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公开(公告)号:DE3711362A1
公开(公告)日:1988-10-27
申请号:DE3711362
申请日:1987-04-07
Applicant: HOECHST AG
Inventor: BAHR CHRISTIAN , HEPPKE GERD PROF DR , LOETZSCH DETLEF , DUEBAL HANS-ROLF DR , GUENTHER DIETER DR , HEMMERLING WOLFGANG DR , MUELLER INGRID DR , WINGEN RAINER DR
Abstract: Compounds which contain a polar chiral grouping (moiety) of the formula are suitable for use as a liquid-crystalline medium or as a chiral constituent of liquid-crystalline media in electro-optical switching and display elements which are based on the utilisation of the electroclinic effect and where the liquid-crystalline medium, when in the operating state, is present in the @A, @B or @E phase. These compounds are derivatives of alpha -chlorocarboxylic acids (I), alpha -hydroxypropionic acid (II), proline (III), epoxy compounds (IV) or their thioanalogues (V).
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公开(公告)号:DE3617826A1
公开(公告)日:1987-04-02
申请号:DE3617826
申请日:1986-05-27
Applicant: HOECHST AG
Inventor: HEPPKE GERD PROF DR , LOETZSCH DETLEF , OESTREICHER FEODOR DR
Abstract: The new esters of a chiral alcohol with a mesogenic carboxylic acid are characterised by the general formula (I) in which the symbols have the following meaning: R is unsubstituted or substituted (C6-C18)aryl, cyclo(C5-C12)alkyl or a mono- or dinuclear five- or six-membered heteroaryl ring, R radicals independently of one another are R or H or (C1-C5)alkyl, it being possible for one CH2 group to be replaced by O, and MC is the radical of a mesogenic monocarboxylic acid molecule after elimination of an OH group, with the exception of compounds in which R is phenyl and R is H. These esters are preferably employed as doping substances in twistable liquid-crystalline phases, in which they cause temperature compensation and a high degree of twisting.
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公开(公告)号:DE3667274D1
公开(公告)日:1990-01-11
申请号:DE3667274
申请日:1986-09-18
Applicant: HOECHST AG
Inventor: BAHR CHRISTIAN , HEPPKE GERD PROF DR , LOETZSCH DETLEF , OESTREICHER FEODOR DR
IPC: C07C69/76 , C07C67/00 , C07C69/767 , C07C69/773 , C07C69/92 , C07C241/00 , C07C245/06 , C07C251/18 , C07C251/24 , C07C253/00 , C07C255/55 , C07C255/57 , C07C291/08 , C09K19/08 , C09K19/58 , G02F1/13
Abstract: 1. An ester of a chiral alcohol and a mesogenic carboxylic acid, which is of the general formula (I) see diagramm : EP0217240,P6,F2 in which the symbols have the following meanings : n denotes 0 or 1, R**1 denotes a straight-chain or branched (C1 -C4 )alkyl which is substituted by halogen, in particular fluorine, R**2 denotes unsubstituted or substituted (C6 -C18 ) aryl, cyclo (C5 -C12 )alkyl or mononuclear or binuclear heteroaryl possessing a five-membered and/or sixmembered ring, and MC denotes R**3 -(A**1 -)n1 (B-)n2 (A**2 -)n3 CO where n = 0 or denotes OC-(A**1 -)n1 (B-)n2 (A**2 -)n3 CO where n = 1, R**3 denotes a straight-chain (C4 -C10 )alkyl in which a CH2 group can be replaced by an 0 atom, A**1 , A**2 independently of one another denote unsubstituted 1,4-phenylene or 1-4-cyclohexylene, B denotes CO-0 or 0-CO, n1 denotes 1 n2 denotes 0 or 1 and n3 denotes 1 or 2.
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公开(公告)号:NO881471D0
公开(公告)日:1988-04-06
申请号:NO881471
申请日:1988-04-06
Applicant: HOECHST AG
Inventor: BAHR CHRISTIAN , HEPPKE GERD , LOETZSCH DETLEF , DUEBAL HANS-ROLF , GUENTHER DIETER , HEMMERLING WOLFGANG , MUELLER INGRID , WINGEN RAINER
Abstract: Compounds which contain a polar chiral grouping (moiety) of the formula are suitable for use as a liquid-crystalline medium or as a chiral constituent of liquid-crystalline media in electro-optical switching and display elements which are based on the utilisation of the electroclinic effect and where the liquid-crystalline medium, when in the operating state, is present in the @A, @B or @E phase. These compounds are derivatives of alpha -chlorocarboxylic acids (I), alpha -hydroxypropionic acid (II), proline (III), epoxy compounds (IV) or their thioanalogues (V).
