公开(公告)号：JP2000150785A

公开(公告)日：2000-05-30

申请号：JP31468798

申请日：1998-11-05

Applicant: IBM

Inventor： KENNETH RAYMOND CARTER ,  ROBERT FRANCIS COOK ,  MARTHA ERIN HERBISON ,  CRAIG JOHN HAWKER ,  JAMES LUPTON HEDRICK ,  LEE VICTOR YEE-WAY ,  ERIK GERHARD RINIGER ,  ROBERT DENNIS MILLER ,  BILLY VOLKSEN ,  DOU IEN YOON

IPC: H01L27/04 ,  C09K3/16 ,  H01L21/31 ,  H01L21/312 ,  H01L21/822

Abstract: PROBLEM TO BE SOLVED: To improve mechanical toughness and polishing characteristics by allowing a dielectric composition for creating an integrated circuit to contain a methylsilsesquioxan and a photosensitive base or a heat-sensitive base product. SOLUTION: In a multilayer integrated circuit device, the lower layer of insulated flattening metal circuit lines 4 is allowed to function as a substrate 2, a perpendicular metal stud 8 is formed in the substrate 2, and at the same time a dielectric material 6 is buried between the flattening metal circuit lines 4 for formation. The dielectric material 6 contains tetraalkoxysilane and tetraethoxy silane, alkyl/trialkoxy, or trihalo silicate, or dialkyl/dialkoxy, or alkyl (methyl) phenylsilsesquioxan that is mixed with dihalo silicate, and a photosensitive base or a heat-sensitive base product.

公开(公告)号：JPH10135332A

公开(公告)日：1998-05-22

申请号：JP28044397

申请日：1997-10-14

Applicant: IBM

Inventor： CRAIG JOHN HAWKER ,  JAMES LUPTON HEDRICK ,  ROBERT DENNIS MILLER

IPC: H01L21/3205 ,  H01L21/312 ,  H01L21/768 ,  H01L23/522 ,  H01L23/532

Abstract: PROBLEM TO BE SOLVED: To make the arranging interval of metallic circuit wiring narrower without increasing cross talk nor capacity coupling, by reducing the dielectric constant of a dielectric material by arranging a dielectric composition containing the resulted product of the reaction between a multi-branched high polymer and an organic polysilica adjacently to the circuit wiring on a substrate. SOLUTION: A dielectric composition 6 containing the resulted product of the reaction between a multi-branched high polymer and an organic polysilica is arranged adjacently to metallic circuit wiring 4 laid on a substrate 2. A suitable multi-branched high polymer includes multi-branched poly(allyl ether phenyl quinoxaline), poly(ether quinoline), poly(allyl ester), poly(ether ketone), etc. In addition, a suitable polysilica includes such silsesquioxane as the phenyl/ C1-6 alykylsilsesquioxane, etc. For example, the dielectric material 6 containing the reaction product is disposed between the metallic circuit wiring 4 laid on the substrate 2 having vertical studs 8.

公开(公告)号：GB2537264A

公开(公告)日：2016-10-12

申请号：GB201607798

申请日：2014-08-01

Applicant: IBM

Inventor： ROBERT DAVID ALLEN ,  KRISHNA MOHAN BAJJURI ,  GREGORY BREYTA ,  JAMES LUPTON HEDRICK ,  CARL ERIC LARSON

IPC: C08J11/28 ,  C07C51/09

Abstract: Provided is a method of depolymerizing polyesters from post-consumer products, such as beverage bottles, to produce a high purity reaction product. For the depolymerization reaction, the polyesters are reacted with an alcohol having 2 to 5 carbons and an amine organocatalyst at a temperature of about 150 degrees C to about 250 degrees C. In one application, the use an organocatalyst with a boiling point significantly lower than the boiling point of the reactant alcohol allows for the ready recycling of the amine organocatalyst. In another application, performing the depolymerization reaction under pressure at a temperature above that of the alcohol allows for accelerated depolymerization rates and the recovery of the organocatalyst with no further heat input. In a further application, glycolytic depolymerization of poly(ethylene terephthalate) (PET) from post-consumer beverage bottles produces a pure reaction product of bis(2-hydroxyethyl)terephthalate (BHET), which may in turn be used to produce high purity beverage bottle grade PET, in a closed loop process with minimal output and waste.

