公开(公告)号：WO1993006837A1

公开(公告)日：1993-04-15

申请号：PCT/US1992006921

申请日：1992-08-21

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  MERIANOS, John, J. ,  GARELICK, Paul

IPC: A61K31/79

CPC classification number: C08F8/22 ,  A01N59/12 ,  A61K31/79 ,  A61K33/18 ,  A61K47/58 ,  C08F26/10

Abstract: A proces for preparing a water-insoluble or water-soluble PVP-iodine product which comprises intimately mixing water-insoluble PVP or water-soluble PVP having a K-value of 10-20, about 10 to 20 % by weight of iodine powder and about 0.05 to 1 % by weight of isopropanol, heating the reaction mixture at a mixing temperature of room temperature to about 30-60 DEG C for about 0.5 to 6 hours, and heating the mixture at a reaction temperature of about 65 to 98 DEG C for about 10-24 hours, generally at least 18 hours, to form a stable, uniform, free-flowing powder.

Abstract translation: 制备水不溶性或水溶性PVP-碘产物的方法，其包括将K值为10-20，约10至20重量％的碘粉末的水不溶性PVP或水溶性PVP与 约0.05-1重量％的异丙醇，在室温至约30-60℃的混合温度下加热反应混合物约0.5至6小时，并在约65至98℃的反应温度下加热该混合物 约10-24小时，通常至少18小时，以形成稳定，均匀的自由流动的粉末。

公开(公告)号：WO1992019390A1

公开(公告)日：1992-11-12

申请号：PCT/US1992002865

申请日：1992-04-01

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  PELESKO, John, D.

IPC: B05D03/02

CPC classification number: B05D5/10 ,  B05D3/029 ,  B05D2401/20 ,  C08F8/14 ,  C08F2810/50 ,  C08J5/18 ,  C08F222/06 ,  C08F216/18

Abstract: A continuous process for the production of pressure sensitive adhesive mass compositions and adhesive elements which exhibit excellent properties with respect to a variety of substrates, which is non-toxic and non-sensitizing. The element exhibits high cohesive strength so that its integrity is maintained on removal from the substrate leaving no residues and is highly flexible so that total confirmation with the underlying shape of the substrate is maintained. The adhesive composition includes the hydrolysis/esterification product of a methyl vinyl ether/maleic anhydride copolymer with an hydroxylated compound. In this invention, the adhesive element is prepared by microwave heating of a mixture of the copolymer and hydroxylated compound, preferably with a surfactant, in the presence of water.

公开(公告)号：WO1992012186A1

公开(公告)日：1992-07-23

申请号：PCT/US1991006782

申请日：1991-09-19

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  VARA, Fulvio, J. ,  DOUGHERTY, James, A. ,  WILKINS, Geoffrey, J.

IPC: C08F220/26

CPC classification number: C09D4/00 ,  C08F222/1006

Abstract: A radiation curable composition is provided herein which comprises suitably 50-90 parts, preferably 60-80 parts, by weight, of a multifunctional acrylate monomer, suitably with 3-6 acrylate groups, preferably pentaerythritol triacrylate or trimethylolpropane triacrylate, 10-50 parts by weight, preferably 20-40 parts by weight, of a divinyl ether monomer having both a hydrophobic backbone and an abrasion-resistant moiety, which is preferably the divinylether of cyclohexane dimethanol, and a radiation curing initiator, suitably a cationic initiator, and preferably, in combination with a free radical initiator.

公开(公告)号：WO1992007546A1

公开(公告)日：1992-05-14

申请号：PCT/US1991005074

申请日：1991-07-18

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  HELIOFF, Michael, W. ,  PLOCHOCKA, Krystyna ,  TAZI, Mohammed

IPC: A61K07/075

CPC classification number: A61Q5/06 ,  A61K8/046 ,  A61K8/8164 ,  A61Q5/02

Abstract: The hair setting shampoo composition comprises a resin provided by about 1-15 % by weight of about a 20-50 % resin active alcoholic solution of the alkyl half-ester of a C1-C5 alkyl vinyl ether-maleic anhydride copolymer having a molecular weight of at least one million, which is about 5-90 % neutralized, preferably with about 0.01-1 % by weight of 2-amino-2-methyl-1-propanol, about 5-60 % by weight of a surfactant, optionally 0-10 % by weight of added ethanol, and about 30-90 % by weight of water. The composition provides a subtle temporary set on hair of the user without the use of auxiliary fixatives in the composition. The mousse hair composition includes 3-15 % by weight of the alcoholic solution of the resin, 60-95 % by weight of water, 0.3-2.0 % by weight of a surfactant, and 0-30 % by weight of added ethanol.

Abstract translation: 头发定型洗发剂组合物包含树脂，其由约1-15重量％的约20-50％的具有分子量的C 1 -C 5烷基乙烯基醚 - 马来酸酐共聚物的烷基半酯的树脂活性醇溶液 至少一百万，约5-90％中和，优选约0.01-1重量％的2-氨基-2-甲基-1-丙醇，约5-60重量％的表面活性剂，任选地0 -10重量％的添加的乙醇和约30-90重量％的水。 该组合物在使用者的头发上提供微妙的临时固定，而不需要在组合物中使用辅助固定剂。 摩丝发组合物包含3-15重量％的树脂醇溶液，60-95重量％的水，0.3-2.0重量％的表面活性剂和0-30重量％的加入的乙醇。

公开(公告)号：WO1992004405A1

公开(公告)日：1992-03-19

申请号：PCT/US1991004649

申请日：1991-06-28

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  TAZI, Mohammed ,  LOGIN, Robert, B.

