公开(公告)号：DE4120536A1

公开(公告)日：1992-01-02

申请号：DE4120536

申请日：1991-06-21

Applicant: KAO CORP

Inventor： MATSUDA MORIO ,  HORIO MASAMITSU ,  TSUKADA KIYOSHI

IPC: B01J23/74 ,  B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  C07B61/00 ,  C07C29/149 ,  C07C29/153 ,  C07C31/00 ,  C07C31/125

Abstract: The hydrogenation catalyst comprises copper, iron, aluminum and optionally zine and a support selected from aluminum hydroxide, aluminum oxide and a mixture of aluminum hydroxide and aluminum oxide, having an atomic ratio of Cu/Fe/Al/Zn in the range of 1/(0.4 to 2.5)/(0.5 to 5.0)/(0 to 1.0). It is produced by dispersing a material for the support in an aqueous medium, depositing cupper and iron on the dispersant, further depositing thereon aluminum and sintering it. It is a catalyst for production of a higher alcohol from its methyl ester, effecting hydrogenation with an improved selectivity and activity.

公开(公告)号：DE4217839B4

公开(公告)日：2004-07-01

申请号：DE4217839

申请日：1992-05-29

Applicant: KAO CORP

Inventor： HATTORI YASUYUKI ,  TAMURA HIROYUKI ,  KADOWAKI HIDETOSHI ,  TSUKADA KIYOSHI

IPC: B01J23/755 ,  C07C27/26 ,  C07C29/149 ,  C07C67/60 ,  C07C69/587 ,  C11B3/02 ,  C07C67/48 ,  B01J23/70

Abstract: A process for producing desulfurized fats and oils or fatty acid esters, which are highly suitable as a starting material for producing alcohols via hydrogenation, at a high yield is disclosed. Desulfurized fats and oils or fatty acid esters are obtained by contacting fats and oils or fatty acid esters with a catalyst represented by the following formula (I) under a hydrogen atmosphere or a mixture of hydrogen with an inert gas: Ni.CuxOy(I) wherein x represents an atomic ratio of Cu determined by referring Ni as 1 and a value of from 0.02 to 8; and y is an atomic ratio of oxygen satisfying the valence requirements of Ni and Cu. A process for producing alcohols using the desulfurized fats and oils or fatty acid esters is also disclosed. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.

公开(公告)号：DE69416955T2

公开(公告)日：1999-08-05

申请号：DE69416955

申请日：1994-12-08

Applicant: KAO CORP

Inventor： TSUKADA KIYOSHI ,  HATTORI YASUYUKI ,  MIMURA TAKU

IPC: B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  B01J23/86 ,  B01J37/18 ,  C07B61/00 ,  C07C29/149 ,  C07C31/02 ,  B01J37/16

Abstract: A copper-containing hydrogenation reaction catalyst is prepared by reducing a precursor of a copper-containing catalyst usable in hydrogenation reaction with hydrogen gas or a mixture of hydrogen and an inert gas by liquid phase reduction in a stream of a solvent in the temperature range of from 50 to 140 DEG C. An alcohol is produced using the catalyst thus obtained in a fixed bed continuous reaction system.

公开(公告)号：DE69414240T2

公开(公告)日：1999-04-22

申请号：DE69414240

申请日：1994-01-20

Applicant: KAO CORP

Inventor： TSUKADA KIYOSHI ,  HATTORI YASUYUKI ,  MIMURA TAKU ,  TABATA OSAMU ,  NISHIGAKI FUTOSHI

IPC: B01J23/72 ,  B01J23/60 ,  B01J23/70 ,  B01J23/745 ,  B01J23/80 ,  B01J23/86 ,  B01J37/00 ,  B01J37/16 ,  B01J37/18 ,  C07B61/00 ,  C07C29/149 ,  C07C31/125

Abstract: PCT No. PCT/JP94/00077 Sec. 371 Date Jun. 6, 1995 Sec. 102(e) Date Jun. 6, 1995 PCT Filed Jan. 20, 1994 PCT Pub. No. WO95/19844 PCT Pub. Date Jul. 27, 1995A method for preparing a copper-containing hydrogenation reaction catalyst includes the step of reducing a formed precursor of a copper-containing hydrogenation reaction catalyst with hydrogen gas or a mixture of hydrogen and inert gas by liquid phase reduction in a stream of a solvent. The reductive activation is carried out by the two steps of performing the first stage of liquid phase reduction by which the catalyst precursor is activated in the temperature range of from 20 DEG to 140 DEG C. so that at least 10% by weight of the copper oxide contained in the catalyst precursor can be reduced by the time when the temperature passes 140 DEG C., and then performing the second stage of liquid phase reduction by which the catalyst precursor is further activated in the temperature range of from 140 DEG to 250 DEG C. The catalyst thus obtained has markedly improved catalytic activity and selectivity. An alcohol of high quality can be obtained at a high productivity using the catalyst in a fixed bed continuous reaction system.

