (j+l+n = 2 or 3). The radicals R , R , R are H or alkyl/alkenyl, R is alkyl/alkenyl or one of the substituents known from LC chemistry, such as an alpha -haloalkanoic radical. In addition, at least one of the building blocks A , A , A must be heteroaromatic and G denotes alkylene or alkenylene.
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公开(公告)号:NO881471D0
公开(公告)日:1988-04-06
申请号:NO881471
申请日:1988-04-06
Applicant: HOECHST AG
Inventor: BAHR CHRISTIAN , HEPPKE GERD , LOETZSCH DETLEF , DUEBAL HANS-ROLF , GUENTHER DIETER , HEMMERLING WOLFGANG , MUELLER INGRID , WINGEN RAINER
Abstract: Compounds which contain a polar chiral grouping (moiety) of the formula are suitable for use as a liquid-crystalline medium or as a chiral constituent of liquid-crystalline media in electro-optical switching and display elements which are based on the utilisation of the electroclinic effect and where the liquid-crystalline medium, when in the operating state, is present in the @A, @B or @E phase. These compounds are derivatives of alpha -chlorocarboxylic acids (I), alpha -hydroxypropionic acid (II), proline (III), epoxy compounds (IV) or their thioanalogues (V).
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公开(公告)号:NO881281D0
公开(公告)日:1988-03-23
申请号:NO881281
申请日:1988-03-23
Applicant: HOECHST AG
Inventor: DUEBAL HANS-ROLF , ESCHER CLAUS , HEMMERLING WOLFGANG , MUELLER INGRID , OHLENDORF DIETER , WINGEN RAINER
Abstract: The compounds of the general formula (I) (I) are particularly highly suitable as components of smectic, liquid-crystal mixtures, the symbols having the following meaning: R1 and R2 denote identical or different, straight-chain or branched alkyl or alkenyl groups which can contain asymmetric carbon atoms, containing 2 to 16 carbon atoms, in which one or more non-adjacent -CH2- groups can be replaced by -O- and/or -S-, -A and -B each denote group in which the radicals R1, R2, in each case, are situated at the phenylene part of -A, -B and m and n denote 0 or 1, but m+n is always zero or 1.
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公开(公告)号:DE59006153D1
公开(公告)日:1994-07-21
申请号:DE59006153
申请日:1990-03-21
Applicant: HOECHST AG
Inventor: DUEBAL HANS-ROLF , ESCHER CLAUS , HARADA TAKAMASA , HEMMERLING WOLFGANG , ILLIAN GERHARD , MUELLER INGRID , MURAKAMI MIKIO , OHLENDORF DIETER , WINGEN RAINER
Abstract: PCT No. PCT/EP90/00458 Sec. 371 Date Nov. 6, 1991 Sec. 102(e) Date Nov. 6, 1991 PCT Filed Mar. 21, 1990 PCT Pub. No. WO90/11336 PCT Pub. Date Oct. 4, 1990.The novel liquid-crystalline mixtures (in the case of ferroelectric behavior they additionally contain an optically active compound as dope) are based on at least two mixture components of the general formula (I) and at least one carboxylate of the general formula (II), (III) or (IV). (* CHEMICAL STRUCTURE *) (I) (* CHEMICAL STRUCTURE *) (II) X = O or a single bond (* CHEMICAL STRUCTURE *) (III) (* CHEMICAL STRUCTURE *) (IV) The mixtures have favorable properties for use in electrooptical display elements, such as high contrast, low melting point and short switching times.
