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公开(公告)号：JPH07188531A
公开(公告)日：1995-07-25
申请号：JP33126493
申请日：1993-12-27
Applicant: KAO CORP
Inventor： HOSOKAWA YASUTOKU , NAKANO YUKIHIRO , ODAKURA SHINJI , SANO YASUNORI
Abstract: PURPOSE:To provide a plastic container produced from a polyester resin composition comprising a specific modified polyester resin and a specified resin dispersed therein, and excellent in environmental characteristics, impact resistance, rigidity, dimensional stability, moldability, luster, etc. CONSTITUTION:This container comprises a polyester resin composition comprising (A) 100 pts.wt. of a modified polyethylene terephthalate resin in which 3-100mol.% among the total amount of 200mol.% comprising 100mol% of the dicarboxylic acid component and 100mol.% of the diol component is modified and which has a glass transition tempeqature of >=50 deg.C and an intrinsic viscosity [eta]of >=0.5dl/g in a phenol/tetrachloroethane (weight ratio : 6/4) mixture solvent at 25 deg.C, and (B) 1-30 pts.wt. of a resin (preferably an acrylic rubber) having a Tg of
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公开(公告)号：JPH05156144A
公开(公告)日：1993-06-22
申请号：JP9472092
申请日：1992-04-15
Applicant: KAO CORP
Inventor： TAKEI SHINOBU , IWASAKI HIROAKI , OTANI SHOJI , OSAWA TETSUHIRO , HOSOKAWA YASUTOKU
Abstract: PURPOSE:To provide a resin compsn. excellent in oil resistance and flexibility and suitable as a material of a container which is neither deformed nor swollen even by the contents contg. an oil in a high proportion and excellent in squeezability, adhesion by pinch-off, and heat-sealing properties, and to provide the container. CONSTITUTION:At least one amorphous or lowly crystalline resin selected from the group consisting of polyester and polyamide resins each having a glass transition point of about 50 deg.C or higher is blended with at least one resin selected from the group consisting of polyester and polyamide resins each having a glass transition point of about 40 deg.C or lower, thereby giving the objective resin compsn.
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公开(公告)号：JPH0464440A
公开(公告)日：1992-02-28
申请号：JP17681690
申请日：1990-07-03
Applicant: KAO CORP
Inventor： HOSOKAWA YASUTOKU , SUZUKI FUMITO , AMIYA TSUYOSHI , YASUDA YUTAKA
Abstract: PURPOSE:To improve the barrier performance against gas such as oxygen, carbon dioxide, or the like, and water vapor by forming a multilayer vessel comprising at least two layers of thermoplastic polyester having a specified composition and polyolefin. CONSTITUTION:A perform is molded by injection molding, which comprises at least two layers of a thermoplastic layer containing an ethylene naphthalate unit of 80mol% as a repeated unit and a polyolefinic layer. It is then subjected to draw/blow molding in at least single axis direction at a temperature of 110-170 deg.C, to thereby form a multilayer vessel. The used polyolefin preferably contains a propylene unit of 70mol% as a repeated unit, and also may be a copolymer of olefin such as 1-octane of 30mol%. In order to enhance the transparency, and the barrier performance against gas such as oxygen, carbon dioxide or the like in the vessel, it is preferable to effect the draw-molding in at least a single axis direction.
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公开(公告)号：JPS6197301A
公开(公告)日：1986-05-15
申请号：JP21814684
申请日：1984-10-17
Applicant: Kao Corp
Inventor： KOBAYASHI TAKATOSHI , HOSOKAWA YASUTOKU
Abstract: PURPOSE: To obtain the titled resin useful as, e.g., a support for immobilizing enzymes or a hydroscopic material stably in good efficiency, by polymerizing an aqueous solution of a water-soluble ethylenically unsaturated monomer suspended by dispersion in a hydrophobic solvent inert to polymerization in the presence of a specified dispersant.
CONSTITUTION: A dispersant mixture (B) is obtained by adding a polyoxyalkyl ene monoether-type hydrophobic group-containing oil-soluble noionic surfactant to a sorbitan fatty acid ester of a HLB of 3ν9 so that the resultant HLB may be adjusted to 6W10. 1pt.wt. 15W80wt% aqueous solution of a water-soluble ethylenically unsaturated monomer (A) [e.g., (meth)acrylic acid] is suspended by dispersing in 1W4pts.wt. hydrophobic solvent inert to polymerization such as an aliphatic or alicyclic hydrocarbon of a b.p. of30W200°C in the presence of 0.05W10wt%, based on component A, component B. A water-soluble radical polymerization initiator (e.g., potassium persulfate) is added to the dispersion and dissolved and this dispersion is subjected to W/O suspension polymerization.