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公开(公告)号:DE3534778A1
公开(公告)日:1987-04-02
申请号:DE3534778
申请日:1985-09-30
Applicant: HOECHST AG
IPC: C07C69/76 , C07C67/00 , C07C69/767 , C07C69/773 , C07C69/92 , C07C241/00 , C07C245/06 , C07C251/18 , C07C251/24 , C07C253/00 , C07C255/55 , C07C255/57 , C07C291/08 , C09K19/08 , C09K19/58 , G02F1/13 , G09F9/35
Abstract: 1. An ester of a chiral alcohol and a mesogenic carboxylic acid, which is of the general formula (I) see diagramm : EP0217240,P6,F2 in which the symbols have the following meanings : n denotes 0 or 1, R**1 denotes a straight-chain or branched (C1 -C4 )alkyl which is substituted by halogen, in particular fluorine, R**2 denotes unsubstituted or substituted (C6 -C18 ) aryl, cyclo (C5 -C12 )alkyl or mononuclear or binuclear heteroaryl possessing a five-membered and/or sixmembered ring, and MC denotes R**3 -(A**1 -)n1 (B-)n2 (A**2 -)n3 CO where n = 0 or denotes OC-(A**1 -)n1 (B-)n2 (A**2 -)n3 CO where n = 1, R**3 denotes a straight-chain (C4 -C10 )alkyl in which a CH2 group can be replaced by an 0 atom, A**1 , A**2 independently of one another denote unsubstituted 1,4-phenylene or 1-4-cyclohexylene, B denotes CO-0 or 0-CO, n1 denotes 1 n2 denotes 0 or 1 and n3 denotes 1 or 2.
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公开(公告)号:DE3886087D1
公开(公告)日:1994-01-20
申请号:DE3886087
申请日:1988-04-02
Applicant: HOECHST AG
Inventor: BAHR CHRISTIAN , HEPPKE GERD PROF DR , LOETZSCH DETLEF , DUEBAL HANS-ROLF DR , ESCHER CLAUS DR , OHLENDORF DIETER DR
IPC: C09K19/02 , C07D303/48 , C07D405/12 , C09K19/58 , G02F1/137 , G02F1/139 , G02F1/141 , G02F1/361 , G02F1/37
Abstract: Compounds which have a chiral, orthogonal, higher-order smectic phase, in particular a S B or a S E phase can be used in the region of this phase or phases as a display or switching medium in electro- optical display elements or switching elements which are based on the utilisation of the electrokinetic effect.
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公开(公告)号:NO881471L
公开(公告)日:1988-10-10
申请号:NO881471
申请日:1988-04-06
Applicant: HOECHST AG
Inventor: BAHR CHRISTIAN , HEPPKE GERD , LOETZSCH DETLEF , DUEBAL HANS-ROLF , GUENTHER DIETER , HEMMERLING WOLFGANG , MUELLER INGRID , WINGEN RAINER
Abstract: Compounds which contain a polar chiral grouping (moiety) of the formula are suitable for use as a liquid-crystalline medium or as a chiral constituent of liquid-crystalline media in electro-optical switching and display elements which are based on the utilisation of the electroclinic effect and where the liquid-crystalline medium, when in the operating state, is present in the @A, @B or @E phase. These compounds are derivatives of alpha -chlorocarboxylic acids (I), alpha -hydroxypropionic acid (II), proline (III), epoxy compounds (IV) or their thioanalogues (V).
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公开(公告)号:NO881471A
公开(公告)日:1988-10-10
申请号:NO881471
申请日:1988-04-06
Applicant: HOECHST AG
Inventor: BAHR CHRISTIAN , HEPPKE GERD , LOETZSCH DETLEF , DUEBAL HANS-ROLF , GUENTHER DIETER , HEMMERLING WOLFGANG , MUELLER INGRID , WINGEN RAINER
CPC classification number: C09K19/126 , C09K19/2021 , C09K19/3405 , C09K19/3411 , C09K19/3483 , C09K19/3491 , C09K19/3497 , C09K2019/3422
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公开(公告)号:AT91032T
公开(公告)日:1993-07-15
申请号:AT88105354
申请日:1988-04-02
Applicant: HOECHST AG
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公开(公告)号:NO881472L
公开(公告)日:1988-10-10
申请号:NO881472
申请日:1988-04-06
Applicant: HOECHST AG
Inventor: BAHR CHRISTIAN , HEPPKE GERD , LOETZSCH DETLEF , DUEBAL HANS-ROLF , ESCHER CLAUS , OHLENDORF DIETER
IPC: C09K19/02 , C07D303/48 , C07D405/12 , C09K19/58 , G02F1/137 , G02F1/139 , G02F1/141 , G02F1/361 , G02F1/37 , C09K19/06 , G09F9/35
Abstract: Compounds which have a chiral, orthogonal, higher-order smectic phase, in particular a S B or a S E phase can be used in the region of this phase or phases as a display or switching medium in electro- optical display elements or switching elements which are based on the utilisation of the electrokinetic effect.
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