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公开(公告)号：JPH07237403A
公开(公告)日：1995-09-12
申请号：JP3268494
申请日：1994-03-02
Applicant: TORAY INDUSTRIES
Inventor： YOKOIKAWA TAKUMI , HIRAI AKIRA
Abstract: PURPOSE:To provide a molding excellent in the shock resistance of weld part of a core, the adhesion between a core part and a shell part, the durability of a caster, and the uniformity of the tint of the core part, and its manufacture simple in production process, taking the resin composition of the core part of the caster and the shell part into consideration. CONSTITUTION:A core part consists of 40-90wt.% A polyamide resin, 5-50wt.% ABS resin, and 3-20wt.% denatured vinyl copolymer consisting of aromatic vinyl, vinyl cyanide, and alpha, beta-unsaturated carbonic acid, and the shell part consists of thermoplastic polyurethane resin, and core part is made after formation of shell part. This caster molded item is excellent in the shock resistance of the weld zone of the core part requested as a caster molding, the adhesion between the core part and the shell part, and the processing property of the core part, and besides the color difference between the nonweld zone and the weld zone is extremely small, and the manufacture process is simple, and this is excellent in the point of productivity.
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公开(公告)号：JPH06122820A
公开(公告)日：1994-05-06
申请号：JP27444892
申请日：1992-10-13
Applicant: TORAY INDUSTRIES
Inventor： YOKOIKAWA TAKUMI , HANATANI YASUNAGA , TERAJIMA TAKESHI
Abstract: PURPOSE:To obtain a resin composition composed of a specified poly-epsilon- caprolactam, an aliphatic bisamide and an aliphatic carboxylic acid or its diol ester and excellent in high-cycling properties in injection molding and mechanical properties. CONSTITUTION:This polyamide resin composition is obtained by blending (A) 100 pts.wt. mixture prepared by adding Ba(OH)2, BaO, etc., to a poly-epsilon- caprolactam exhibiting >=0.4 ratio of gamma-type crystal, e.g. a molten poly-epsilon- caprolactam after completion of polymerization with (B) 0.01 to 1 pt.wt., preferably 0.02 to 0.5 pt.wt. aliphatic bisamide [e.g. methylene-bis(stearylamide)] of formula I or II (R1 is a 1 to 10C hydrocarbon group; R2 and R3 are each a 10 to 30C hydrocarbon group; R4 and R5 are each H or a 1 to 4C hydrocarbon group) and (C) 0.01 to 0.8 pt.wt., preferably 0.05 to 0.5 pt.wt. 1 to 22C aliphatic carboxylic acid or its diol ester (preferably ethylene glycol ester or 1,4-butane diol ester of montanic acid).
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公开(公告)号：JPS63179957A
公开(公告)日：1988-07-23
申请号：JP1285587
申请日：1987-01-22
Applicant: TORAY INDUSTRIES
Inventor： YOKOIKAWA TAKUMI , IWAMOTO MASATOSHI , KISHIMOTO AKIHIKO
Abstract: PURPOSE:To obtain a thermoplastic resin composition having impact resistance, molding and processing properties and chemical resistance, by blending ABS resin with a polyamide resin and a specific modified vinyl polymer. CONSTITUTION:A resin composition consisting of (A) 10-84pts.wt. ABS resin consisting of preferably 5-85pts.wt. diene rubber, 8-50pts.wt. vinyl cyanide, 10-90pts.wt. aromatic vinyl and, if necessary, another copolymerizable monomer, (B) 15-89pts.wt. polyamide resin, preferably nylon 6 of nylon 66 and (C) 1-70pts.wt. modified vinyl polymer obtained by copolymerizing an aromatic vinyl (preferably styrene or alpha-styrene) with a vinyl cyanide (preferably acrylonitrile), an alpha,beta-unsaturated carboxylic acid [e.g. (meth)acrylic acid] and, if necessary, another copolymerizable monomer having 100pts.wt. in sum of the components A, B and C.
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公开(公告)号：JPS6310656A
公开(公告)日：1988-01-18
申请号：JP14643386
申请日：1986-06-23
Applicant: TORAY INDUSTRIES
Inventor： WAKABAYASHI TOSHIO , YOKOIKAWA TAKUMI , KISHIMOTO AKIHIKO , CHIBA KAZUMASA
Abstract: PURPOSE:To provide the title compsn. having excellent rigidity, moldability and resistance to impact and heat, by blending a specified polyphenylene ether with a polyamide and a (hydrogenated) block copolymer elastomer. CONSTITUTION:100pts.wt. polyphenylene ether (i) of the formula [wherein Q1, Q2 Q3 and Q4 are each H, halogen, a (halo)hydrocarbon or a (halo) hydrocarbonoxy; n is the total number of monomers and 20 or greather] is reacted with 0.1-20pts.wt. 1,2-substd. olefin compd. (ii) having a carboxyl group or carboxylic acid anhydride structure in the presence of 0.1-30pts.wt. [based on the amount of the component (ii)] radical-generating agent to obtain a polyphenylene ether (a) having a carboxyl group and/or carboxylic acid anhydride structure as part of substituents. 5-95wt% component (a) is blended with 5-90wt% polyamide (b) and 5-60wt% (hydrogenated) A-B-A' block copolymer elastomer (c) (wherein A and A' are each a polymerized hydrocarbon block; and B is a polymerized conjugated block which may be hydrogenated).
