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公开(公告)号:ES2603272T3
公开(公告)日:2017-02-24
申请号:ES08843293
申请日:2008-10-21
Applicant: KAO CORP
Inventor: OKUTSU MUNEHISA , TAKAI MASANORI , NISHIOKA TORU , IHARA TAKESHI , NOJIRI NAOKI , UMEHARA MASAHIRO , NAKANISHI KOHEI
IPC: C08B11/08 , C08B1/06 , C08B11/14 , C08B11/145
Abstract: Un procedimiento para producir un derivado de éter de celulosa, el cual comprende producir celulosa en polvo de baja cristalinidad, la cual tiene una cristalinidad del 50% o menos, triturando toscamente pulpas en forma de láminas para obtener pulpas en forma de virutas, y tratando las pulpas en forma de virutas mediante una extrusora y posteriormente mediante un molino de bolas, así como una etapa de reaccionar la celulosa en polvo de baja cristalinidad con un compuesto epoxi, en presencia de un catalizador.
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公开(公告)号:AU2006316121B2
公开(公告)日:2012-03-08
申请号:AU2006316121
申请日:2006-11-17
Applicant: KAO CORP
Inventor: SAKUMA YASUMITSU , INOMATA YUKIO , UESAKA TOSHIO , SUGAWARA SATOSHI , UMEHARA MASAHIRO
Abstract: Provided is an O/W emulsion cosmetic composition, which contains the following components (A), (B) and (C): (A) a polymer which is either a nonionic or cationic polymer composed of a hydrophobic monomer unit and a hydrophilic monomer unit and contains from 40 to 80 wt.% of a hydrophilic group; (B) a dispersion containing the following components (a), (b), (c) and (d): (a) powders having ultraviolet screening ability and having a surface subjected to hydrophobic treatment, (b) a polymer composed of a hydrophobic monomer unit and a hydrophilic monomer unit, (c) a silicone oil, and (d) an alcohol having from 1 to 3 carbon atoms, at an (a):(b):(c):(d) weight ratio of (from 25 to 65):(from 0.1 to 5):(from 10 to 50):(from 10 to 50); and (C) water.
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公开(公告)号:CA2677870A1
公开(公告)日:2008-08-21
申请号:CA2677870
申请日:2008-02-15
Applicant: KAO CORP
Inventor: TOMIOKA KEIICHIRO , OKUTSU MUNEHISA , UMEHARA MASAHIRO , NOJIRI NAOKI , KITSUKI TOMOHITO
IPC: C08B1/00
Abstract: A process with excellent productivity by which noncrystalline cellulose r educed in cellulose I type crystallinity can be efficiently obtained from a cellulose-containing raw material. The process is for producing noncrystalli ne cellulose from a cellulose-containing raw material having a cellulose I c rystallinity calculated with the following formula exceeding 33%, wherein th e cellulose-containing raw material has a bulk density of 100-500 kg/m3 and the residual components obtained by removing water from the raw material hav e a cellulose content of 20 mass% or higher. The process for noncrystalline- cellulose production comprises treating the cellulose-containing raw materia l with a medium type pulverizer to reduce the cellulose I crystallinity to 3 3% or lower. Cellulose I crystallinity (%) = [(I22.6-I18.5)/I22.6] x 100 [I2 2.6 represents the diffraction intensity for the lattice plane (002) in X-ra y diffractometry, and I18.5 represents the diffraction intensity for the amo rphous part.]