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公开(公告)号:NO913774A
公开(公告)日:1992-03-30
申请号:NO913774
申请日:1991-09-26
Applicant: HOECHST AG
Inventor: ILLIAN GERD , WINGEN RAINER , MUELLER INGRID
IPC: C07D239/26 , C07D239/34 , C07F7/10 , C09K19/34 , C09K19/40 , C09K19/42 , G02F1/13
CPC classification number: C09K19/406 , C07D239/34 , C09K19/3458 , C09K19/3466 , C09K19/3469
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公开(公告)号:NO169226B
公开(公告)日:1992-02-17
申请号:NO883048
申请日:1988-07-07
Applicant: HOECHST AG
Inventor: WINGEN RAINER , DUEBAL HANS-ROLF , HEMMERLING WOLFGANG , MUELLER INGRID , OHLENDORF DIETER
IPC: C04B35/64 , B22F3/14 , B22F3/15 , B23B27/14 , C04B35/10 , C04B35/56 , C04B35/58 , C04B35/645 , C04B35/80 , C04B35/81 , C04B41/50 , C04B41/52 , C04B41/87 , C04B41/89 , C07C20060101 , C07C69/712 , C07C69/773 , C07C69/92 , C07D239/26 , C07D239/34 , C07D405/12 , C09K19/20 , C09K19/54 , C09K19/58 , G02F1/13
Abstract: PCT No. PCT/EP87/00653 Sec. 371 Date May 5, 1989 Sec. 102(e) Date May 5, 1989 PCT Filed Nov. 2, 1987 PCT Pub. No. WO88/03525 PCT Pub. Date May 19, 1988.Arylcarboxylates of 2-hydroxypropionates are known, amongst other compounds, as dopes for converting tilted smectic liquid-crystal phases into ferroelectric liquid-crystal phases. The novel chiral aryloxypropionates of the general formula are two-fold chiral and in which the symbols have the following meaning: R1 denotes a straight-chain alkyl or alkoxy radical having 1 to 16 carbon atoms or a branched alkyl or alkoxy radical having 4 to 16 carbon atoms, it being possible for one or two non-adjacent CH2 groups to be replaced by a sulfur and/or oxygen atom; A denotes one, two or three aromatic or heteroaromatic rings which are linked to one another directly or via one or two COO groups; B denotes a chemical bond or one or two aromatic or heteroaromatic rings which are linked directly to one another; R2 (a) if B is a chemical bond, denotes an alkyl radical having 2 to 10 carbon atoms which contains an asymmetrical carbon atom which is substituted by CH3, halogen or a COOC2H5 group, or an alkyl radical having 3 to 10 carbon atoms which contains two adjacent, asymmetrical carbon atoms of which one is substituted by halogen and the other by a CH3 group, or which, together with an O, form an oxirane ring, or (b) if B denotes one or two aromatic or heteroaromatic rings which are bonded directly to one another, denotes alkoxy radicals having the same number of carbon atoms and the same structure of the alkyl group as under (a).
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18.
公开(公告)号:CA2087093A1
公开(公告)日:1992-01-13
申请号:CA2087093
申请日:1991-06-27
Applicant: HOECHST AG
Inventor: TETZLAFF HERIBERT , MUELLER INGRID , RITTNER SIEGBERT , WINGEN RAINER
IPC: C07D239/36 , C07D239/38 , C09K19/34
Abstract: (57) Disclosed is a method for the separation by multi-stage extraction of 2-alkylthio-5-phenylpyrimidines of general formula (I) in which R1 is H or an alkyl group with 1 to 15 C-atoms, X is an oxygen atom or a single bond and R2 is an alkyl with 1 to 15 C-atoms, using two organic solvents which give two immiscible phases. The method has the advantage that the phenyl pyrimidines are obtained from the reaction mixture at a high level of purity even on a commercial scale.
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公开(公告)号:NO913675A
公开(公告)日:1991-11-15
申请号:NO913675
申请日:1991-09-18
Applicant: HOECHST AG
Inventor: DUEBAL HANS-ROLF , ESCHER CLAUS , HARADA TAKAMASA , HEMMERLING WOLFGANG , ILLIAN GERHARD , MUELLER INGRID , MURAKAMI MIKIO , OHLENDORF DIETER , WINGEN RAINER
IPC: C09K20060101 , C09K19/34 , C09K19/46 , C09K19/58
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公开(公告)号:NO913697A
公开(公告)日:1991-09-19
申请号:NO913697
申请日:1991-09-19
Applicant: HOECHST AG
Inventor: DUEBAL HANS-ROLF , ESCHER CLAUS , HARADA TAKAMASA , HEMMERLING WOLFGANG , ILLIAN GERHARD , MUELLER INGRID , MURAKAMI MIKIO , OHLENDORF DIETER , WINGEN RAINER
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