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公开(公告)号：JPS62177065A
公开(公告)日：1987-08-03
申请号：JP1909086
申请日：1986-01-30
Applicant: TORAY INDUSTRIES
Inventor： WAKABAYASHI TOSHIO , KISHIMOTO AKIHIKO , YOKOIKAWA TAKUMI
IPC: C08L23/26 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L71/12 , C08L77/00 , C08L101/00
Abstract: PURPOSE:A thermoplastic resin composition, obtained by blending a polyphenylene ether resin with polyamide and specific modified polyolefin in a specific proportion and having improved impact, heat, weather and chemical resistance and moldability. CONSTITUTION:A thermoplastic resin composition obtained by uniformly blending and melt kneading (A) 5-90wt%, preferably 15-80wt% polyphenylene ether resin, e.g. poly(2,6-dimethyl-1,4-phenylene)ether, etc., with (B) 5-90wt%, preferably 10-80wt% polyamide, e.g. nylon 6, nylon 11, etc., and copolyamide consisting essentially thereof and (C) 5-60wt%, preferably 8-50wt% polyolefin having one or more functional groups selected from the group consisting of carboxylic acid group and acid anhydride group, preferably a polyolefin graft modified with a vinyl based monomer having carboxylic acid (anhydride) group.
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Patent Agency Ranking
公开(公告)号：JP2000308737A
公开(公告)日：2000-11-07
申请号：JP12188299
申请日：1999-04-28
Applicant: TORAY INDUSTRIES
Inventor： YOKOIKAWA TAKUMI , GOTO YOSHIAKI
IPC: A63F7/02
Abstract: PROBLEM TO BE SOLVED: To provide a highly transparent, shock-proof and chemical-proof ball running slope part for a game machine to be manufactured by injection molding. SOLUTION: This ball running slope for a game machine is made of a polyester copolymer comprising more than two kinds of diol components and/or dicarboxylic acid components of polyester. Optionally, the ball running slope is made of a resin composition comprised of 10-90 weight % of a polyester copolymer comprising more than two diol components and/or dicarboxylic acid components of polyester and 90-10 weight % of polycabonate melted and mixed together. The ball running slope part can be manufactured by molding a polyester copolymer comprising more than two kinds of diol components and/or dicarboxylic acid components.
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公开(公告)号：JPH0460499B2
公开(公告)日：1992-09-28
申请号：JP1285687
申请日：1987-01-22
Applicant: TORAY INDUSTRIES
Inventor： YOKOIKAWA TAKUMI , IWAMOTO MASAAKI , KISHIMOTO AKIHIKO
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公开(公告)号：JPH03422B2
公开(公告)日：1991-01-08
申请号：JP14643386
申请日：1986-06-23
Applicant: TORAY INDUSTRIES
Inventor： WAKABAYASHI TOSHIO , YOKOIKAWA TAKUMI , KISHIMOTO AKIHIKO , CHIBA KAZUMASA
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公开(公告)号：JPS63234055A
公开(公告)日：1988-09-29
申请号：JP6576187
申请日：1987-03-23
Applicant: TORAY INDUSTRIES
Inventor： GOTO NORIAKI , YOKOIKAWA TAKUMI , IWAMOTO MASAAKI
Abstract: PURPOSE:To obtain the titled composition having excellent impact resistance and weld strength and improved weather resistance, molding and processing properties, by blending a composition consisting of an AES polymer obtained by water suspension polymerization and an aromatic polycarbonate with polymethacrylic acid ester, etc. CONSTITUTION:100pts.wt. composition consisting of (A) 10-90pts.wt. granular graft copolymer obtained by blending 100pts.wt. sum of A1: 10-60pts.wt. ethylene-propylene-diene rubber and A2: 40-90pts.wt. mixture of (i) 55-95wt.% aromatic vinyl monomer and/or methacrylic acid ester monomer and (ii) 5-45wt.% vinyl cyanide monomer with A3: 20-400pts.wt. hydrocarbon solvent and polymerizing and (B) 90-10pts.wt. aromatic polycarbonate is blended in molten state with (C) 1-20pts.wt. polymethacrylic acid ester and/or polyglutarimide and (D) 0-20pts.wt. MBS polymer and/or acrylic acid ester graft polymer.
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公开(公告)号：JPS63221155A
公开(公告)日：1988-09-14
申请号：JP5459087
申请日：1987-03-10
Applicant: TORAY INDUSTRIES
Inventor： GOTO NORIAKI , YOKOIKAWA TAKUMI , IWAMOTO MASAAKI
Abstract: PURPOSE:To provide the title compsn. having excellent impact resistance, weld strength and moldability, by adding two specific components to a compsn. consisting of an ABS resin and an arom. polycarbonate resin. CONSTITUTION:10-90wt.% ABS resin (a) obtd. from diene rubber, a vinyl cyanide monomer, an arom. vinyl monomer and optionally, other copolymerizable monomer, is blended with 90-10wt.% arom. polycarbonate resin (b) to obtain a compsn. 1-20pts.wt. polymethacrylate resin (c) and/or polyglutarimide (c) which is a polymer having a cyclic imide unit of formula [wherein R1, R2 and R3 are each H, a 1-20C (substd.) alkyl or aryl] and 0.5-20 pts.wt. MBS resin (d) obtd. by grafting an alkyl unsaturated carboxylate and an arom. vinyl monomer onto diene rubber and/or acrylate graft copolymer (d) obtd. by grafting a vinyl compd. onto a copolymer obtd. from an alkyl acrylate and a polyfunctional polymerizable monomer having a conjugated diene type double bond, are added to 100pts.wt. said composition.
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