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公开(公告)号:DE602004012809D1
公开(公告)日:2008-05-15
申请号:DE602004012809
申请日:2004-08-05
Applicant: KAO CORP
Inventor: UMEHARA MASAHIRO , YAMASHITA HIROYUKI , SAKUMA YASUMITSU , MIYOSHI KAZUHITO
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公开(公告)号:EP2433969A4
公开(公告)日:2013-10-30
申请号:EP10777793
申请日:2010-05-19
Applicant: KAO CORP
Inventor: OSAKI KAZUTOMO , TOMIOKA KEIICHIRO , NOJIRI NAOKI , UMEHARA MASAHIRO , MIYAMOTO MASAFUMI
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公开(公告)号:EP2204386A4
公开(公告)日:2011-05-25
申请号:EP08843293
申请日:2008-10-21
Applicant: KAO CORP
Inventor: OKUTSU MUNEHISA , TAKAI MASANORI , NISHIOKA TORU , IHARA TAKESHI , NOJIRI NAOKI , UMEHARA MASAHIRO , NAKANISHI KOHEI
IPC: C08B11/08 , C08B1/06 , C08B11/14 , C08B11/145
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公开(公告)号:EP2112169A4
公开(公告)日:2010-12-08
申请号:EP08711383
申请日:2008-02-15
Applicant: KAO CORP
Inventor: NOJIRI NAOKI , UMEHARA MASAHIRO , KITSUKI TOMOHITO , OKUTSU MUNEHISA , TOMIOKA KEIICHIRO
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公开(公告)号:JP2011148927A
公开(公告)日:2011-08-04
申请号:JP2010012301
申请日:2010-01-22
Inventor: FUKAYA KEIKO , TOMIOKA KEIICHIRO , UMEHARA MASAHIRO , YOSHINO TAIKI
IPC: C08B15/08
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing cellulose particles having a small average particle size and a low cellulose I-type crystallinity by suppressing aggregation of celluloses. SOLUTION: The method for producing cellulose particles includes adding, as a grinding aid, 0.1-100 pts.mass of a compound having two or more ester groups in the molecule to 100 pts.mass of a low crystalline cellulose material having a cellulose I-type crystallinity of 33% or less as represented by following formula (1) and treating the mixture by means of a grinding machine in a dry process, wherein the average particle size of the cellulose particles is 25 μm or less. Cellulose I crystallinity (%)= [(I 22.6 -I 18.5 )/I 22.6 ]×100 (1). In the formula, I 22.6 denotes the diffraction intensity of a lattice plane (002 plane), and I 18.5 denotes the diffraction intensity of an amorphous part. COPYRIGHT: (C)2011,JPO&INPIT
Abstract translation: 待解决的问题:提供通过抑制纤维素聚集来制备平均粒径小和纤维素I型结晶度低的纤维素颗粒的方法。 解决方案:制备纤维素颗粒的方法包括将作为研磨助剂的0.1-100重量份的分子中具有两个或更多个酯基的化合物加入到100磅/小时的低结晶纤维素材料中,所述低结晶纤维素材料具有 纤维素I型结晶度为33%以下,由下式(1)表示,并通过研磨机以干法处理混合物,其中纤维素颗粒的平均粒径为25μm以下。 纤维素I的结晶度(%)= [(I SB)18.5 SB>)×100(1)。 在该式中,I
22.6 SB>表示晶格面(002平面)的衍射强度,I SB> 18.5 SB>表示非晶部分的衍射强度。 版权所有(C)2011,JPO&INPIT -
公开(公告)号:JP2010155982A
公开(公告)日:2010-07-15
申请号:JP2009274741
申请日:2009-12-02
Inventor: FUKAYA KEIKO , TOMIOKA KEIICHIRO , UMEHARA MASAHIRO , YOSHINO TAIKI