COPYRIGHT: (C)1986,JPO&JapioAbstract translation: 目的：通过将通过分散体悬浮的水溶性烯属不饱和单体的水溶液聚合到对聚合反应惰性的疏水性溶剂中，获得用作例如稳定酶稳定的支持物或吸湿材料的标题树脂 存在特定的分散剂。 构成：通过向具有3nu9的HLB的脱水山梨糖醇脂肪酸酯中加入含有聚氧烷基烯醚单醚型疏水基团的油溶性离子表面活性剂，得到分散剂混合物（B），得到的HLB可调至6-10 。 1pt.wt. 将水溶性烯键式不饱和单体（A）[例如（甲基）丙烯酸]的15-80重量％水溶液通过分散在1-4pts.wt。 对聚合惰性的疏水溶剂如脂肪族或脂环族烃的沸点 在基于组分A，组分B的情况下，在0.05-10重量％的存在下，将30-200℃。将水溶性自由基聚合引发剂（例如过硫酸钾）加入到分散体中并溶解，并将该分散体经受W / O悬浮聚合。
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公开(公告)号：JP2000026738A
公开(公告)日：2000-01-25
申请号：JP16713698
申请日：1998-06-15
Applicant: KAO CORP
Inventor： HOSOKAWA YASUTOKU , IGARASHI TADASHI , TSURU ISAO , HANADA YOKO
IPC: C08K3/32 , A61F13/15 , C08K3/00 , C08K3/10 , C08K5/00 , C08K5/16 , C08K5/5317 , C08K5/56 , C08L33/02 , C08L101/00 , C08L101/14
Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition causing no degradation of the highly water-absorbing resin even in e.g. an aqueous solution containing radical- generating matter such as L-ascorbic acid and transition metal ion(s) such as iron ion despite being high in water absorption by including a highly water- absorbing resin, a specific metal compound such as of titanium, and a chelate compound. SOLUTION: This composition is obtained by including (A) a highly water- absorbing resin, (B) a metal compound containing Ti and/or Zr, pref. a polyvalent metal salt composed of a hydroxy acid (salt) and Ti and/or Zr (mixed with alkoxide(s) of Ti and/or Zr), and (C) a chelate compound (pref. a water-soluble inorganic phosphorus-based compound, aminocarboxylic acid-based compound, organophosphorus-based compound, surfactant-based compound, or the like); alternatively, by including the component A and (D) a compound with the component C coordinated on the above metal(s).
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Patent Agency Ranking
公开(公告)号：JPH06144433A
公开(公告)日：1994-05-24
申请号：JP29847992
申请日：1992-11-09
Applicant: KAO CORP
Inventor： TAKENAKA AKIRA , ITOI AKITO , NISHI ISAO , HOSOKAWA YASUTOKU
IPC: B29C49/08 , B29K67/00 , B29L22/00 , B65D1/00 , B65D1/02 , C08K5/07 , C08L67/00 , C08L67/02 , B65D1/09
Abstract: PURPOSE:To decrease the amount of resin in a polyester container while increasing the strength of the container by making the container by stretched blow molding with a specified compound added to polyester resin. CONSTITUTION:A resin composition obtained by adding a compound shown in a formula I or a compound shown in a formula III in 0.1-10 pts.wt. to polyester resin in 100 pts.wt. is molded by stretched blow molding. In the formula I, R stands for alkyl group or alkoxyl group, and R'stands for hydrocarbon group, m and n are the integers with which m+n becomes not less than 0 and not more than 3, p and r are the integers with which p+r becomes 1 or 2, q is 0 or 1 and X is either one of those which are in the formula II. R1 and R2 in the formula II stand respectively for H or alkyl group with carbons in 4 or below. B1 and B2 in the formula III stand for alkyl group or alkoxyl group respectively with carbons in numbers from not less than 3 to not more than 18, A stands for dialiphatic hydrocarbon group, dialicyclic hydrocarbon group or diaromatic hydrocarbon group. When making stretched blow molding, magnification of planate stretching is four times or more.
