公开(公告)号：JPH09278914A

公开(公告)日：1997-10-28

申请号：JP29883496

申请日：1996-11-11

Applicant: TORAY INDUSTRIES

Inventor： ENOU MASAZUMI ,  MURAKI TOSHIO ,  YAMANE SHOJI

IPC: C08J5/24

Abstract: PROBLEM TO BE SOLVED: To obtain a fiber-reinforced plastic having both excellent mechanical properties and flame retardance and a prepreg excellent in moldability in order to obtain the fiber-reinforced plastics. SOLUTION: This prepreg comprises carbon fibers impregnated with a composition comprising an epoxy resin component composed of at least one epoxy resin selected from the group of brominated epoxy resins, bisphenol A type epoxy resins having a high epoxy equiv., novolak type epoxy resins, bisphenol A type epoxy resins having a low epoxy equiv. and tetraglycidyldiaminodiphenylmethane, a curing agent for the epoxy resin and antimony trioxide. Furthermore, the carbon-fiber reinforced plastics is obtained from the prepreg.

公开(公告)号：JPH0423653B2

公开(公告)日：1992-04-22

申请号：JP14018485

申请日：1985-06-28

Applicant: TORAY INDUSTRIES

Inventor： MURAKI TOSHIO ,  MATSUZAKI AKIMITSU ,  TAKEO AKIRA

IPC: C08F20/22 ,  B32B17/02 ,  B32B17/04 ,  C08F20/00 ,  C08J5/24 ,  C08L63/00

公开(公告)号：JPH0420027B2

公开(公告)日：1992-03-31

申请号：JP25648087

申请日：1987-10-12

Applicant: TORAY INDUSTRIES

Inventor： CHIBA KAZUMASA ,  TANAKA SEIJI ,  MURAKI TOSHIO

IPC: C08K3/10 ,  C08K3/16 ,  C08K5/18 ,  C08L23/00 ,  C08L77/00

公开(公告)号：JPH0363571B2

公开(公告)日：1991-10-01

申请号：JP1763682

申请日：1982-02-08

Applicant: TORAY INDUSTRIES

Inventor： KOBAYASHI KAZUHIKO ,  CHIBA KAZUMASA ,  MURAKI TOSHIO

IPC: C08G69/00 ,  C08G69/44 ,  G01K7/16 ,  H01B3/30 ,  H01C7/04

公开(公告)号：JPH02143810A

公开(公告)日：1990-06-01

申请号：JP29699688

申请日：1988-11-24

Applicant: TORAY INDUSTRIES

Inventor： KIMOTO YUKITANE ,  MURATA KOZO ,  MURAKI TOSHIO

IPC: B29B11/16 ,  B29C45/00 ,  B29C45/02 ,  B29C70/06 ,  B29C70/14 ,  B29C70/46 ,  B29K101/12 ,  B29K105/06 ,  C08J5/24 ,  F02F7/00

Abstract: PURPOSE:To obtain a FRTP product with excellent dynamic characteristics by compounding thermoplastics resin with a specific melting viscosity and strip- shaped members consisting of reinforcing fibers disposed in a random direction within two dimensions and paralleled in one direction, and make it a pseudo isotropy in its surface. CONSTITUTION:Strip-shaped members are compounded, consisting of thermoplastics resin of 1000-15000 poise in its melting viscosity and reinforcing fibers disposed in a random direction within two dimensions and paralleled in one direction. And, the strip-shaped members are 0.2mm or less in its thickness. The length in a direction perpendicularly intersecting relative to the direction of the reinforcing fibers is 2-25mm, and the length in a direction of the reinforcing fibers is 5-30mm, furthermore, (the length in a direction perpendicularly intersecting relative to the direction of reinforcing fibers)/(the length in a direction of the reinforcing fibers) is 0.15-1.5. Besides, it is a pseudo isotropy in its surface. Owing to this, it may be more uniform in the distribution of the reinforcing fibers, and it may also be excellent in its molding property and isotropy.

公开(公告)号：JPS63308064A

公开(公告)日：1988-12-15

申请号：JP9063188

申请日：1988-04-13

Applicant: TORAY INDUSTRIES

Inventor： CHIBA KAZUMASA ,  MURAKI TOSHIO

IPC: F28F21/06 ,  C08K7/14 ,  C08L77/00

Abstract: PURPOSE:To obtain a top and base of an automotive radiator, by blending a mixture of a polyamide, such as nylon 6 or nylon 66, with a higher polyamide, such as nylon 11, as necessary, adding an inorganic reinforcing material and molding the resultant blend. CONSTITUTION:A top and base obtained by blending 100pts.wt. mixture of (A) 5-95wt.% polyamide (preferably nylon 66) containing caproamide and/or hexamethylene adipamide units as main constituent units with (B) 5-95wt.% polyamide (preferably nylon 6.9, nylon 6.10 or nylon 6.12) prepared by melt polymerizing one or more selected from equimolar salts (except hexamethylene diammonium adipate) of 11-22C aliphatic amino acids, lactams and 6-12C aliphatic diamines with 6-12C aliphatic dicarboxylic acids with (C) 0-10pts.wt. inorganic reinforcing material (preferably glass fibers), melt kneading the blend and molding the kneaded blend (preferably by injection molding).