IPC: C08K05/05

CPC classification number: C08J3/09 ,  C08J2335/08

Abstract: What is described herein is a process for making ethanol solutions of alkyl half-esters of copolymers of maleic anhydride and a C1-C4 alkyl vinyl ether which are benzene and acetone-free. The invention is characterized by (a) precharging a reactor with excess C1-C4 alkyl vinyl ether as both monomer reactant and solvent, and a free radical polymerization intiator, at a reaction temperature; (b) feeding the alkyl half-ester of maleic anhydride formed by reaction of substantially one mole of maleic anhydride and substantially one mole of alkanol into the precharged reactor to form the desired alkyl half-ester of the alternating copolymer of maleic anhydride and the C1-C4 alkyl vinyl ether in excess alkyl vinyl ether as solvent; (c) cooling the reactor to room temperature; and (d) introducing ethanol solvent into the reactor and removing excess alkyl vinyl ether to form the desired half-ester copolymer in ethanol solution.

公开(公告)号：WO1992002564A1

公开(公告)日：1992-02-20

申请号：PCT/US1991004875

申请日：1991-07-11

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  TAZI, Mohammed ,  ARDAN, John, J. ,  COHEN, Jeffrey, M. ,  ZAMORA, John, N.

IPC: C08F16/16

CPC classification number: C08F216/18 ,  C08F222/06

Abstract: What is described herein is a process for making a copolymer of high specific viscosity by polymerisation of maleic anhydride and a C1-C4 alkyl vinyl ether monomer. The invention involves polymerizing said monomers to form a slurry of said copolymer in excess alkyl vinyl ether as solvent and toluene or an aliphatic organic compound as cosolvent, and is characterized by the steps of: (a) precharging a reactor with C1-C4 alkyl vinyl ether as solvent at a reaction temperature, (b) feeding a mixture of maleic anhydride and a C1-C4 alkyl vinyl ether in substantially stoichiometric amounts, preferably with a slight excess of the alkyl vinyl ether, and at a selected rate, into said precharged reactor, and (c) simultaneously feeding a predetermined mixture of toluene or an aliphatic organic compound and a polymerization initiator continuously over substantially the entire period of polymerization.

Abstract translation: 本文描述的是通过马来酸酐和C1-C4烷基乙烯基醚单体的聚合制备高比粘度的共聚物的方法。 本发明涉及使所述单体聚合以形成作为溶剂的过量烷基乙烯基醚中的所述共聚物的浆液和作为共溶剂的甲苯或脂族有机化合物，其特征在于以下步骤：（a）用C1-C4烷基乙烯基 乙醚作为溶剂，（b）将基本上化学计量的马来酸酐和C1-C4烷基乙烯基醚的混合物，优选稍微过量的烷基乙烯基醚，并以选定的速率进料到所述预充电 反应器，和（c）在基本上整个聚合期间内同时进料预定的甲苯或脂族有机化合物和聚合引发剂的混合物。

公开(公告)号：WO1991018024A1

公开(公告)日：1991-11-28

申请号：PCT/US1991002764

申请日：1991-04-24

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  TAZI, Mohammed ,  ARDAN, John, J.

IPC: C08F02/00

CPC classification number: C08F216/18

Abstract: What is described herein is a process for making copolymers of maleic anhydride and C1-C4 alkyl vinyl ethers of predetermined specific viscosities extending over a wide viscosity range. The invention is characterized by (a) precharging a reactor with a C1-C4 alkyl vinyl ether as solvent and a polymerization initiator at a reaction temperature, (b) feeding a mixture of maleic anhydride and a C1-C4 alkyl vinyl ether in substantially stoichiometric amounts, preferably with a slight excess of alkyl ether, and at a selected rate, into said precharged reactor, (c) polymerizing said reactants to form a slurry of said copolymer in said excess alkyl vinyl ether solvent, and (d) introducing toluene into said reactor during the polymerization to control the specific viscosity of the copolymer product being produced.

公开(公告)号：WO1991017142A1

公开(公告)日：1991-11-14

申请号：PCT/US1991002717

申请日：1991-04-19

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  NARAYANAN, Kolazi, S. ,  TAYLOR, Paul, D.

IPC: C07C331/00

CPC classification number: C07B61/00 ,  C07C331/20

Abstract: A method for preparing (R)Xm-pAp by reacting (R)Xm and MA in N-methylpyrrolidone and recovering the by-product MX as a precipitate.

公开(公告)号：WO1991016318A1

公开(公告)日：1991-10-31

申请号：PCT/US1991001538

申请日：1991-03-07

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  BUCHANAN, Donald, W., Jr.

IPC: C07D307/32

CPC classification number: C07D315/00

Abstract: What is provided herein is a vapor phase process for the production of butyrolactone in which the vapor mixture of the feed compound and hydrogen is provided at high flow rates from finely divided droplets of the feed compound which are vaporized rapidly with hot hydrogen gas.

公开(公告)号：WO1991015522A1

公开(公告)日：1991-10-17

申请号：PCT/US1991002115

申请日：1991-03-28

Applicant: ISP INVESTMENTS INC.

Inventor： ISP INVESTMENTS INC. ,  TAZI, Mohammed ,  MANDELLA, William, L.

IPC: C08F26/08

CPC classification number: C08F26/10

Abstract: An uncrosslinked, water-soluble polyvinylpyrrolidone having a K-value in excess of 120 and containing less than about 0.1 percent by weight of residual monomer. A method for preparing the high molecular weight polyvinylpyrrolidone is also disclosed.

Abstract translation: 未交联的水溶性聚乙烯吡咯烷酮，其K值超过120，并含有少于约0.1重量％的残余单体。 还公开了制备高分子量聚乙烯吡咯烷酮的方法。