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    SOLID-ACID CATALYST
    11.
    发明专利
    SOLID-ACID CATALYST 未知

    公开(公告)号：MY126054A

    公开(公告)日：2006-09-29

    申请号：MYPI20002753

    申请日：2000-06-19

    Applicant: KAO CORP

    Inventor： MIMURA TAKU ,  KAITA JUN ,  FUKUOKA NORIAKI ,  HATTORI YASUYUKI

    IPC: B01J23/40 ,  B01J27/16 ,  B01J31/02 ,  C07C41/56 ,  C07C67/03 ,  C07C67/08

    Abstract: THE PRESENT INVENTION PROVIDES A SOLID ACID CATALYST DEVELOPING HIGH ACTIVITY AND EXHIBITING HIGH DURABILITY IN VARIOUS ORGANIC REACTIONS. THAT IS, THE PRESENT INVENTION PROVIDES A SOLID ACID CATALYST HAVING THE STRUCTURE (A) IN WHICH A HYDROGEN ATOM IS ELIMINATED FROM AT LEAST ONE OF OH GROUPS CONTAINED IN AN INORGANIC PHOSPHORUS ACID, THE STRUCTURE (B) IN WHICH A HYDROGEN ATOM IS ELIMINATED FROM AT LEAST ONE OF OH GROUPS CONTAINED IN AN ORGANIC PHOSPHORUS ACID REPRESENTED BY THE FORMULA (1) OR (2) AND AT LEAST ONE METAL ATOM (C) SELECTED FROM ALUMINUM, GALLIUM AND IRON AND A METHOD FOR PRODUCING AN ESTER, A KETAL OR AN ACETAL BY USING THE SOLID ACID CATALYST; WHEREIN EACH OF -R1 AND -R² IS SELECTED FROM -R, -OR, -OH AND -H IN WHICH AT LEAST ONE OF -R1 AND -R² IS -R OR -OR, GIVEN THAT -R IS AN ORGANIC GROUP HAVING 1-22 CARBON ATOMS.

    14.
    发明专利
    未知

    公开(公告)号：DE4217044B4

    公开(公告)日：2006-04-13

    申请号：DE4217044

    申请日：1992-05-22

    Applicant: KAO CORP

    Inventor： MORI ATSUHITO ,  HATTORI YASUYUKI ,  TSUKADA KIYOSHI ,  FUKUOKA NORIAKI

    IPC: B01J23/80 ,  B01J21/06 ,  B01J23/78 ,  B01J23/83 ,  B01J23/85 ,  B01J23/887 ,  B01J37/02 ,  C07C29/149

    Abstract: A process for producing a hydrogenation reaction catalyst precursor is disclosed, including the steps of: (i) coating the outer surface of at least one of a first titanium oxide and a first titanium hydroxide having an outer surface area of at least 15 m2/g with at least one of a second titanium oxide and a second titanium hydroxide formed by hydrolyzing at least one of a titanium alkoxide represented by Formula (I) and a titanium alkoxo acid represented by Formula (II) to prepare a catalyst carrier (A); Ti(OR)4(I) wherein R represents an alkyl group having from 1 to 18 carbon atoms or an aryl group, H2[Ti(OR)6](II) wherein R has the same meaning as above; (ii) applying a metal oxide composition (B) onto the catalyst carrier (A) obtained in step (i), or mixing the metal oxide composition (B) with the catalyst carrier (A) to obtain a hydrogenation reaction catalyst precursor. Also, a process for producing an alcohol is described, including catalytically reducing an organic carboxylic acid ester with hydrogen in the presence of a catalyst obtained by reducing the hydrogenation reaction catalyst precursor produced by the process described above.

    15.
    发明专利
    未知

    公开(公告)号：DE4131209C2

    公开(公告)日：2002-06-20

    申请号：DE4131209

    申请日：1991-09-19

    Applicant: KAO CORP

    Inventor： TSUKADA KIYOSHI ,  HATTORI YASUYUKI ,  TAMURA HIROYUKI ,  YAMAMURO AKIRA ,  HASHIBA KUNIZO ,  TABATA OSAMU

    IPC: C07C29/149

    Abstract: A process for producing alcohols comprising catalytically reducing fats and oils or fatty acid esters with hydrogen in the presence of a catalyst for ester reduction is disclosed, wherein the starting oils are first treated at a temperature of from 50 DEG to 200 DEG C. in hydrogen gas or a mixed gas of hydrogen and an inert gas in the presence of a nickel catalyst to yield a sulfur content at not more than 0.6 ppm an acid value (KOH mg/g) of not more than 2. By use of the thus purified starting oils, the catalyst for ester reduction exhibits a prolonged duration.