公开(公告)号：GB2524924B

公开(公告)日：2018-01-03

申请号：GB201512719

申请日：2014-03-31

Applicant: IBM ,  AGENCY SCIENCE TECH & RES

Inventor： JAMES LUPTON HEDRICK ,  ASHLYNN L Z LEE ,  VICTOR W L NG ,  YI YAN YANG

IPC: C08G63/06

公开(公告)号：GB2535360B

公开(公告)日：2017-04-12

申请号：GB201606994

申请日：2014-09-28

Applicant: IBM

Inventor： JAMES LUPTON HEDRICK ,  HANS W HORN ,  GAVIN O JONES ,  JEANNETTE M O'BRIEN ,  KUMAR R VIRWANI

IPC: C08G12/08

Abstract: Polyhexahydrotriazine (PHT) film layers are formed by a process comprising heating a first mixture comprising i) a solvent, ii) paraformaldehyde, and iii) a diamine monomer comprising two primary aromatic amine groups at a temperature of about 20° C. to less than 150° C. This heating step forms a stable polyhemiaminal (PHA) in solution, which can be cast on a surface of a substrate, thereby forming an initial film layer comprising the PHA. The initial film layer is heated at a temperature of 180° C. to about 280° C., thereby converting the PHA film layer to a PHT film layer. Young's moduli of about 8 GPA to about 14 GPA have been observed for the PHT film layers.

公开(公告)号：GB2537264B

公开(公告)日：2021-01-20

申请号：GB201607798

申请日：2014-08-01

Applicant: IBM

Inventor： ROBERT DAVID ALLEN ,  KRISHNA MOHAN BAJJURI ,  GREGORY BREYTA ,  JAMES LUPTON HEDRICK ,  CARL ERIC LARSON

IPC: C08J11/28 ,  C07C51/09

Abstract: Provided is a method of depolymerizing polyesters from post-consumer products, such as beverage bottles, to produce a high purity reaction product. For the depolymerization reaction, the polyesters are reacted with an alcohol and an amine organocatalyst at a temperature of about 150° C. to about 250° C. In one application, the use of an organocatalyst with a boiling point significantly lower than the boiling point of the reactant alcohol allows for the ready recycling of the amine organocatalyst. In another application, performing the depolymerization reaction under pressure at a temperature above the boiling point of the alcohol allows for accelerated depolymerization rates and the recovery of the organocatalyst with no further heat input. In a further application, glycolytic depolymerization of poly(ethylene terephthalate) (PET) produces a reaction product of bis(2-hydroxyethyl)terephthalate (BHET), which may in turn be used to produce high purity beverage bottle grade PET, in a closed loop process with minimal waste.

公开(公告)号：GB2493877B

公开(公告)日：2016-11-23

申请号：GB201221302

申请日：2011-04-28

Applicant: CENTRAL GLASS CO LTD ,  IBM

Inventor： DANIEL PAUL SANDERS ,  JAMES LUPTON HEDRICK ,  MANABU YASUMOTO ,  MASAKI FUJIWARA

IPC: C07D319/04 ,  C07D317/36 ,  C08G64/02 ,  C08G64/30

Abstract: A one pot method of preparing cyclic carbonyl compounds comprising an active pendant pentafluorophenyl carbonate group is disclosed. The cyclic carbonyl compounds can be polymerized by ring opening methods to form ROP polymers comprising repeat units comprising a side chain pentafluorophenyl carbonate group. Using a suitable nucleophile, the pendant pentafluorophenyl carbonate group can be selectively transformed into a variety of other functional groups before or after the ring opening polymerization.

公开(公告)号：GB2535360A

公开(公告)日：2016-08-17

申请号：GB201606994

申请日：2014-09-28

Applicant: IBM

Inventor： JAMES LUPTON HEDRICK ,  HANS W HORN ,  GAVIN O JONES ,  JEANNETTE M O'BRIEN ,  KUMAR R VIRWANI

IPC: C08G12/08

Abstract: Polyhexahydrotriazine (PHT) film layers are formed by a process comprising heating a first mixture comprising i) a solvent, ii) paraformaldehyde, and iii) a diamine monomer comprising two primary aromatic amine groups at a temperature of about 20°C to less than 150 °C. This heating step forms a stable polyhemiaminal (PHA) in solution, which can be cast on a surface of a substrate, thereby forming an initial film layer comprising the PHA. The initial film layer is heated at a temperature of 180°C to about 280°C, thereby converting the PHA film layer to a PHT film layer. Young's moduli of about 8 GPA to about 14 GPA have been observed for the PHT film layers.