公开(公告)号：DE69408614D1

公开(公告)日：1998-04-02

申请号：DE69408614

申请日：1994-10-04

Applicant: KAO CORP

Inventor： HATTORI YASUYUKI ,  TSUKADA KIYOSHI

IPC: B01J23/76 ,  B01J21/06 ,  B01J23/78 ,  B01J23/80 ,  B01J29/76 ,  B01J37/02 ,  C07B61/00 ,  C07C29/149 ,  C07C31/02 ,  C07C33/02 ,  C07C35/02 ,  C07C37/01 ,  C07C39/02 ,  B01J23/72

Abstract: A hydrogenation reaction catalyst precursor of the present invention comprises a catalyst carrier (A) and a metal oxide composition (B) carried on or mixed with the catalyst carrier (A) at a weight ratio of (B)/(A) = 15/85 to 65/35; the catalyst carrier (A) comprising a carrier base material of silica, alumina silica-alumina, magnesia, zirconia, zeolite or diatomaceous earth, and a coating of titanium oxide and/or titanium hydroxide, the metal oxide composition (B) comprising copper oxide, zinc oxide, and at least one oxide of a metal selected from the group consisting of an element of group IIa of the periodic table, an element of group IIIb of the table, a lantanide element, and an actinide element at a weight ratio of 100/(0 to 25)/(0 to 25). A hydrogenation reaction catalyst with a high catalytic activity and a high reaction selectivity is obtained by reduction of the hydrogenation reaction catalyst precursor. By the use of the hydrogenation reaction catalyst of the present invention, a high quality alcohol can be produced at a high yield and with a high selectivity even at a low reaction temperature and a low hydrogen pressure.

公开(公告)号：FR2665090B1

公开(公告)日：1995-03-10

申请号：FR9107463

申请日：1991-06-18

Applicant: KAO CORP

Inventor： MATSUDA MORIO ,  MORIO MATSUDA ,  HORIO MASAMITSU ,  MASAMITSU HORIO ,  TSUKADA KIYOSHI ,  KIYOSHI TSUKADA

IPC: B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  C07B61/00 ,  B01J23/74 ,  C07C29/149 ,  C07C29/153 ,  C07C31/00 ,  C07C31/125 ,  B01J23/70 ,  B01J21/02 ,  B01J37/04

Abstract: La présente invention a pour objet un catalyseur d'hydrogénation, caractérisé en ce qu'il comprend du cuivre, du fer, de l'aluminium et éventuellement du zinc, ainsi qu'un support choisi parmi l'hydroxyde d'aluminium, l'oxyde d'aluminium et un mélange d'hydroxyde d'aluminium et d'oxyde d'aluminium, ayant un rapport atomique Cu/Fe/Al/Zn de 1/(0,4 à 2,5)/(0,5 à 5,0)/(0 à 1,0).