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公开(公告)号：JPH05125165A
公开(公告)日：1993-05-21
申请号：JP28847691
申请日：1991-11-05
Applicant: KAO CORP
Inventor： HOSOKAWA YASUTOKU , SATO TAKAHIRO , YASUDA YUTAKA
IPC: B65D1/02 , C08G63/66 , C08G63/672
Abstract: PURPOSE:To obtain the subject resin, containing a specific amount of a specified diol, excellent in transparency, heat resistance and mechanical strength and suitable as hollow containers, etc. CONSTITUTION:The objective resin in which the principal component of a dicarboxylic acid component constituting the polyester is terephthalic acid and 3-80mol% of a diol component such as ethylene glycol is a diol [e.g. ethylene oxide adduct of bis(4-hydroxyphenyl)methane] expressed by formula I [R is H or methyl; X is direct bond, C2H4, formula II (Y and Z are H or 1-3C alkyl), O or SO2; (n) and (m) are 1-5].
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公开(公告)号：JPH04148929A
公开(公告)日：1992-05-21
申请号：JP27486290
申请日：1990-10-12
Applicant: KAO CORP
Inventor： HOSOKAWA YASUTOKU , SUZUKI FUMITO , AMIYA TSUYOSHI , YASUDA YUTAKA
Abstract: PURPOSE:To obtain a multilayer plastic container having transparency and excellent in barrier properties to gas, water vapor and ultraviolet rays by forming the container consisting of two layers of a thermoplastic polyester layer which has ethylene terephthalate as a main repeating unit, and a thermoplastic polyester layer containing ethylene naphthalate. CONSTITUTION:In this process for producing a multilayer plastic container, a preform (preliminarily molded article) consisting of at least two layers of a thermoplastic polyester layer (layer A) which has the main repeating unit of 90mol% or more ethylene terephthalate as a repeating unit, and a thermoplastic polyester layer (layer B) which has 5-90mol% ethylene naphthalate as a repeating terminal, is molded by injection molding and then blow-molded to be oriented at least in an uniaxial direction in a temperature range of 80-120 deg.C. The multilayer plastic container thus produced is uniform in its thickness, has transparency and is further excellent in barrier properties to gas, such as an oxygen gas and a carbonic acid gas, or to water vapor, and also in barrier properties to ultraviolet rays. In particular, the container can be suitably utilized as a foodstuff packaging container.
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公开(公告)号：JPH03193996A
公开(公告)日：1991-08-23
申请号：JP33242189
申请日：1989-12-20
Applicant: KAO CORP
Inventor： IKOMA KIYOKO , KAKIUCHI HIDESUKE , HOSOKAWA YASUTOKU
Abstract: PURPOSE:To provide a hydrolyzable paper capable of being flowed in a toilet after used by employing a water-soluble anionic adhesive and a specific water- soluble cationic polymer as a yield-improving agent. CONSTITUTION:A pulp slurry is mixed with a water-soluble cationic polymer having repeating units of the formula [R1 is H or methyl; R2 and R3 are 1-3C alkyl, hydroxyl-substituted alkyl or benzyl; Z is -C(O)O- or -C(O)NH-; Y is 2-4C alkylene or hydroxyl-substituted alkylene; X is anion; n is >=2] and a viscosity (20 deg.C) of 9-200cP, preferably 9-200cP, in a state of 20% aqueous solution preferably in an amount of 1-6% (based on the weight of the pulp), further mixed with a water-soluble anionic adhesive (e.g. CMC or carrageenan) and subsequently subjected to a paper-making process to provide the objective hydrolyzable paper.
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公开(公告)号：JPS61231004A
公开(公告)日：1986-10-15
申请号：JP7241885
申请日：1985-04-05
Applicant: KAO CORP
Inventor： OTANI SHOJI , HOSOKAWA YASUTOKU , YASUDA YUTAKA
Abstract: PURPOSE:The titled dispersant which can consistently given small polymer granules free of fine polymer particles, prepared by reacting a polymer of an N-vinyl cyclic amide with an alpha-olefin or an alkyl vinyl ether in the presence of a peroxide compound. CONSTITUTION:A polymer of an N-vinyl cyclic amide of formula II (wherein R' and R'' are each H, CH3 or C2H5 and n is 1-3), e.g., N-vinylpyrrolidone, is reacted with a 6C or higher alpha-olefin or an alkyl vinyl ether, wherein the alkyl group is 6C or higher, at 80-200 deg.C for 10-40hr in the presence of a peroxide compound to obtain the titled dispersant comprising a polymer having repeating units of formula II, wherein (R1, R2) is selected from among the combinations of (H, H), (H, CH3), (H, C2H5), (CH3, C2H5), (H, 6C or higher linear or branched alkyl) and (H, 6C or higher alkoxyethyl) and R3-4 are each a 6C or higher linear or branched alkyl or a 6C or higher alkoxyethyl. A monomer is subjected to reversed phase suspension polymerization in the presence of 0.01-10wt% said dispersant.
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