Abstract: PROBLEM TO BE SOLVED: To produce cellulose particles having a small average particle diameter and low crystallinity of cellulose I type by suppressing coagulation of the cellulose particles with one another. SOLUTION: Disclosed is the method for producing the cellulose particles, in which a grinding aid selected from a higher alcohol, a higher fatty acid, a higher fatty acid salt, a higher fatty acid ester, and a polyether is added to a low crystallinity cellulose raw material represented by formula described below with the crystallinity of cellulose I type of 33% or less, and the mixture is processed with a grinder in a dry process. Provided are (1) the method for producing the cellulose particles wherein the ratio [(an average particle diameter of cellulose particles)/(an average particle diameter of the low crystallinity cellulose raw material)] is 0.7 or less, and (2) the method for producing the cellulose particles wherein the average particle diameter of the cellulose particles is 50 μm or less. The crystallinity of cellulose I type (%)=[(I 22.6 -I 18.5 )/I 22.6 ]×100, wherein I 22.6 represents diffraction intensity of a lattice plane (002 plane), and I 18.5 represents diffraction intensity of an amorphous part. COPYRIGHT: (C)2010,JPO&INPIT
Abstract translation: 待解决的问题:通过抑制纤维素颗粒的凝结而使纤维素I型的平均粒径小,结晶度低的纤维素粒子。 解决方案:公开了一种制备纤维素颗粒的方法,其中将选自高级醇,高级脂肪酸,高级脂肪酸盐,高级脂肪酸酯和聚醚的研磨助剂加入到 纤维素I型结晶度为33%以下的下述式所示的低结晶性纤维素原料,在干燥工序中用研磨机进行处理。 本发明提供了(1)纤维素颗粒的制造方法,其中[(纤维素颗粒的平均粒径)/(低结晶性纤维素原料的平均粒径)]为0.7以下,(2) 纤维素粒子的平均粒径为50μm以下的纤维素粒子的制造方法。 纤维素I型的结晶度(%)= [(I SB = 22.6(S)]×100,其中I
22.6 SB>表示晶格面(002平面)的衍射强度,I SB> 18.5 SB>表示非晶部分的衍射强度。 版权所有(C)2010,JPO&INPIT -
公开(公告)号:JP2010047622A
公开(公告)日:2010-03-04
申请号:JP2008210300
申请日:2008-08-19
Inventor: UMEHARA MASAHIRO , NOJIRI NAOKI , UGAJIN TORU , OTSUKA HITOSHI
Abstract: PROBLEM TO BE SOLVED: To provide a method for effectively producing low crystalline cellulose wherein cellulose I type crystallinity is reduced from a cellulose-containing raw material with excellent productivity. SOLUTION: In the method for producing low crystalline cellulose, a cellulose-containing raw material, wherein cellulose I type crystallinity of the cellulose represented by formula (1) exceeds 33%, is processed in a twin-screw extruder; and a cellulose-containing raw material with water content of ≤5 mass% is processed in a twin-screw extruder having a clearance between an inner wall of a cylinder and an external surface of a kneading screw of 0.05-5.0 mm at a shear rate of 600-4,000 sec -1 to reduce the cellulose I type crystallinity to ≤33%. Cellulose I type crystallinity (%)=[(I 22.6 -I 18.5 )/I 22.6 ]×100 (1), wherein I 22.6 is the diffraction intensity of the lattice plane (002) in X-ray diffractometry (diffraction angle 2θ=22.6°), and I 18.5 is the diffraction intensity of the amorphous moiety (diffraction angle 2θ=18.5°). COPYRIGHT: (C)2010,JPO&INPIT
Abstract translation: 要解决的问题:提供一种有效生产低结晶纤维素的方法,其中纤维素I型结晶度从具有优异生产率的含纤维素原料中降低。 解决方案:在生产低结晶纤维素的方法中,在双螺杆挤出机中加工其中由式(1)表示的纤维素的纤维素I型结晶度超过33%的含纤维素原料, 含水量≤5质量%的含纤维素原料在双螺杆挤出机中以剪切速率在圆筒内壁与混炼螺杆外表面之间的间隙为0.05-5.0mm的条件下进行加工 600-4,000秒
-1 SP>以将纤维素I型结晶度降低至≤33%。 纤维素I型结晶度(%)= [(I 22.6 SB> -I SB> 18.5 SB>)×100(1)其中I < SB> 22.6 SB>是X射线衍射(衍射角2θ= 22.6°)中的晶格面(002)的衍射强度,I SB> 18.5 SB>是无定形部分的衍射强度 (衍射角2θ= 18.5°)。 版权所有(C)2010,JPO&INPIT
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