公开(公告)号：FR2673950B1

公开(公告)日：1993-12-03

申请号：FR9202913

申请日：1992-03-11

Applicant: KAO CORP

Inventor： TAMURA HIROYUKI ,  HATTORI YASUYUKI ,  HASHIBA KUNIZO ,  TABATA OSAMU ,  TSUKADA KIYOSHI ,  FUKUOKA NORIAKI

IPC: C11B3/02 ,  C07C29/149 ,  C07C31/02 ,  C07C67/60

Abstract: L'invention a notamment pour objet un procédé pour produire des alcools par réduction catalytique de graisses et d'huiles ou d'esters d'acides gras par l'hydrogène en présence d'un catalyseur pour la réduction des esters. Selon l'invention, lesdites graisses et huiles ou lesdits esters d'acides gras sont préalablement traités dans une atmosphère d'hydrogène ou d'un mélange d'hydrogène et d'un gaz inerte à une température de 100 à 350degré C pour donner une teneur en soufre des graisses et huiles ou des esters d'acides gras de 0,6 ppm ou moins, en présence d'un catalyseur représenté par la formule (I) suivante: (CF DESSIN DANS BOPI) dans laquelle X représente un élément choisi parmi Fe, Zn et Cr; Y représente un élément choisi parmi Al, Si et Ti; x et y représentent chacun une proportion atomique rapportée à la proportion de Cu prise égale à 1, pourvu que x ait une valeur de 0,02 à 2,4 et y une valeur de 0 à 2,0; et z est la proportion d'oxygène satisfaisant les conditions de valences des éléments représentés par X et Y. Applications: fabrication d'alcools de haute pureté avec un bon rendement par réduction.

公开(公告)号：DE4217839A1

公开(公告)日：1992-12-10

申请号：DE4217839

申请日：1992-05-29

Applicant: KAO CORP

Inventor： HATTORI YASUYUKI ,  TAMURA HIROYUKI ,  KADOWAKI HIDETOSHI ,  TSUKADA KIYOSHI

IPC: B01J23/755 ,  C07C27/26 ,  C07C29/149 ,  C07C67/60 ,  C07C69/587 ,  C11B3/02

Abstract: A process for producing desulfurized fats and oils or fatty acid esters, which are highly suitable as a starting material for producing alcohols via hydrogenation, at a high yield is disclosed. Desulfurized fats and oils or fatty acid esters are obtained by contacting fats and oils or fatty acid esters with a catalyst represented by the following formula (I) under a hydrogen atmosphere or a mixture of hydrogen with an inert gas: Ni.CuxOy(I) wherein x represents an atomic ratio of Cu determined by referring Ni as 1 and a value of from 0.02 to 8; and y is an atomic ratio of oxygen satisfying the valence requirements of Ni and Cu. A process for producing alcohols using the desulfurized fats and oils or fatty acid esters is also disclosed. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.

公开(公告)号：DE69416955D1

公开(公告)日：1999-04-15

申请号：DE69416955

申请日：1994-12-08

Applicant: KAO CORP

Inventor： TSUKADA KIYOSHI ,  HATTORI YASUYUKI ,  MIMURA TAKU

IPC: B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  B01J23/86 ,  B01J37/18 ,  C07B61/00 ,  C07C29/149 ,  C07C31/02 ,  B01J37/16

Abstract: A copper-containing hydrogenation reaction catalyst is prepared by reducing a precursor of a copper-containing catalyst usable in hydrogenation reaction with hydrogen gas or a mixture of hydrogen and an inert gas by liquid phase reduction in a stream of a solvent in the temperature range of from 50 to 140 DEG C. An alcohol is produced using the catalyst thus obtained in a fixed bed continuous reaction system.

公开(公告)号：DE69408614T2

公开(公告)日：1998-07-16

申请号：DE69408614

申请日：1994-10-04

Applicant: KAO CORP

Inventor： HATTORI YASUYUKI ,  TSUKADA KIYOSHI

IPC: B01J23/76 ,  B01J21/06 ,  B01J23/78 ,  B01J23/80 ,  B01J29/76 ,  B01J37/02 ,  C07B61/00 ,  C07C29/149 ,  C07C31/02 ,  C07C33/02 ,  C07C35/02 ,  C07C37/01 ,  C07C39/02 ,  B01J23/72

Abstract: A hydrogenation reaction catalyst precursor of the present invention comprises a catalyst carrier (A) and a metal oxide composition (B) carried on or mixed with the catalyst carrier (A) at a weight ratio of (B)/(A) = 15/85 to 65/35; the catalyst carrier (A) comprising a carrier base material of silica, alumina silica-alumina, magnesia, zirconia, zeolite or diatomaceous earth, and a coating of titanium oxide and/or titanium hydroxide, the metal oxide composition (B) comprising copper oxide, zinc oxide, and at least one oxide of a metal selected from the group consisting of an element of group IIa of the periodic table, an element of group IIIb of the table, a lantanide element, and an actinide element at a weight ratio of 100/(0 to 25)/(0 to 25). A hydrogenation reaction catalyst with a high catalytic activity and a high reaction selectivity is obtained by reduction of the hydrogenation reaction catalyst precursor. By the use of the hydrogenation reaction catalyst of the present invention, a high quality alcohol can be produced at a high yield and with a high selectivity even at a low reaction temperature and a low hydrogen pressure.