公开(公告)号：JPS63295664A

公开(公告)日：1988-12-02

申请号：JP9063588

申请日：1988-04-13

Applicant: TORAY INDUSTRIES

Inventor： CHIBA KAZUMASA ,  MURAKI TOSHIO

IPC: C08L77/00

Abstract: PURPOSE:To make it possible to form a tube for automobile pipes, possessing all of heat resistance rigidity, toughness, dimensional stability, road antifreezer resistance, etc., by mixing two polyamides at a specified ratio and molding the mixture. CONSTITUTION:A tube for automobile pipes is formed by molding a mixture 5-95wt.% polyamide (A) mainly consisting of structural units of capramide and/or hexamethyleneadipamide units (e.g., nylon 6 or nylon 56) with a polyam ide obtained by melt-polymerizing at least one member selected from among an 11-12C aliphatic amino acid, a lactam and an equimolar salt of a 6-12C aliphatic diamine with a 6-12C aliphatic dicarboxylic acid (except for hexamethylenediammoniumadipate) (e.g., nylon 11 or nylon 12).

公开(公告)号：JPS6356907B2

公开(公告)日：1988-11-09

申请号：JP5189282

申请日：1982-03-30

Applicant: TORAY INDUSTRIES

Inventor： CHIBA KAZUMASA ,  KOBAYASHI KAZUHIKO ,  MURAKI TOSHIO

IPC: C08L77/00 ,  C08K5/10 ,  C08K5/43 ,  C08L67/00 ,  C08L77/12

公开(公告)号：JPS62185720A

公开(公告)日：1987-08-14

申请号：JP2673486

申请日：1986-02-12

Applicant: TORAY INDUSTRIES

Inventor： SUZUE SHIGERU ,  HASUMI SHIGERU ,  MURAKI TOSHIO

IPC: C08J5/24 ,  C08G59/00 ,  C08G59/50 ,  C08L63/00 ,  C08L79/04 ,  C08L81/06

Abstract: PURPOSE:To produce the titled high-quality composition within a short time, by dissolving a specified ground thermoplastic resin in an epoxy resin and mixing the resulting solution with a cyanic ester resin. CONSTITUTION:100-20wt% cyanic ester of formula I (wherein R is an aromatic organic group and m is 2-5) and 0-80wt% maleimide of formula II (wherein R is a bi- to penta-valent aromatic or aliphatic organic group and m is 2-5) are prepolymerized at 80-160 deg.C for 1-4hr to obtain a cyanic ester (C). A thermoplastic resin of a glass transition temperature >=100 deg.C (e.g., polyether sulfone) is ground with an impact mill and classified to obtain a thermoplastic resin powder (A) of a particle diameter

公开(公告)号：JPS6236427A

公开(公告)日：1987-02-17

申请号：JP17565085

申请日：1985-08-12

Applicant: TORAY INDUSTRIES

Inventor： MATSUZAKI AKIMITSU ,  MURAKI TOSHIO ,  TAKEO AKIRA

IPC: C08G59/00 ,  C08J5/04 ,  C08J5/24 ,  C08L33/00 ,  C08L33/02 ,  C08L63/00 ,  C08L67/00

Abstract: PURPOSE:The titled lightweight composite material of excellent strength, comprising a specified carbon fiber and a matrix resin. CONSTITUTION:A prepreg is obtained by impregnation a carbon fiber having a 1.5mu-thick surface layer whose perfectness of crystal is on level with that of the fiber core, said surface layer having a 0.2mu-thick or below super-thin outer layer whose perfectness of crystal is low as compared with that of the fiber core,a tensile strength at a fiber volume rate of 70%>=370kg/mm , a tensile strength of a resin-impregnated strand >=600kg/mm , a content of heat- decomposable organic matter of 0.05-0.5wt%, and a ratio of functional group content (OIs/CIs) detected by X-ray photo-electron spectroscopy of 0.1-0.4 with a matrix resin (e.g.., epoxy resin) or a tensile elongation at break (JIS-K-7113)>=3.0 (e.g., epoxy resin). Several to several tens of such prepregs are laminated and heated to cure the resin.