    16.
    发明专利
    未知

    公开(公告)号：FR2667062B1

    公开(公告)日：1993-12-03

    申请号：FR9111659

    申请日：1991-09-20

    Applicant: KAO CORP

    Inventor： TSUKADA KIYOSHI ,  HATTORI YASUYUKI ,  TAMURA HIROYUKI ,  YAMAMURO AKIRA ,  HASHIBA KUNIZO ,  TABATA OSAMU

    IPC: C07C29/149 ,  C07C67/60 ,  C11B3/02

    Abstract: A process for producing alcohols comprising catalytically reducing fats and oils or fatty acid esters with hydrogen in the presence of a catalyst for ester reduction is disclosed, wherein the starting oils are first treated at a temperature of from 50 DEG to 200 DEG C. in hydrogen gas or a mixed gas of hydrogen and an inert gas in the presence of a nickel catalyst to yield a sulfur content at not more than 0.6 ppm an acid value (KOH mg/g) of not more than 2. By use of the thus purified starting oils, the catalyst for ester reduction exhibits a prolonged duration.

    17.
    发明专利
    未知

    公开(公告)号：DE4131209A1

    公开(公告)日：1992-03-26

    申请号：DE4131209

    申请日：1991-09-19

    Applicant: KAO CORP

    Inventor： TSUKADA KIYOSHI ,  HATTORI YASUYUKI ,  TAMURA HIROYUKI ,  YAMAMURO AKIRA ,  HASHIBA KUNIZO ,  TABATA OSAMU

    IPC: C07C29/149

    Abstract: A process for producing alcohols comprising catalytically reducing fats and oils or fatty acid esters with hydrogen in the presence of a catalyst for ester reduction is disclosed, wherein the starting oils are first treated at a temperature of from 50 DEG to 200 DEG C. in hydrogen gas or a mixed gas of hydrogen and an inert gas in the presence of a nickel catalyst to yield a sulfur content at not more than 0.6 ppm an acid value (KOH mg/g) of not more than 2. By use of the thus purified starting oils, the catalyst for ester reduction exhibits a prolonged duration.

    19.
    发明专利
    未知

    公开(公告)号：DE4207787C2

    公开(公告)日：2002-10-24

    申请号：DE4207787

    申请日：1992-03-11

    Applicant: KAO CORP

    Inventor： TAMURA HIROYUKI ,  HATTORI YASUYUKI ,  HASHIBA KUNIZO ,  TABATA OSAMU ,  TSUKADA KIYOSHI ,  FUKUOKA NORIAKI

    IPC: C07C29/149 ,  C11B3/02 ,  B01J23/80 ,  B01J23/70 ,  C07C31/125 ,  C07C33/02

    Abstract: A process for producing desulfurized fats and oils or fatty acid esters is disclosed, which comprises treating fats and oils or fatty acid esters under hydrogen or a mixture of hydrogen and an inert gas atmosphere at a pressure of from 0.1 to 500 kg/cm2 in the absolute pressure at a temperature of from 100 DEG to 350 DEG C. in the presence of a catalyst of the following formula (I): CuxXxxYyxOz(I) wherein all symbols are defined in the disclosure. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.

    20.
    发明专利
    未知

    公开(公告)号：DE19738759C2

    公开(公告)日：2002-08-29

    申请号：DE19738759

    申请日：1997-09-04

    Applicant: KAO CORP

    Inventor： TAMURA HIROYUKI ,  TAHARA HIDEO ,  MITSUDA YOSHINORI ,  HATTORI YASUYUKI

    IPC: B01J23/10 ,  B01J23/12 ,  C07B61/00 ,  C07C27/02 ,  C07C29/149 ,  C07C33/02 ,  C07C33/025

    Abstract: A process for producing an unsaturated alcohol wherein the catalytic activity and the capability of maintaining double bond are sustained for a long time and side-reactions are suppressed. An unsaturated alcohol is obtained by hydrogenating an alkyl or alkenyl ester of an unsaturated fatty acid or a triglyceride having a long-chain aliphatic unsaturated hydrocarbon group in the presence of a catalytic composition which is a composite metal oxide consisting of (a) zinc oxide and (b) oxide(s) of at least one metal selected from the group consisting of the elements of the group 3A in the periodic table and having a weight ratio of (a)/(b) of from 1/0.01 to 1/1.2.

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